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Wyświetlanie 1-2 z 2
Tytuł:
The Effect of the Type of Admixture on the Properties of Polyacrylonitrile Membranes Modified With Nanotubes, Graphene Oxide and Graphene
Autorzy:
Fryczkowska, B.
Przywara, L.
Powiązania:
https://bibliotekanauki.pl/articles/124223.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
composite membranes
PAN/GO
PAN/RG
PAN/MWCNT
ultrafiltration
electroplating waste water
Opis:
This paper presents the results of research on the production of composite polyacrylonitrile (PAN) membranes with nanotubes (MWCNT), graphene (RG) and graphene oxide (GO) addition. All of the specified additions differ diametrically in terms of properties, starting from the spatial structure of the particles, to the chemical properties. The membranes were obtained using phase inversion method from a solution of N,N-dimethylformamide (DMF). Subsequently, the impact of the nano-addition on the transport and separation properties of the membranes was investigated using Millipore AMICON ultrafiltration kit. Membranes with graphene addition (PAN/RG) are characterized by the best transport properties and the highest specific permeate flux values in the range of ~913÷1006 dm3/m2×h for the working pressure of 2.0 MPa. In order to test the separation properties, electroplating wastewater generated in one of the Silesian galvanizing plants was used. The qualitative and quantitative composition of the wastewater was tested by means of UV-Vis spectrophotometer (HACH) and absorption atomic spectrometry (AAS). The ultrafiltration process carried out on composite membranes allows for the complete removal of phosphate ions and ~88÷94% removal of iron from the waste water. The rejection coefficient of the remaining metals is high: ~35÷85% for copper and ~17÷100% for cadmium.
Źródło:
Journal of Ecological Engineering; 2017, 18, 5; 72-81
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prevention of Hydrosphere Contamination with Electroplating Solutions through Electromembrane Processes of Regeneration
Autorzy:
Serdiuk, Vasyl
Sklabinskyi, Vsevolod
Bolshanina, Svetlana
Ableyev, Alexey
Dychenko, Tetiana
Powiązania:
https://bibliotekanauki.pl/articles/124544.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
electrolysis
electroplating solution
cation exchange membrane
cadmium cation
zinc cation
forced mixing
Opis:
The work studies the process of Сd2+ and Zn2+ cations transfer through a RALEX®CM-PES 11–66 cation-exchange membrane and the cations reduction as metals on the cathodes at the cathode chambers of the electrochemical units with a view to prevent the hydrosphere contamination with the electroplating solutions. Electrolysis of the solutions that imitated the possible composition of the passivating baths contained 50 g/l sodium dichromate, 10 g/l sulfuric acid and impurity ions of Сd2+ and Zn2+ in various concentrations. The designed passivation solutions with certain amount of impurity ions in the colour solution were forcibly mixed. The impact of the impurity ions concentration in the colour solution and of a forced mixing on the metal reduction was studied. Regularity in the increased metal reduction dependent on the metal concentration was found and the conditions favouring the ion migration through the cation-exchange membrane due to forced mixing were defined.
Źródło:
Journal of Ecological Engineering; 2020, 21, 4; 61-69
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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