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Tytuł:
Anode Modification with Reduced Graphene Oxide–Iron Oxide Improves Electricity Generation in Microbial Fuel Cell
Autorzy:
Nosek, Dawid
Cydzik-Kwiatkowska, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/2202130.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
MFC
reduced graphene oxide
iron(III) oxide
electricity generation
wastewater
Opis:
In recent years, much research has focused on energy recovery from biomass as an alternative to fossil fuel usage. Microbial fuel cells (MFCs), which produce electricity via microbial decomposition of organic matter, are of great interest. The performance of an MFC depends on the electrode material; most often, carbon materials with good electrical conductivity and durability are used. To increase the power output of an MFC, the anode material can be modified to reduce the internal resistance and increase the anode surface area. Therefore, this study determined how modifying a carbon felt anode with reduced graphene oxide (rGO) and a combination of rGO with iron (III) oxide (rGO-Fe) affected electricity generation in an MFC fueled with wastewater. A mixed microbial consortium was used as the anode biocatalyst. The MFC-rGO-Fe produced significantly higher voltages than other cells (average 109.4 ± 75.1 mV in the cycle). Power density curves indicated that modifying the anode with rGO-Fe increased the power of the MFC to 4.5 mW/m2, 9.3- and 3.9-times higher than that of the control MFC and the MFC-rGO, respectively. Anode modification reduced the internal resistance of the cells from 1029 Ω in the control MFC to 370 and 290 Ω in the MFC-rGO and MFC-rGO-Fe, respectively. These results show that a mixture of rGO with iron (III) oxide positively affects electricity production and can be successfully used for anode modification in the MFCs fueled with wastewater.
Źródło:
Journal of Ecological Engineering; 2022, 23, 10; 147--153
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Treatment of Acid Mine Drainage in a Bioelectrochemical System, Based on an Anodic Microbial Sulfate Reduction
Autorzy:
Angelov, Anatoliy
Bratkova, Svetlana
Ivanov, Rosen
Velichkova, Polina
Powiązania:
https://bibliotekanauki.pl/articles/27323817.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
BES
bioelectrochemical system
MFC
microbial fuel cell
MEC
microbial electrolysis cell
ethanol stillage
microbial sulfate reduction
acid mine drainage
heavy metals
sulphate
Opis:
The possibilities of simultaneous removal of sulfates and heavy metals (Cu, Ni, Zn) from acid mine drainage have been investigated in two-section bioelectrochemical system (BES). The used BES is based on the microbial sulfate reduction (MSR) process in the anode zone and abiotic reduction processes in the cathodic zone. In the present study, the model acid mine drainage with high sulfate (around 4.5 g/l) and heavy metals (Cu2+, Ni2+ and Zn2+) content was performed. As a separator in the laboratory, BES used an anionic exchange membrane (AEM), and for electron donor in the process of microbial sulfate reduction in the bioanode zone – waste ethanol stillage from the distillery industry was employed. In this study, the possibility of sulfates removal from the cathodic zone was established by their forced migration through AEM to the anode zone. Simultaneously, as a result of the MSR process, the sulfate ions passed through AEM are reduced to H2S in the anode zone. The produced H2S, having its role as a mediator in electron transfer, is oxidized on the anode surface to S0 and other forms of sulfur. The applicability of waste ethanol stillage as a cheap and affordable organic substrate for the MSR process has also been established. Heavy metals (Cu2+, Ni2+ and Zn2+) occur in the cathode chamber of BES in different degrees of the removal. As a microbial fuel cell (MFC) operating for 120 hours, the reduction rate of Cu2+ reaches 94.6% (in waste ethanol stillage) and 98.6% (in the case of Postgate culture medium). On the other hand, in terms of Ni2+ and Zn2+, no significant decrease in their concentrations in the liquid phase is found. In the case of microbial electrolysis cell (MEC) mode reduction of Cu2+– 99.9%, Ni2+– 65.9% and Zn2+– 64.0% was achieved. For 96 hours, the removal of sulfates in MEC mode reached 69.9% in comparison with MFC mode – 35.2%.
Źródło:
Journal of Ecological Engineering; 2023, 24, 7; 175--186
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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