Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

Wyszukujesz frazę "geochemical" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Surface geochemical anomalies in the vicinity of the Wańkowa Oil Field (SE Polish Carpathians)
Autorzy:
Sechman, H.
Kuśmierek, J.
Machowski, G.
Guzy, P.
Dzieniewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/191525.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
surface geochemical survey
soil gas
light hydrocarbons
oil traps
Skole Nappe
Outer Carpathians
Polska
Opis:
The oil accumulations discovered in the Skole Synclinorium (eastern part of Polish Outer Carpathians) are located in zones of pinch-out of the Kliva Sandstone. An example is the Wańkowa Oil Field, which contains the largest oil reserves in the region. As the seismic identification of this type of hydrocarbon trap is ambiguous, a surface geochemical survey was carried out in the vicinity of the Wańkowa Oil Field along an experimental line perpendicular to the fold axes. A traverse across the zones with anomalous seismic records indicated the presence of undiscovered lithological traps. During the surface geochemical survey, 94 samples of soil gas were collected from a depth of 1.2 m and then investigated chromatographically. The spacing of sampling sites was 100 m, which was reduced to 50 m in the Wańkowa Oil Field area. The maximum concentrations of CH4 and total alkanes C2-C5 detected in samples were: 4250.0 ppm (0.425 vol. %) and 0.43 ppm, respectively. The first of these was detected at measurement point no. 86, located over the Wańkowa Field and the second at point no. 59, about 1,300 m south of the Wańkowa Field. The chemical analyses also detected maximum values of total alkenes C2-C4, H2 and CO2: 0.147 ppm, 0.042 vol. % and 4.4 vol. %, respectively. The results of the surface geochemical survey were integrated with observations on subsurface geological structures, which were interpreted on the basis of seismic data. This procedure permitted the documentation of anomalous concentrations of alkanes in the near-surface zone and contributed to an understanding of the tectonics of the hydrocarbon reservoirs in depth. The pattern of geochemical anomalies here is controlled by anticlines made up of Early Oligocene–Paleocene sediments and by overthrusts that displace these structures. The hydrocarbons migrated from condensate and/or oil accumulations located at various depths. The character of the anomalous zone discovered over the Wańkowa Oil Field is related to the effective sealing of hydrocarbon traps and/or the relatively low pressure caused by the production of oil for 130 years. However, this anomaly also may be the result of hydrocarbon migration from deeper, as yet undiscovered gas or gas-condensate accumulations, hosted in older reservoirs forming the hinge of the Ropienka-Łodyna Mine Anticline. The most pronounced anomalies were detected over the Wańkowa Village - Bandrów and Grabownica-Załuż anticlines. The active hydrocarbon dispersion in this zone may have resulted from the presence of overthrusts displacing the structures. Moreover, these anomalies may indicate the presence of shallow, maybe poorly sealed hydrocarbon accumulations.
Źródło:
Annales Societatis Geologorum Poloniae; 2016, 86, 2; 219-235
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phenomena at interface of saline aquifer and claystone caprock under conditions of CO2 storage
Autorzy:
Labus, K.
Powiązania:
https://bibliotekanauki.pl/articles/191188.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
aquifer CO2 sequestration
gas–rock–water interactions
caprock reactivity
geochemical modelling
Upper Silesian Coal Basin
Opis:
When modelling the impact of the hydrogeochemical processes of CO2 sequestration on the contact zone of a saline sandstone aquifer and a claystone caprock in the Upper Silesian Coal Basin, small decreases in porosity were noted, visible mainly in the aquifer rocks. They were due to the degradation of kaolinite, albite and muscovite, and the recrystallization of K-feldspar and quartz. The porosity of the caprock remained almost unchanged, which was to the advantage of the integrity of the repository. In major parts of the aquifer and caprock zone, the mineral trapping of CO2 has beneficial effects, but at the interface of the aquifer and the insulating layer, in the basal part of the caprock, a release of carbon dioxide may occur temporarily, associated with the dissolution of calcite.
Źródło:
Annales Societatis Geologorum Poloniae; 2012, 82, 3; 255--262
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular and isotopic compositions of gases adsorbed to near surface sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Dzieniewicz, M.
Sechman, H.
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/191497.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
near-surface geochemical survey
adsorbed gases
origin of gaseous hydrocarbons
origin of carbon dioxide
Quaternary sediments
Starunia palaeontological site
Carpathian region
Ukraine
Opis:
The near-surface geochemical survey of gases desorbed from sediment samples was carried out in the area of an abandoned ozokerite mine in Starunia, where remnants of mammoth and three woolly rhinoceroses and one almost completely preserved rhinoceros carcass were discovered in 1907 and 1929. Numerous hydrocarbon seeps (gas and oil "eyes") occur on the surface of the study area. Analyses of molecular and stable carbon isotope compositions of adsorbed gases were carried out in two variants. The first included sampling of cuttings from 30 auger boreholes at depths of 4.8, 5.6 and 6.4 m. In total, 88 samples were collected. In the second variant core samples were collected from 17 selected boreholes. In total, 78 samples were taken from various depths to 12 m. The results of molecular composition analyses of desorbed gases indicated high saturation of near-surface sediments with the oil. The highest concentrations of alkanes were detected in Miocene strata. Hydrocarbon migration from deep accumulations to the surface was relatively fast and proceeded along the faults, fractures and cracks. In the near-surface zone hydrocarbons were subjected to oxidation and dehydrogenation, which resulted in generation of unsaturated hydrocarbons and hydrogen. These processes were most intensive in the Pleistocene sediments and in the mine dumps. Increased concentrations of hydrogen may also originate from water radiolysis in the presence of hydrocarbons. Concentrations of carbon dioxide in the adsorbed gases show the higher values in comparison with the analysed gaseous compounds. However, a slight increase in CO2 concentration was detected in the mine dump, which may indicate conditions more favourable for hydrocarbon oxidation. Carbon dioxide from the analysed adsorbed gases is of thermogenic origin. Occasionally, insignificant influence of secondary hydrocarbon oxidation and/or Quaternary organic matter can be observed. Concentrations of alkanes, alkenes and carbon dioxide in the gas derived from desorption of rock samples are lower and the concentration of hydrogen is higher than those measured in free gases. This indicates that additional effects from recent (e.g. microbial) processes are absent.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 421-437
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface geochemical survey at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Sechman, H.
Kotarba, M. J.
Dzieniewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/191493.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
surface geochemical survey
stable carbon isotopes
methane origin
gaseous hydrocar bon C2-C5
carbon dioxide origin
woolly rhinoceros
Starunia
Carpathian region
Ukraine
Opis:
A surface geochemical survey was carried out in an abandoned ozokerite mine in Starunia, where remnants of a mammoth and three woolly rhinoceroses and one almost completely preserved rhinoceros carcass were found in 1907 and 1929. In total, 689 measurement sites were defined within the selected 300×350 m rectangle (ca. 10.5 ha). The analysed soil gases vary in their molecular and isotopic compositions. Several zones with anomalous methane concentrations over 10 vol% were identified in the study area. These anomalous concentrations correlate well with total C2-C5 alkane anomalies (over 1 vol%). The zones with carbon dioxide concentrations over 15 vol% are generally shifted SW of those, where the methane and the sum of C2-C5 alkanes anomalies were identified. High helium concentrations of crustal origin (over 0.001 vol%) are clustered near fault zones. In a majority of cases methane is of thermogenic origin, migrating to the near-surface zone from deep-seated accumulations. Microbial methane, or methane with a high microbial component, is genetically related to recent swamps. The high variability of concentrations of gaseous components together with the highly variable isotopic composition of individual gases in the soil, indicate their thermogenic and/or microbial origin, and point to the lithological diversity of Quaternary sediments in the study area. Several zones with thermogenic gaseous hydrocarbons and helium were delineated. It is likely that during the Pleistocene winters, under a thick ice and snow cover, the tundra lake and swamp zones around outflows of brines, oil, helium and thermogenic gases had a higher temperature, which resulted in melting and cracking of the ice cover. These sites would be more prospective for future search of well-preserved large vertebrates.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 375-390
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Distribution and origin of gaseous hydrocarbons and carbon dioxide in the Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Kotarba, M. J.
Sechman, H.
Dzieniewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/191503.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
near-surface geochemical survey
depth gas distribution
stable carbon isotopes
gaseous hydrocarbon origin
carbon dioxide origin
Quaternary sediments
woolly rhinoceros
Starunia palaeontological site
Ukrainian Carpathians
Opis:
Near-surface gases were investigated in Starunia, where remains of mammoth and woolly rhinoceroses were discovered at the beginning of the 20th century. Samples were collected at 30 measurement sites, from 0.8, 1.6, 2.4, 3.2 and 4.0 m depths and analysed for their molecular and isotopic compositions. Most of the methane and all higher gaseous hydrocarbons accumulated within the near-surface zone are of thermogenic origin. The distribution of thermogenic methane and higher gaseous hydrocarbons in Quaternary sediments is variable and, generally, increases with depth. Microbial methane or a mixture of microbial and thermogenic methane also occurs at the near-surface zone. The presence of hydrogen and alkenes in the near-surface gases also suggests a contribution from recent, microbial processes. Helium of crustal origin migrated through the Rinne Fault and other tectonic zones located in the study area, and was subsequently dispersed during migration through the lithologically diversified Pleistocene and Holocene sediments. The high variability of the carbon dioxide concentration and stable carbon isotope composition at various depths in the near-surface zone is caused by its polygenetic origin (thermogenic, microbial, and oxidation of hydrocarbons and Quaternary organic matter), and also by its dissolution in water and oil during migration through lithologically diversified Pleistocene and Holocene sediments. Zones of thermogenic methane occurrence within Pleistocene sediments, dominated by muds saturated with bitumen and brines, provide the most favourable environment for preservation of large extinct mammals. It is likely that during the Pleistocene winters, when thick ice and snow covered the tundra lake and swamp, zones of outflow of brines, oils, helium, and thermogenic gaseous hydrocarbons had a higher temperature, which could have resulted in melting and cracking of the ice cover and drowning of large mammals. The most favourable conditions for preservation of large, extinct mammals probably still exists in the vicinity of sampling probe sites Nos 21, 22, 23 and 36. Zones of dominance of microbial methane concentrations are less favourable sites for preservation of extinct mammals, because this methane was generated within recent swamps and also within recent descending meteoric waters which infiltrated into Pleistocene and Holocene sediments. Older Pleistocene microbial gases have already escaped to the atmosphere.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 403-419
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

    Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies