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    Wyświetlanie 1-6 z 6
    Tytuł:
    Ordered Nanoporous Silica Modified with Nanoparticles of Lanthanide Oxides
    Autorzy:
    Zeleňáková, A.
    Kapusta, O.
    Zeleňák, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1368473.pdf
    Data publikacji:
    2014-07
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    75.75.Fk
    81.05.Rm
    75.40.Cx
    Opis:
    Lanthanide oxide nanoparticles were encapsulated inside of pores of highly ordered periodic silica of SBA15 type with hexagonal symmetry. The magnetic properties of such nanoperticles were investigated. The structural characterization using the SAXS, XANES, XRD, and $N_{2}$ adsorption measurements showed the presence of lanthanide oxides of $Ln_{2}O_{3}$ type (Ln=La, Pr, Nd, Gd, Eu), with the size of about 5 nm, incorporated in nanoporous channel system. Their magnetic properties, studied by SQUID apparatus, showed the weak antiferromagnetic ordering at 2 K in the nanocomposites $Gd_{2}O_{3}$@SBA15, $Pr_{2}O_{3}$@SBA15 and $Nd_{2}O_{3}$@SBA15. This behaviour of the nanoparticles is caused by blocking process of magnetic moments, which at 300 K exhibit the superparamagnetism, evidenced from ZFC/FC magnetization.
    Źródło:
    Acta Physica Polonica A; 2014, 126, 1; 218-219
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Magnetocaloric effect in Gd₂O₃@SiO₂ nanocomposite
    Autorzy:
    Zeleňáková, A.
    Hrubovčák, P.
    Berkutova, A.
    Kapusta, O.
    Zeleňák, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1054708.pdf
    Data publikacji:
    2017-04
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    75.30.Sg
    81.05.Rm
    75.20.Ck
    75.75.Fk
    Opis:
    Nanocomposite consisting of Gd₂O₃ nanoparticles embedded in periodical porous silica matrix was investigated with respect to its magnetocaloric properties. Series of field (up to 5 T) dependence of magnetization data were recorded in temperature range 2-52 K. The data were subsequently processed employing Maxwell relation in order to calculate magnetic entropy change (Δ S_M) of the system. Examined nanocomposite exhibited reasonably high value of Δ S_M ≈ 29 J/(kg K) at maximal field change 5 T at the temperature of 2 K which suggests that this material could be feasible for cryomagnetic refrigeration applications.
    Źródło:
    Acta Physica Polonica A; 2017, 131, 4; 810-812
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Fe₂O₃ and Gd₂O₃ Nanoparticles Embedded in Mesoporous Silica: Magnetic Properties Comparison
    Autorzy:
    Kapusta, O.
    Zeleňáková, A.
    Hrubovčák, P.
    Girman, V.
    Zeleňák, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1031039.pdf
    Data publikacji:
    2017-04
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    07.78.+s
    47.11.Kb
    75.75.Cd
    75.40.Cx
    78.20.-e
    Opis:
    Nanocomposite materials containing Fe₂O₃ and Gd₂O₃ nanoparticles with the same concentration were prepared by nanocasting method. At this procedure silica matrix serves as nanoreactor for growth of nanoparticles. Temperature and external dc field dependences of the magnetization both samples were compared. Composite containing Fe₂O₃ nanoparticles shows superparamagnetic behaviour with blocking temperature around 45 K. Otherwise, paramagnetic properties were observed for the sample with Gd₂O₃ (above 10 K). Additionally, due to free pores the silica matrix could serve as medium to increase the number of bonded water molecules. These properties together with appropriate magnetic characteristics make studied materials suitable for magnetic resonance imaging applications.
    Źródło:
    Acta Physica Polonica A; 2017, 131, 4; 860-862
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    XAFS Studies of the Behaviour of Bi in Co/Cu Multilayers
    Autorzy:
    Krupiński, M.
    Kąc, M.
    Polit, A.
    Zabila, Y.
    Zając, D.
    Marszałek, M.
    Kapusta, Cz.
    Dobrowolska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/1809826.pdf
    Data publikacji:
    2009-02
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    61.05.cj
    68.55.-a
    68.65.Ac
    Opis:
    The atomic environment of Bi atoms in the Co/Cu multilayered system was studied with X-ray absorption fine structure spectroscopy. Experiments were carried out on a Co(1 nm)/Cu(2 nm) system with 5 and 10 repetitions of Co/Cu evaporated with very low deposition rate in ultrahigh vacuum. A very small amount of Bi (0.06 nm) was deposited on each Cu film in the system. The X-ray absorption fine structure spectra were measured at the $BiL_3$ edge in the X-ray absorption near-edge structure and extended X-ray absorption fine structure ranges at the Beamline X1 of HASYLAB/DESY synchrotron laboratory in Hamburg. The experimental data showed different local neighbourhood of Bi, depending on the number of Co/Cu bilayer repetitions. The results are discussed in terms of the location and segregation of the Bi atoms as well as its possible oxidation ways.
    Źródło:
    Acta Physica Polonica A; 2009, 115, 2; 565-567
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of Carbon on Spin Reorientation Processes in $Er_{2-x}R_xFe_{14}C$ (R~=~Gd, Pr) - Mössbauer and Magnetometric Studies
    Autorzy:
    Pędziwiatr, A.
    Krawiec, K.
    Bogacz, B.
    Kapusta, Cz.
    Przewoźnik, J.
    Kaczorowski, D.
    Talik, E.
    Powiązania:
    https://bibliotekanauki.pl/articles/1506592.pdf
    Data publikacji:
    2011-01
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    76.80.+y
    75.25.-j
    75.50.-y
    75.50.Bb
    Opis:
    The $Er_{2-x}R_{x}Fe_{14}C$ (R=Gd, Pr) polycrystalline compounds have been synthesized and investigated with $\text{}^{57}Fe$ Mössbauer spectroscopy and magnetic measurements. The spin reorientation phenomena were studied extensively by narrow step temperature scanning in the neighborhood of the spin reorientation temperature. Obtained Mössbauer spectra were analyzed using a procedure of simultaneous fitting and the transmission integral approach. Consistent description of Mössbauer spectra were obtained, temperature and composition dependencies of hyperfine interaction parameters and subspectra contributions were derived from fits and the transition temperatures were determined for all the compounds studied. Initial magnetization versus temperature measurements (in zero and non-zero external field) for $Er_{2-x}Gd_{x}Fe_{14}C$ compounds allowed to establish the temperature regions of reorientation, change of magnetization value during the transition process. The results obtained with different methods were analyzed and the spin arrangement diagrams were constructed. Data obtained for $Er_{2-x}Gd_{x}Fe_{14}C$ were compared with those for $Er_{2-x}Gd_{x}Fe_{14}B$ series.
    Źródło:
    Acta Physica Polonica A; 2011, 119, 1; 48-51
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    An NMR study of Pr$\text{}_{0.5}$Ca$\text{}_{0.5}$Mn$\text{}_{1-x}$Ga$\text{}_{x}$O$\text{}_{3}$ (x=0 and 0.03)
    Autorzy:
    Oates, C. J.
    Kapusta, Cz.
    Riedi, P. C.
    Sikora, M.
    Zając, D.
    Rybicki, D.
    Martin, C.
    Yaicle, C.
    Maignan, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/2037129.pdf
    Data publikacji:
    2004
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    76.60.-k
    75.47.Gk
    Opis:
    An NMR study of polycrystalline Pr$\text{}_{0.5}$Ca$\text{}_{0.5}$Mn$\text{}_{1-x}$Ga$\text{}_{x}$O$\text{}_{3}$ (x=0 and 0.03) at 3 K is presented. Zero field spin-echo spectra of the Ga doped compound consist of an overlapping $\text{}^{69,71}$Ga signal at 74~MHz (hyperfine field of 5.3 T), a $\text{}^{55}$Mn double exchange line at 375 MHz (35.5 T) and a weak Mn$\text{}^{3+}$ signal between 400 and 550 MHz. Measurements in an applied field show a step-like increase in the double exchange line intensity, which corresponds to an increase in the amount of the ferromagnetic metallic phase. This coincides with a step-like feature in the bulk magnetization measurements. The effect is similar to that in the previous field dependent $\text{}^{55}$Mn NMR measurements of Pr$\text{}_{0.67}$Ca $\text{}_{0.33}$MnO$\text{}_{3}$. At the demagnetized and remanent state, a variation of spin- spin relaxation time, T$\text{}_{2}$, across the $\text{}^{55}$Mn line, due to the Suhl-Nakamura interaction is observed, which suggests that the ferromagnetic metallic double exchange regions, at liquid helium temperatures, are at least 4 nm in size.
    Źródło:
    Acta Physica Polonica A; 2004, 105, 1-2; 189-195
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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