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Wyszukujesz frazę "Sreńscek-Nazzal, J." wg kryterium: Wszystkie pola


Wyświetlanie 1-3 z 3
Tytuł:
Activated carbons from molasses as CO₂ sorbents
Autorzy:
Młodzik, J.
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1070546.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
Aim of this research is to obtain effective, molasses based activated carbon, which would adsorb big amounts of CO₂. Molasses was mixed with KOH. Weight ratio of dry materials was 1:1 (AC1, AC3) and 1:2 (only AC2). Homogeneous mixture was obtained. Material was left for 3 h at 25°C. Drying lasted for 12 h at 200°C, and the material was grounded. The mixture was pyrolysed at 750°C, under constant flow (18 dm³/min) of nitrogen. The material was grounded again. Then, powder was washed with water, until filtrate was neutral, which took about 5 dm³ of water. AC3 was washed with 1 dm³ of water. After drying, materials were soaked in HCl (0.1 mol/dm³) for 19 h, and washed with water, until filtrate was neutral. CO₂ adsorption was performed under high pressure up to 40 atm, at 40°C. Specific surface area (according to the Brunauer-Emmett-Teller equation) was calculated for AC1, AC2 and AC3 and it is respectively 1985, 1967, and 2026 m²/g, micropore volume - 0.714, 0.707, and 0.728 cm³/g and it was between 75% and 89% of total pore volume. The excess uptake at 40 atm pressure was as follows: AC1 - 14.02 mmol/g, AC2 - 12.75 mmol/g, and AC3 - 15.79 mmol/g.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 402-404
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of activated carbon from beet molasses and TiO₂ as the adsorption of CO₂
Autorzy:
Glonek, K.
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1075525.pdf
Data publikacji:
2016-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
The objective of this work is to produce activated carbon from sugar beet molasses containing TiO₂ for CO₂ adsorption and reduction. Textural properties of activated carbons were obtained based on the adsorption-desorption isotherms of nitrogen at 77 K. The specific surface areas of activated carbons were calculated by the Brunauer-Emmett-Teller method. The volumes of micropores were obtained by density functional theory method. The adsorption isotherms of CO₂ were measured up to the pressure of 1 atm at a temperature of 40°C. The best activated carbon adsorbed 1.9 mmol/g of CO₂.
Źródło:
Acta Physica Polonica A; 2016, 129, 1; 158-161
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of commercial activated carbons for CO₂ adsorption
Autorzy:
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel,A. Gęsikiewicz-Puchalska, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1070602.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
The aim of the investigations was a modification of DTO, a commercial activated carbon (AC), to improve CO₂ adsorption capacity. The adsorption of CO₂ up to 40 bar at 40°C temperature was investigated. The volumetric method was applied for CO₂ adsorption isotherm measurements. The starting material - DTO - was modified using chemical activation (KOH, ZnCl₂, K₂CO₃). The textural parameters of all the ACs were determined by nitrogen adsorption at the liquid nitrogen temperature of -196°C on Quadrasorb SI. Results showed that the AC modified with KOH had the highest S_{BET}, V_{tot}, V_{mic} values of 2063 m²/g, 1.13 cm³/g, and 0.67 cm³/g, respectively. ACs with a wider pore size distribution (from micropores to mesopores) were obtained. The maximum CO₂ adsorption was equal to 14.44 mmol/g for DTO/KOH - modified carbon whereas 8.07 mmol/g of CO₂ was adsorbed at DTO. The CO₂ adsorption capacities of the ACs were found to be closely correlated with the BET surface areas of the materials tested. The experimental data was fitted to the Freundlich, Langmuir, Sips and Toth equations to determine the model isotherm. The Sips model was found to be the best for fitting the adsorption of CO₂.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 394-401
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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