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Wyszukujesz frazę "Fe(III)" wg kryterium: Wszystkie pola


Wyświetlanie 1-3 z 3
Tytuł:
Experimental Evidence for Jahn-Teller Transition in a Fe(II)Fe(III) Bimetallic Oxalate
Autorzy:
Tang, G.
He, Y.
Xu, F.
Zhang, Q.
Powiązania:
https://bibliotekanauki.pl/articles/1400401.pdf
Data publikacji:
2013-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Xx
76.80.+y
Opis:
Bimetallic oxalate ${[N-(n-C_4H_9)_4][FeFe(C_2O_4)_3]}_{n}$ has been investigated by the Mössbauer spectroscopy. The Mössbauer studies confirm that high-spin Fe(III) (S=5/2) and Fe(II) (S=2) ions are present in the compound. These spectra above 60 K consist of three quadrupole doublets, indicating that there are three different Fe sites in the material. The Mössbauer results reveal that spontaneous magnetization of Fe(II) sublattices increases more steeply than that of Fe(III) sublattices as the temperature decreases from $T_{C}$. Great increase of quadrupole splitting at 50 K provides compelling evidence for the predicted Jahn-Teller transition.
Źródło:
Acta Physica Polonica A; 2013, 123, 1; 118-120
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Binding of the Trace Elements: Cu(II) and Fe(III) to the Native and Modified Nutritive Potato Starches Studied by EPR
Autorzy:
Śmigielska, H.
Lewandowicz, G.
Goslar, J.
Hoffmann, S. K.
Powiązania:
https://bibliotekanauki.pl/articles/2043599.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
87.15.-v
Opis:
The Cu(II) and Fe(III) ions have been adsorbed by four potato starches of different degrees of oxidation (different numbers of COOH groups replacing host CH$\text{}_{2}$OH groups): native (no oxidized), white (pudding) with oxidation degree of 0.04%, gelating (0.1%), and LUBOX starch (0.5%). Concentration of the ions in starches was determined from atomic absorption and EPR spectrum intensity. For small concentration of the adsorbed ions (below 4 mg/g) nearly all ions are adsorbed from the solution. EPR shows that adsorbed copper(II) ions are chemically bonded to the starch molecules (preferably) at COOH sites and uniformly dispersed in the starch structure. The complexes are typical of octahedral or square-quadratic coordination with spin-Hamiltonian parameters g$\text{}_{ǁ}$=2.373, g$\text{}_{⊥}$= 2.080, A$\text{}_{ǁ}$=12.1 mT, A$\text{}_{⊥}$=1.0 mT. For higher concentrations the Cu(II) displays a tendency to clustering. Iron(III) ions are introduced into starch in a form of clusters mainly, even for the smallest concentration. The highest concentrations of both Cu(II) and Fe(III) were observed in LUBOX starch having the highest degree of oxidation.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 303-310
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Time-Resolved Pump-Probe Diffraction Experiment at SOLEIL Synchrotron: Photoinduced Spin Transition in the Molecular Crystal [TPA Fe(III) TCC] $PF_6$
Autorzy:
Laulhé, C.
Ravy, S.
Fertey, P.
Elkaim, E.
Legrand, F.
Féret, P.
Hollander, Ph.
Hustache, S.
Bordessoule, M.
Ricaud, J.
Collet, E.
Lorenc, M.
Buron-Le Cointe, M.
Cailleau, H.
Tissot, A.
Boillot, M.
Powiązania:
https://bibliotekanauki.pl/articles/1489972.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.Ks
61.05.cp
31.70.Ks
78.47.J-
Opis:
We present the first time-resolved pump-probe experiment performed at synchrotron SOLEIL at the CRISTAL diffraction beamline. The time-resolved setup will be used in the near future for sub-ns time resolution experiments. We studied spin state switching in a [TPA Fe(III) TCC] $PF_6$ single crystal as induced by a ≈6 ns laser pulse (1064 nm), by measuring the 3D diffraction volume of the 002 Bragg reflection as a function of time after excitation. The intensity profiles (rocking curves) are found to evolve at two characteristic timescales, namely hundreds of ns and few μs, exhibiting subtle profile changes and peak broadenings. Consistently with previous studies, we interpret these features as due to structural inhomogeneities related to laser-induced deformation wave propagation and heat diffusion, which both start from the absorbing sites.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 332-335
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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