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Wyświetlanie 1-4 z 4
Tytuł:
High-resolution Campanian-Maastrichtian carbon and oxygen stable isotopes of bulk-rock and skeletal components: palaeoceanographic and palaeoenviron-mental implications for the Boreal shelf sea
Autorzy:
Wilmsen, M.
Niebuhr, B.
Powiązania:
https://bibliotekanauki.pl/articles/139424.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Cretaceous
northern Germany
stable isotopes
low-magnesium calcite
palaeoceanography
kreda
Niemcy Północne
izotopy stabilne
kalcyt
paleoceanografia
Opis:
A high-resolution latest Early Campanian to Early Maastrichtian carbon and oxygen stable isotope record from the northern German Boreal shelf sea based on 537 analyses of co-occurring belemnites, brachiopods, inoceramids, oysters, and bulk rock samples is presented. All samples are precisely related to their stratigraphic, systematic and facies backgrounds and form an integrated, nearly 10-myr-long dataset with considerable palaeoenvironmental and palaeoceanographical implications. Petrographic studies indicate that low-magnesium calcitic coccoliths and calcispheres (i.e., planktic carbonate) predominate the bulk-rock data (marl-limestone rhythmites and chalks), thus representing a sea-surface water signal, and that only minor diagenetic alteration of the carbonate muds took place. Based on TL and CL microscopy, the investigated belemnites are extraordinarily well preserved, which may in part be explained by their early diagenetic surficial silicification (container effect), while the other macroinvertebrate groups are all less well preserved. The (plankton-dominated) δ13C values of the marl-limestone rhythmites and chalks (+1.1 to +2.5‰), recording a surface water signal, compare well with the δ13C data of inoceramids while δ13C brach.values (+1.5 to +3.0‰) are heavier than the bulk rock data. The large variation in the δ13Cbel. (-0.1 to +3.6‰) is attributed to isotopic disequilibrium of the biogenic carbonate formed by the belemnite animal. The bulk rock δ18O values show a remarkable low scatter, supporting petrographic observation of only minor diagenetic stabilisation/cementation, and can be approximated with northern German shelf sea-surface temperatures of ca. 20°C for the Late Campanian (ca. -2‰ δ18O), being slightly cooler during the Early Maastrichtian. The δ18O values of the belemnite rostra are even less variable and quite rich in heavier 18O (-0.7 to +0.6 with a mean of -0.1‰ δ18Obel.) in comparison to bulk rock and other skeletal components. Based on their excellent microstructural preservation and non-luminescence, we conclude that the belemnite rostra are diagenetically unaltered and have preserved the primary δ18O signal of ambient seawater (12±2°C). In the absence of any indication for migration from cooler water masses and evidence for authochtonous populations we assume that the belemnites of the genera Belemnitella and Belemnella lived as nektobenthos near the sea-floor and thus record the temperature of the bottom mixed layer of the seasonally weakly stratified north German shelf sea at water depths of 100 to 150 m; the temperature gradient was thus 12.5–18.75 m/1°C. A conspicuous latest Campanian cooling event is evident in both sea-surface and bottom-water temperatures. The δ18O values of nearly all investigated benthic fossils lie between the isotope values of pristine belemnites and bulk rock, and, therefore, should be used for palaeotemperature reconstructions only with great care.
Źródło:
Acta Geologica Polonica; 2017, 67, 1; 47-74
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemical and stable isotope patterns of calcite cementation in the Upper Cretaceous Chalk, UK: Direct evidence from calcite-filled vugs in brachiopods
Autorzy:
Hu, X.
Jeans, C.
Dickson, T.
Powiązania:
https://bibliotekanauki.pl/articles/139259.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
cement kalcytowy
diageneza
historia
izotopy stabilne
kreda
pierwiastki śladowe
wpływ drobnoustrojów
anoxia
calcite cement
chalk
diagenesis
history
Microbial influence
oxia
stable isotopes
suboxia
trace elements
Opis:
The history of research into the cementation of the Upper Cretaceous Chalk of the UK is reviewed. Calcite-filled vugs within the shell cavities of terebratulid brachiopods from the Cenomanian Chalk of eastern england have been investigated by cathodoluminesence imaging, staining, electron microprobe and stable isotope analysis. This has provided the first detailed analysis of the geochemistry of the Chalk.s cement. two cement series, suboxic and anoxic, are recognized. Both start with a Mg-rich calcite with positive [delta^13]C values considered to have been precipitated under oxic conditions influenced by aerobic ammonification. The suboxic series is characterized by positive [delta^13]C values that became increasingly so as cementation progressed, reaching values of 3.5[per mil]. Manganese is the dominant trace element in the earlier cement, iron in the later cement. Mn-and Fe-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. The anoxic series is characterized by [delta^13]C values that became increasingly negative as cementation progressed, reaching values of .6.5[per mil]. Trace elements are dominated by iron and manganese. Sulphate-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. Both cement series are related closely to lithofacies and early lithification pre-dating the regional hardening of the Chalk. The suboxic series occurs in chalk which was continuously deposited and contained hematite pigment and limited organic matter. The anoxic series was associated with slow to nil deposition and hardground development inc halks that originally contained hematite pigment but no longer do so, and an enhanced supply of organic matter.
Źródło:
Acta Geologica Polonica; 2012, 62, 2; 143-172
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin and significance of early-diagenetic calcite concretions and barite from Silurian black shales in the East European Craton, Poland
Autorzy:
Bojanowski, Maciej J.
Kędzior, Artur
Porębski, Szczepan J.
Radzikowska, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/138638.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
carbonate concretions
stable isotopes
cathodoluminoscopy
sedimentation rate
marine productivity
biogenic gas production
bacterial sulfate reduction
shale gas
konkrecje węglanowe
izotopy stabilne
katodoluminoskopia
szybkość sedymentacji
produktywność morska
gaz biogenny
redukcja bakteryjna siarczanu
gaz łupkowy
Opis:
The Silurian Pelplin Formation is a part of a thick, mud-prone distal fill of the Caledonian foredeep, which stretches along the western margin of the East European Craton. The Pelplin Formation consists of organic carbon-rich mudstones that have recently been the target of intensive investigations, as they represent a potential source of shale gas. The Pelplin mudstones host numerous calcite concretions containing authigenic pyrite and barite. Mineralogical and petrographic examination (XRD, optical microscopy, cathodoluminoscopy, SEM-EDS) and stable isotope analyses (δ13Corg, δ13C and δ18O of carbonates, δ34S and δ18O of barite) were carried out in order to understand the diagenetic conditions that led to precipitation of this carbonate-sulfide-sulfate paragenesis and to see if the concretions can enhance the understanding of sedimentary settings in the Baltic and Lublin basins during the Silurian. Barite formed during early diagenesis before and during the concretionary growth due to a deceleration of sedimentation during increased primary productivity. The main stages of concretionary growth took place in yet uncompacted sediments shortly after their deposition in the sulfate reduction zone. This precompactional cementation led to preferential preservation of original sedimentary structures, faunal assemblages and earlydiagenetic barite, which have been mostly lost in the surrounding mudstones during burial. These components allowed for the reconstruction of important paleoenvironmental conditions in the Baltic and Lublin basins, such as depth, proximity to the detrital orogenic source and marine primary productivity. Investigation of the concretions also enabled estimation of the magnitude of mechanical compaction of the mudstones and calculation of original sedimentation rates. Moreover, it showed that biogenic methane was produced at an earlydiagenetic stage, whereas thermogenic hydrocarbons migrated through the Pelplin Formation during deep burial.
Źródło:
Acta Geologica Polonica; 2019, 69, 3; 403-430
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inter- and intra-specific variability in δ13C and δ18O values of freshwater gastropod shells from Lake Lednica, western Poland
Autorzy:
Apolinarska, K.
Pełechaty, M.
Powiązania:
https://bibliotekanauki.pl/articles/139408.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
C stable isotopes
O stable isotopes
recent gastropod shells
freshwater
inter-specific differences
intraspecific variability
lake Lednica
izotopy stabilne
izotopy węgla
izotopy tlenu
muszle ślimaków
słodkowodne
różnice międzygatunkowe
zmienność wewnątrzgatunkowa
jezioro Lednickie
Opis:
This study focuses on the inter- and intra-specific variability in δ13C and δ18O values of shells and opercula of gastropods sampled live from the littoral zone of Lake Lednica, western Poland. The δ13C and δ18O values were measured in individual opercula of Bithynia tentaculata and in shells of Bithynia tentaculata, Gyraulus albus, Gyraulus crista, Lymnaea sp., Physa fontinalis, Radix auricularia, Theodoxus fluviatilis and Valvata cristata. The gastropods selected for the study are among the species most commonly found in European Quaternary lacustrine sediments. The carbon isotope composition of the gastropod shells was species-specific and the same order of species from the most to the least 13C-depleted was observed at all sites sampled. Differences in shell δ13C values between species were similar at all sampling sites, thus the factors influencing shell isotopic composition were interpreted as species-specific. The δ18O values of shells were similar in all the species investigated. Significant intra-specific variability in shell δ13C and δ18O values was observed not only within the populations of Lake Lednica, which can be explained by heterogeneity of δ13C DIC, δ18O water and water temperature between the sites where macrophytes with snails attached were sampled, but also between individuals sampled from restricted areas of the lake’s bottom. The latter points to the importance of factors related to the ontogeny of individual gastropods.
Źródło:
Acta Geologica Polonica; 2017, 67, 3; 441-458
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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