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Wyszukujesz frazę "optymalna temperatura" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
Determination of optimum temperatures and activationenergies of inulin hydrolysis by endo-inulinase Aspergillus Niger
Autorzy:
Miłek, Justyna
Powiązania:
https://bibliotekanauki.pl/articles/185420.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
endo-inulinase Aspergillus niger
optimum temperature
activation energy
deactivation energy
endo-inulinaza Aspergillus niger
optymalna temperatura
energia aktywacji
energia dezaktywacji
Opis:
The paper presents a comparative analysis to determine the optimal temperatures and the activationenergies for various origin endo-inulinases fromAspergillus niger. The parameters were estimatedbased on the literature of the activity curves vs. temperature for hydrolysis of inulin. It was assumedthat both the hydrolysis reaction process and the deactivation process of endo-inulinase were first-orderreactions by the enzyme concentration. A mathematical model describing the effect of temperature onendo-inulinases fromAspergillus nigeractivity was used. Based on the comparison analysis, valuesof the activation energies Ea were in the range from23:53+/-3:20kJ/mol to50:66+/-3:61kJ/mol, thedeactivation energies Ed were in the range from88:42+/-5:03kJ/mol to142:87+/-2:75kJ/mol andthe optimum temperatures Topt were obtained in the range from317:12+/-0:83K to332:55+/-0:72forendo-inulinase A. niger.
Źródło:
Chemical and Process Engineering; 2020, 41, 3; 229--236
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimal feed temperature for hydrogen peroxide decomposition process occurring in a bioreactor with fixed-bed of commercial catalase: a case study on thermal deactivation of the enzyme
Autorzy:
Grubecki, I.
Powiązania:
https://bibliotekanauki.pl/articles/185125.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
fixed-bed (bio)reactor
hydrogen peroxide decomposition
optimal feed temperature
hydrogen
peroxide conversion
parallel and thermal enzyme deactivation
diffusional resistances
reaktor z nieruchomym złożem
optymalna temperatura zasilania
wodór
konwersja nadtlenku
opory dyfuzyjne
Opis:
On the basis of hydrogen peroxide decomposition process occurring in the bioreactor with fixed-bed of commercial catalase the optimal feed temperature was determined. This feed temperature was obtained by maximizing the time-average substrate conversion under constant feed flow rate and temperature constraints. In calculations, convection-diffusion-reaction immobilized enzyme fixed-bed bioreactor described by a coupled mass and energy balances as well as general kinetic equation for rate of enzyme deactivation was taken into consideration. This model is based on kinetic, hydrodynamic and mass-transfer parameters estimated in earlier work. The simulation showed that in the biotransformation with thermal deactivation of catalase optimal feed temperature is only affected by kinetic parameters for enzyme deactivation and decreases with increasing value of activation energy for deactivation. When catalase undergoes parallel deactivation the optimal feed temperature is strongly dependent on hydrogen peroxide feed concentration, feed flow rate and diffusional resistances expressed by biocatalyst effectiveness factor. It has been shown that the more significant diffusional resistances and the higher hydrogen peroxide conversions, the higher the optimal feed temperature is expected.
Źródło:
Chemical and Process Engineering; 2018, 39, 4; 491--501
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimal feed temperature for an immobilized enzyme fixed-bed reactor: a case study on hydrogen peroxide decomposition by commercial catalase
Autorzy:
Grubecki, I.
Powiązania:
https://bibliotekanauki.pl/articles/185291.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
optimal feed temperature
maximum hydrogen peroxide conversion
parallel deactivation
immobilized commercial catalase
diffusional resistances
fixed-bed reactor
optymalna temperatura zasilania
maksymalna konwersja nadtlenku wodoru
dezaktywacja równoległa
unieruchomiona komercyjna katalaza
opory dyfuzyjne
reaktor z nieruchomym złożem
Opis:
Optimal feed temperature was determined for a non-isothermal fixed-bed reactor performing hydrogen peroxide decomposition by immobilized Terminox Ultra catalase. This feed temperature was obtained by maximizing the average substrate conversion under constant feed flow rate and temperature constraints. In calculations, convection-diffusion-reaction immobilized enzyme fixed-bed reactor described by a set of partial differential equations was taken into account. It was based on kinetic, hydrodynamic and mass transfer parameters previously obtained in the process of H2O2 decomposition. The simulation showed the optimal feed temperature to be strongly dependent on hydrogen peroxide concentration, feed flow rate and diffusional resistances expressed by biocatalyst effectiveness factor.
Źródło:
Chemical and Process Engineering; 2018, 39, 1; 39--57
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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