- Tytuł:
- Acoustical Spectroscopy of Carbohydrate Aqueous Solutions: Saccharides; Alkyl Glycosides; Cyclodextrins. Part I. Conformer Variations
- Autorzy:
- Kaatze, U.
- Powiązania:
- https://bibliotekanauki.pl/articles/177869.pdf
- Data publikacji:
- 2010
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
acoustical spectroscopy
non-equilibrium spectroscopy
carbohydrate solutions - Opis:
- Acoustical attenuation spectra in the frequency range 12 kHz – 2 GHz and nonequilibrium time domain measurements are briefly reviewed for aqueous solutions of various mono- and disaccharides as well as alkyl glycosides. Several relaxation regimes emerge with relaxation times between 10^-11 s and 10^3 s. In this paper relaxation terms reflecting conformational changes are discussed, particularly mutarotation (10^3 s), chair-chair ring inversion (1 ąs), two modes of pseudorotation (100 ns, 10 ns), disaccharide ring isomerisation (10 ns), and exocyclic side group rotation (1 ns).
- Źródło:
-
Archives of Acoustics; 2010, 35, 4; 715-738
0137-5075 - Pojawia się w:
- Archives of Acoustics
- Dostawca treści:
- Biblioteka Nauki
Artykuł