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Wyszukujesz frazę "calcite" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
High-resolution Campanian-Maastrichtian carbon and oxygen stable isotopes of bulk-rock and skeletal components: palaeoceanographic and palaeoenviron-mental implications for the Boreal shelf sea
Autorzy:
Wilmsen, M.
Niebuhr, B.
Powiązania:
https://bibliotekanauki.pl/articles/139424.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Cretaceous
northern Germany
stable isotopes
low-magnesium calcite
palaeoceanography
kreda
Niemcy Północne
izotopy stabilne
kalcyt
paleoceanografia
Opis:
A high-resolution latest Early Campanian to Early Maastrichtian carbon and oxygen stable isotope record from the northern German Boreal shelf sea based on 537 analyses of co-occurring belemnites, brachiopods, inoceramids, oysters, and bulk rock samples is presented. All samples are precisely related to their stratigraphic, systematic and facies backgrounds and form an integrated, nearly 10-myr-long dataset with considerable palaeoenvironmental and palaeoceanographical implications. Petrographic studies indicate that low-magnesium calcitic coccoliths and calcispheres (i.e., planktic carbonate) predominate the bulk-rock data (marl-limestone rhythmites and chalks), thus representing a sea-surface water signal, and that only minor diagenetic alteration of the carbonate muds took place. Based on TL and CL microscopy, the investigated belemnites are extraordinarily well preserved, which may in part be explained by their early diagenetic surficial silicification (container effect), while the other macroinvertebrate groups are all less well preserved. The (plankton-dominated) δ13C values of the marl-limestone rhythmites and chalks (+1.1 to +2.5‰), recording a surface water signal, compare well with the δ13C data of inoceramids while δ13C brach.values (+1.5 to +3.0‰) are heavier than the bulk rock data. The large variation in the δ13Cbel. (-0.1 to +3.6‰) is attributed to isotopic disequilibrium of the biogenic carbonate formed by the belemnite animal. The bulk rock δ18O values show a remarkable low scatter, supporting petrographic observation of only minor diagenetic stabilisation/cementation, and can be approximated with northern German shelf sea-surface temperatures of ca. 20°C for the Late Campanian (ca. -2‰ δ18O), being slightly cooler during the Early Maastrichtian. The δ18O values of the belemnite rostra are even less variable and quite rich in heavier 18O (-0.7 to +0.6 with a mean of -0.1‰ δ18Obel.) in comparison to bulk rock and other skeletal components. Based on their excellent microstructural preservation and non-luminescence, we conclude that the belemnite rostra are diagenetically unaltered and have preserved the primary δ18O signal of ambient seawater (12±2°C). In the absence of any indication for migration from cooler water masses and evidence for authochtonous populations we assume that the belemnites of the genera Belemnitella and Belemnella lived as nektobenthos near the sea-floor and thus record the temperature of the bottom mixed layer of the seasonally weakly stratified north German shelf sea at water depths of 100 to 150 m; the temperature gradient was thus 12.5–18.75 m/1°C. A conspicuous latest Campanian cooling event is evident in both sea-surface and bottom-water temperatures. The δ18O values of nearly all investigated benthic fossils lie between the isotope values of pristine belemnites and bulk rock, and, therefore, should be used for palaeotemperature reconstructions only with great care.
Źródło:
Acta Geologica Polonica; 2017, 67, 1; 47-74
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calcite cements and the stratigraphical significance of the marine [delta^13]C carbonate reference curve for the Upper Cretaceous Chalk of England
Autorzy:
Jeans, C.
Hu, X.
Mortimore, R.
Powiązania:
https://bibliotekanauki.pl/articles/139078.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
cement kalcytowy
chemostratygrafia
izotopy
korelacja
kreda
krzywa referencyjna
ograniczenia
calcite cement
chemostratigraphy
correlation
Cretaceous
[delta^13]C reference curve
isotope events
limitations
Opis:
The hypothesis of Jarvis et al. (2006) that a [delta^13]C (calcite) reference curve based upon bulk samples from the Upper Cretaceous Chalk of England can be used as a primary criterion for trans-continental correlation is reviewed in the light of new stable isotope data from the Upper Albian and Cenomanian chalks of eastern England and from the Cenomanian to Campanian chalks of southern England. Evidence demonstrates that in the coloured chalks of eastern England the cements invariably have positive [delta^13]C values (up to 3.5[per mil]) except where they have been affected by hardground development when the cements have negative [delta^13]C values down to -6.5[per mil]. in contrast, the White Chalk of southern England may have cements with [delta^13]C values as negative as -8[per mil]. Modelling indicates that the coloured chalks may preserve a truer record of the primary palaeo-oceanographic [delta^13]C signal than the white and grey chalks of southern England. it is suggested that (1) many of the 72 isotope events described from the [delta^13]C (calcite) reference curve and proposed for correlation may reflect the effects of variations in the type and extent of calcite cementation; and (2) until much more is known about the patterns of calcite cementation in the Upper Cretaceous Chalk the use of minor isotope events for trans-continental stratigraphic correlation can only be applied with the utmost caution.
Źródło:
Acta Geologica Polonica; 2012, 62, 2; 173-196
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemical and stable isotope patterns of calcite cementation in the Upper Cretaceous Chalk, UK: Direct evidence from calcite-filled vugs in brachiopods
Autorzy:
Hu, X.
Jeans, C.
Dickson, T.
Powiązania:
https://bibliotekanauki.pl/articles/139259.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
cement kalcytowy
diageneza
historia
izotopy stabilne
kreda
pierwiastki śladowe
wpływ drobnoustrojów
anoxia
calcite cement
chalk
diagenesis
history
Microbial influence
oxia
stable isotopes
suboxia
trace elements
Opis:
The history of research into the cementation of the Upper Cretaceous Chalk of the UK is reviewed. Calcite-filled vugs within the shell cavities of terebratulid brachiopods from the Cenomanian Chalk of eastern england have been investigated by cathodoluminesence imaging, staining, electron microprobe and stable isotope analysis. This has provided the first detailed analysis of the geochemistry of the Chalk.s cement. two cement series, suboxic and anoxic, are recognized. Both start with a Mg-rich calcite with positive [delta^13]C values considered to have been precipitated under oxic conditions influenced by aerobic ammonification. The suboxic series is characterized by positive [delta^13]C values that became increasingly so as cementation progressed, reaching values of 3.5[per mil]. Manganese is the dominant trace element in the earlier cement, iron in the later cement. Mn-and Fe-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. The anoxic series is characterized by [delta^13]C values that became increasingly negative as cementation progressed, reaching values of .6.5[per mil]. Trace elements are dominated by iron and manganese. Sulphate-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. Both cement series are related closely to lithofacies and early lithification pre-dating the regional hardening of the Chalk. The suboxic series occurs in chalk which was continuously deposited and contained hematite pigment and limited organic matter. The anoxic series was associated with slow to nil deposition and hardground development inc halks that originally contained hematite pigment but no longer do so, and an enhanced supply of organic matter.
Źródło:
Acta Geologica Polonica; 2012, 62, 2; 143-172
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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