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    Wyświetlanie 1-3 z 3
    Tytuł:
    Bench life (work time) of moulding and core sands with chemical binders – a new, ultrasound investigation method
    Autorzy:
    Zych, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/381341.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    bench life
    ultrasound
    binding sand
    moulding sand
    investigation method
    ultradźwięk
    materiał wiążący
    masa formierska
    metoda badawcza
    Opis:
    The obtained results of the investigations of influences of the selected technological factors on the bench life (work time) of moulding and core sands with chemical binders are presented in the hereby paper. The bench life assessment is performed by the new, author’s method with the application of the ultrasound technique. This method was patented by the author. The influence of such factors as: matrix (surroundings) temperature, matrix water content, ratio of binding components hardener/binder (h/b) and the reclamation – on the bench life of furan moulding sands was determined. The empirical dependencies (regressions) were determined, which allowed forecasting the bench life (BL) of moulding sands as functions: BL = f(W%), BL = f(T) for the fresh and after the reclamation sands, BL = f(h/b). These dependencies should be treated as examples of the new method application for investigating the bench life of moulding sands with chemical binders.
    Źródło:
    Archives of Foundry Engineering; 2013, 13, 4; 117-122
    1897-3310
    2299-2944
    Pojawia się w:
    Archives of Foundry Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Assessment of the Harmfulness of Moulding Sands with Alkyd Resin Subjected to the High Temperature Influence
    Autorzy:
    Holtzer, M.
    Dańko, R.
    Żymankowska-Kumon, S.
    Kubecki, M.
    Bobrowski, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/354778.pdf
    Data publikacji:
    2016
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    moulding sand
    binding
    BTEX
    thermal analysis
    GC/MS
    Opis:
    Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. These resins in their initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin, under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAHs) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX and PAHs group. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 500 – 1 300°C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. The qualitative and quantitative analyses of compounds were performed by means of the gas chromatography coupled with the mass spectrometry (GC/MS).
    Źródło:
    Archives of Metallurgy and Materials; 2016, 61, 4; 2171-2176
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analysis of the compounds from the BTEX group, emitted during thermal decomposition of alkyd resin
    Autorzy:
    Kubecki, M.
    Holtzer, M.
    Bobrowski, A.
    Dańko, R.
    Grabowska, B.
    Żymankowska-Kumon, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/380216.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    masa formierska
    wiązanie
    BTEX
    analiza termiczna
    GC-MS
    moulding sand
    binding
    thermal analysis
    Opis:
    Suitability of the given binding agent for the moulding sands preparation depends on the one hand on the estimation of technological properties of the sand and the mould made of it and the obtained casting quality and on the other hand on the assessment of this sand influence on the natural and working environment. Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. If in the initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin (phenol-formaldehyde, urea, furfuryl, urea-furfuryl, alkyd) under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAH) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX group. An emission of these components constitutes one of the basic criteria of the harmfulness assessment of binders applied for moulding and core sands. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 5000C - 13000C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. Within investigations the minimal amount of adsorbent necessary for the adsorption of compounds released during the decomposition of the resin sample of a mass app. 15 mg was selected. Also the minimal amount of solvent needed for the desorption of compounds adsorbed in the column with adsorbent was found. The temperature range, in which the maximal amounts of benzene, toluene, ethylobenzene and xylenes are released from the resin, was defined. The qualitative and quantitative analyses of compounds from the BTEX group were performed by means of the gas chromatography combined with the mass spectrometry (GC/MS).
    Źródło:
    Archives of Foundry Engineering; 2012, 12, 3; 69-74
    1897-3310
    2299-2944
    Pojawia się w:
    Archives of Foundry Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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