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Wyszukujesz frazę "microstructure" wg kryterium: Wszystkie pola


Tytuł:
LMO Ceramics Microstructure
Autorzy:
Bruś, B.
Zarycka, A.
Powiązania:
https://bibliotekanauki.pl/articles/350959.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
LMO
microstructure
hot pressing
free sintering
Opis:
The aim of this work was to characterize the microstructure of LMO type ceramics. The ceramics obtained by the free sintering at two temperatures 1473 K and 1573 K and two sintering times 6 and 12 h was the test material. One series was also obtained by the hot pressing method for a comparison. In all the cases the material synthesis was conducted by the solid-state reaction method at 1173 for 24 h. Photographs of the specimen fractures were taken by a scanning electron microscope to characterize the microstructure of the ceramics obtained in a more detailed way. The VISILOG 4 system, enabling to calculate a lot of parameters characterizing the material microstructure, such as e.g.: a number of grains on the unit area, an average grain size, shape indexes of the grains in question, was used as well. It allows determining a grain size distribution, and a frequency of presence of grains with the specific shape index. By analyzing a set of the parameters obtained an influence of the technological conditions on the microstructure of the material in question, and on its properties and applicability at the same time can be determined.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 857-862
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prediction of Microstructure in ADI Castings
Autorzy:
Guzik, E.
Sokolnicki, M.
Królikowski, M.
Ronduda, M.
Nowak, A.
Powiązania:
https://bibliotekanauki.pl/articles/353713.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
prediction of microstructure
ADI castings
results of the ADI microstructure examinations
Opis:
Tests were carried out on samples of low-alloy ductile iron with additions of Ni, Cu and Mo, subjected to austempering heat treatment. The samples were austenitized at 850, 900 and 950 °C, and then austempered at T = 210, 240, 270, 300 and 330 °C. The ausferritizing treatment was carried out in a salt bath for the time τ = 2 - 8 hours. Additionally, tests and studies covered samples subjected to the ausferritizing treatment at 270 °C with the time of holding castings in a bath from 2 to 24 hours. Evaluation covered the results of the ADI microstructure examinations and hardness measurements. The ADI matrix morphology was identified counting the average number of ausferrite plates and measuring their width and spacing. The regression equations HB = f (τ, T) and τ = f (HB, T) were derived to establish the, so-called, “process window”, allowing obtaining a priori the required microstructure of ADI and, consequently, the required mechanical properties, mainly hardness, shaping the functional properties of castings, abrasion wear resistance – in particular.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 4; 2159-2164
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure Control of High-alloyed White Cast Iron
Autorzy:
Kawalec, M.
Powiązania:
https://bibliotekanauki.pl/articles/382878.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
white cast iron
microstructure
vanadium carbide
mechanical properties
microstructure modification
żeliwo białe
mikrostruktury
węglik wanadu
właściwości mechaniczne
modyfikacja mikrostruktury
Opis:
This paper presents the results of studies of high-alloyed white cast iron modified with lanthanum, titanium, and aluminium-strontium. The samples were taken from four melts of high-vanadium cast iron with constant carbon and vanadium content and near-eutectic microstructure into which the tested inoculants were introduced in an amount of 1 wt% respective of the charge weight. The study included a metallographic examinations, mechanical testing, as well as hardness and impact resistance measurements taken on the obtained alloys. Studies have shown that different additives affect both the microstructure and mechanical properties of high-vanadium cast iron.
Źródło:
Archives of Foundry Engineering; 2014, 14, 1; 49-54
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of dynamic compression on the evolution of microstructure in aluminium and its alloys
Wpływ dynamicznego ściskania na mikrostrukturę aluminium i jego stopów
Autorzy:
Leszczyńska-Madej, B.
Richert, M.
Powiązania:
https://bibliotekanauki.pl/articles/352301.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
aluminium alloys
microstructure
ultrafine-grained microstructure
nanocrystalline microstructure
transmission electron microscopy TEM
stopy aluminium
mikrostruktura
mikrostruktura drobnoziarnista
mikrostruktura nanokrystaliczna
transmisyjny mikroskop elektronowy
Opis:
In the work, the microstructure and selected properties of aluminium and its alloys (AlCu4Zr0.5, AlMg5, AlZn6Mg2.5CuZr) deformed with high strain rate were investigated. The cylindrical samples were compressed by a falling - weight-type impact-testing machine at the strain rate ranging from 1.77-6.06x102 s-1 in order to attain true strains between Φ = 0 - 0.62. After compression, the microhardness of the samples was tested and the microstructure was examined by means of both optical (LM) and transmission electron microscopy (TEM). Additionally the misorientation of selected microstructural elements using proprietary KILIN software was determined. The large density of shear bands, bands and microbands was the characteristic feature of the microstructure. The statistical width of the microbands observed in the microstructure was calculated using the mean chord method. The obtained data demonstrate reduction of the microbands width with the increase of deformation. The main object of investigations concerns the microstructure elements refinement affected by dynamic compression.
W pracy przedstawiono wyniki badań mikrostruktury i wybranych właściwości polikrystalicznego aluminium i jego stopów: AlMg5, AlCu4Zr0.5, AlZn6Mg2.5CuZr ściskanych dynamicznie za pomocą młota spadowego. Próbki odkształcano w zakresie odkształceń rzeczywistych Φ = 0-0.62 z prędkością odkształcenia z zakresu 1.77-6.06x102 s-1. Na tak odkształconych materiałach przeprowadzono pomiar mikrotwardości oraz badania mikrostruktury przy zastosowaniu transmisyjnego mikroskopu elektronowego (TEM) i mikroskopu świetlnego (LM), dodatkowo przeprowadzono pomiar dezorientacji w mikroobszarach metodą linii Kikuchiego przy zastosowaniu oprogramowania KILIN. Cechą charakterystyczną mikrostruktury badanych materiałów były licznie obserwowane pasma i pasma ścinania. Wyniki uzyskane przy zastosowaniu transmisyjnego mikroskopu elektronowego dowiodły występowania licznych mikropasm i mikropasm ścinania, które w zależności od materiału przebiegały na tle różnych układów dyslokacyjnych. Obserwowane mikropasma wykazywały dużą dezorientację względem osnowy. Stwierdzono wzajemnie przecinanie się mikropasm. W zakresie wyższych wartości odkształcenia, mikropasma wypełniały niemal całą objętość próbek. Zaobserwowano zależność zmniejszania się średniej szerokości i mikropasm wraz ze wzrostem wielkości odkształcenia i prędkości odkształcenia. Praca miała na celu określenie wpływu prędkości odkształcenia (1.77x101 - 6.06x102s-1) na możliwość rozdrobnienia mikrostruktury polikrystalicznego aluminium A199.5 i jego stopów (AlMg5, AlCu4Zr0.5, AlZn6Mg2.5CuZr) odkształcanych w procesie dynamicznego ściskania za pomocą młota spadowego.
Źródło:
Archives of Metallurgy and Materials; 2013, 58, 4; 1097-1103
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure of Hot-Deformed Cu-3Ti Alloy
Autorzy:
Szkliniarz, A.
Szkliniarz, W.
Blacha, L.
Siwiec, G.
Powiązania:
https://bibliotekanauki.pl/articles/352283.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper-titanium alloy
hot deformation
microstructure
recrystallization
Opis:
In the paper, results of investigations regarding temperature and strain rate effects on hot-deformed Cu-3Ti alloy microstructure are presented. Evaluation of the alloy microstructure was performed with the use of a Gleeble HDS-V40 thermal-mechanical simulator on samples subjected to uniaxial hot compression within 700 to 900ºC and at the strain rate of 0.1, 1.0 or 10.0 s-1 until 70% (1.2) strain. It was found that within the analyzed temperature and strain rate ranges, the alloy deformation led to partial or complete recrystallization of its structure and to multiple refinement of the initial grains. The recrystallization level and the average diameter of recrystallized grains increase with growing temperature and strain rate. It was shown that entirely recrystallized, fine-grained alloy structure could be obtained following deformation at the strain rate of min 10.0 s-1 and the temperature of 800°C or higher.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 347-352
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Heat Treatment on Mechanical Properties and Microstructure Morphology of Low-Alloy High-Strength Steel
Autorzy:
Bolanowski, K.
Powiązania:
https://bibliotekanauki.pl/articles/353874.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
microalloyed steel
mechanical properties
microstructure
Opis:
The paper analyzes the influence of different heat treatment processes on the mechanical properties of low-alloy high-strength steel denoted by Polish Standard (PN) as 10MnVNb6. One of the findings is that, after aging, the mechanical properties of rolled steel are high: the yield strength may reach > 600 MPa, and the ultimate tensile strength is > 700 MPa. These properties are largely dependent on the grain size and dispersion of the strengthening phase in the ferrite matrix. Aging applied after hot rolling contributes to a considerable rise in the yield strength and ultimate tensile strength. The process of normalization causes a decrease in the average grain size and coalescence (reduction of dispersion) of the strengthening phase. When 10MnVNb6 steel was aged after normalization, there was not a complete recovery in its strength properties.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 475-480
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure and properties of tin bronzes produced by the SPD method
Autorzy:
Sobota, J.
Rodak, K.
Nowak, M.
Powiązania:
https://bibliotekanauki.pl/articles/355126.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
tin bronzes
KOBO
microstructure
mechanical properties
corrosion
Opis:
In this article the structural and mechanical properties of grain refinement of Cu-Sn alloys with tin content of 10%, 15% and 20% using the KOBO method have been presented. The direct extrusion by KOBO (name from the combination of the first two letters of the names of its inventors – A. Korbel and W. Bochniak) method employs, during the course of the whole process, a phenomenon of permanent change of strain travel, realized by a periodical, two-sided, plastic metal torsion. Moreover the aim of this work was to study corrosion resistance. The microstructure investigations were performed using an optical microscope Olimpus GX71, a scanning electron microscope (SEM) and a scanning transmission electron microscope (STEM). The mechanical properties were determined with INSTRON 4505/5500 machine. Corrosion tests were performed using «Autolab» set – potentiostat/galvanostat from EcoChemie B.V. with GPES software ver. 4.9. The obtained results showed possibility of KOBO deformation of Cu-Sn casting alloys. KOBO processing contributed to the refinement of grains and improved mechanical properties of the alloys. The addition of tin significantly improved the hardness. Meanwhile, with the increase of tin content the tensile strength and yield strength of alloys decrease gradually. Ductility is controlled by eutectoid composition and especially δ phase, because they initiate nucleation of void at the particle/matrix interface. No significant differences in the corrosion resistance between cast and KOBO processed materials were found.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 1; 95-102
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure and Properties of Multifibre Composites
Autorzy:
Głuchowski, W.
Rdzawski, Z.
Domagała-Dubiel, J.
Sobota, J.
Powiązania:
https://bibliotekanauki.pl/articles/356505.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
fibrous composite
copper matrix
microstructure
mechanical properties
electrical properties
Opis:
In the study microstructure and properties of composite multifibre copper-base wires are presented. A decision was made to produce wires with “soft” fibres (Al) and “hard” fibres (Fe). In the study the phenomenon occurring on the border of Al-Cu was also analysed. The produced Cu-Al and Cu-Fe composites presented ordered microstructure with the fibres uniformly distributed in the copper matrix. The composites underwent plastic consolidation to the degree which provided satisfactory mechanical and electrical properties. During the drawing the fibres deformed proportionally with copper matrix therefore their content in the cross section remained unchanged.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2B; 911-916
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Microstructure of Oriented Eutectic Fe-C Alloy
Autorzy:
Trepczyńska-Łent, M.
Powiązania:
https://bibliotekanauki.pl/articles/381607.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
directional solidification
eutectic alloy
microstructure
longitudinal section
transverse section
krzepnięcie
stop eutektyczny
mikrostruktura
Opis:
Fe - 4,25% C alloy was directionally solidified with a constant temperature gradient of G = 33,5 K/mm and growth rate of v = 83,3 μm/s (300 mm/h) using a vacuum Bridgman-type crystal growing facility with liquid metal cooling technique. To reveal more detailed microstructure, the deep etching was made. This was obtained in the process of electrolytic dissolution. The microstructure of the sample was examined on the longitudinal and transverse sections using an Optical Microscope and Scanning Electron Microscope. Using the Electron Backscattered Diffraction technique, phase map and analysis of phase were made. In this paper the analysis of Fe-C alloy eutectic microstructure is presented. Regular eutectic structure was obtained. The fracture surfaces show lamellar structure. Microscopic observation after electrolytic extraction indicates that the grains of longitudinal shape of eutectic cementite have been obtained. These grains are characterized by layered construction with many rounded discontinuities.
Źródło:
Archives of Foundry Engineering; 2018, 18, 1; 123-128
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanical Properties and Microstructure of PM Mn-Cr-Mo Steels With Low Carbon Concentration
Autorzy:
Lichańska, E.
Sułkowski, A.
Ciaś, A.
Powiązania:
https://bibliotekanauki.pl/articles/352303.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
PM steels
microstructure
mechanical properties
Opis:
The effect of chemical composition of the sintering atmosphere on the microstructure and mechanical properties of PM structural low-carbon steels is presented. The base powders were Astaloy CrL, Astaloy CrM, low carbon ferromanganese and graphite C-UF. From the base powders two mixtures with compositions of Fe-3%Mn-(1.5/3%)Cr-(0.2/0.5)%Mo-0.2%C were prepared. Following pressing in a steel rigid die, compacts were sintered at 1250°C for 60 min in a semi-closed container. 5%H2-95%N2 mixture and air were the sintering atmospheres. For sintering in air, lumps of ferromanganese were placed with the compacts in the container. After sintering, half of the samples were tempered at 200°C for 60 minutes in air. Mechanical tests (tensile, bend, toughness, hardness) and microstructural investigations were performed. The microstructures of the steels were inhomogeneous, mainly ferritic-bainic. Tempering of steel based on Astaloy CrM sintered in an atmosphere of 5% H2-95% N2 slightly reduced tensile strength and toughness: from 748 to 734 MPa and from 7.15 to 6.83 J/cm2, respectively. Chemical composition had a greater effect; steels based on Astaloy CrL and Astaloy CrM had tensile strengths 526-665 and 672-748 MPa, hardness 280-325 and 388-421 HV, respectively. The best properties were obtained after sintering in air of Fe-3%Mn-3%Cr-0.5%Mo-0.2%C without heat treatment: tensile strength 672 MPa, toughness 6.93 J/cm2, hardness 421.1 HV, 0.2 % offset yield strength 395 MPa.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 109-114
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Formation of microstructure and properties of Cu-3Ti alloy in thermal and thermomechanical processes
Autorzy:
Szkliniarz, A.
Powiązania:
https://bibliotekanauki.pl/articles/355778.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper-titanium alloy
microstructure
thermal and thermomechanical processes
Opis:
This paper presents the possibilities of forming the microstructure as well as mechanical properties and electrical conductivity of Cu-3Ti alloy (wt.%) in thermal and thermomechanical processes that are a combination of homogenising treatment, hot and cold working, solution treatment and ageing. Phase composition of the alloy following various stages of processing it into the specified semi-finished product was being determined too. It was demonstrated that the application of cold plastic deformation between solution treatment and ageing could significantly enhance the effect of hardening of the Cu-3Ti alloy without deteriorating its electrical conductivity. It was found that for the investigated alloy the selection of appropriate conditions for homogenising treatment, hot and cold deformation as well as solution treatment and ageing enables to obtain the properties comparable to those of beryllium bronzes.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 223-230
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Variable Manganese Content on Microstructure of Al-Cu Alloys
Autorzy:
Stąpór, S.
Górny, M.
Kawalec, M.
Gracz, B.
Powiązania:
https://bibliotekanauki.pl/articles/355992.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Al-Cu-Mn alloys
microstructure
macrostructure
DSC
Opis:
The presented access the influence of Mn content (0-0.94 wt.%) on the course of the cooling curves, phase transformation, macrostructure, and microstructure of Al-Cu alloys for three series: initial (Series I), with the addition of an AlTi master (Series II), and modified with AlTi5B1 (Series III). The maximum degree of undercooling ΔT was determined based on the cooling curves. The surface density of the grains (NA ) was determined and associated with the inverse of solidification interval 1/ΔTk . Titanium (contained in the charge materials as well as the modifier) has a significant effect on the grinding of the primary grains in the tested alloys. A DSC thermal analysis allowed for the determination of phase transition temperatures under conditions close to equilibrium. For series II and III, the number of grains decreases above 0.2 wt.% Mn with a simultaneous increase in solidification interval 1/ΔT2 . The presence of Al2 Cu eutectics as well as the Cu-, Fe-, and Mn-containing phases in the examined samples was demonstrated using scanning electron microscopy.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 4; 1377-1383
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prediction of Microstructure of Grey Cast Irons by Electrical Resistivity Measurements
Autorzy:
Petrič, M.
Mrvar, P.
Kastelic, S.
Powiązania:
https://bibliotekanauki.pl/articles/354044.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solidification
grey cast iron
electrical resistivity
graphite shape
microstructure
Opis:
The paper describes the influence of graphite shape, size and amount to electrical properties of different cast irons. Experiments of electrical resistivity measurements were conducted during solidification of four different melts in different time intervals from melt treatment by inoculation and nodularization. Metallographic analyses were made in order to determine the shape, size, distribution and amount of graphite and correlate results with electrical resistivity measurements. It was found out that nodular graphite is giving the lowest electrical resistivity and is decreased during solidification. Electrical resistivity of lamellar cast iron is increased during solidification since lamellas interrupt metal matrix severely. There is no significant difference in resistivity of vermicular cast iron from nodular cast iron. Smaller size of graphite and lower amount of graphite and higher amount of metal matrix also decrease resistivity.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 1; 365-369
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure and Mechanical Properties of CrMoV Steel after Long-Term Service
Autorzy:
Golański, G.
Pietryka, I.
Słania, J.
Mroziński, S.
Jasak, J.
Powiązania:
https://bibliotekanauki.pl/articles/351929.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
microstructure
mechanical properties
long-term service
Opis:
The paper presents the results of research on the microstructure and mechanical properties of 12HMF steel after longterm service. The investigated material was taken from a pipeline with circumferential welded joint after 419 988 hours of service at the temperature of 490°C, steam pressure 8 MPa. Performed research has shown that the 12HMF steel after service was characterized by a typical microstructure for this grade of steel, that is a ferritic-bainitic microstructure without any visible advanced processes of its degradation. The investigation of mechanical properties has shown that the examined steel after service was characterized by a very low impact energy KV, and yield strength lower than the required minimum. Whilst tensile strength and yield strength determined at elevated temperature was higher and similar to the standard requirements, respectively. It has been proved that the main cause of an increase in brittleness and a decrease in yield strength of the examined steel should be seen in the segregation of phosphorus to grain boundaries and the formation of precipitate free zones near the boundaries.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 51-54
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of Structural Steel Containing 3÷5 wt% Al with Microlaminated Microstructure
Autorzy:
Garbarz, B.
Adamczyk, M.
Niżnik-Harańczyk, B.
Powiązania:
https://bibliotekanauki.pl/articles/351953.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high strength steel
alloying with aluminium
microlaminated microstructure
Opis:
The aim of this work was to develop basic parameters of hot rolling and controlled cooling technology allowing to obtain the microlaminated (lamellar) microstructure in a lean-alloy structural steel containing 3÷5 wt % Al. Thermo-mechanical rolling tests of two experimental steels were carried out in a semi-industrial line comprising a one – stand reversing rolling mill. The final microstructure of the specimens subjected to rolling in the γ + α stability region characterised with the microlaminated morphology composed of lamellae of ferrite with thickness down to 1 μm or less and lamellae or grains of phases developed during transformation of the austenite. Determined parameters of the thermo-mechanical processing allowed to achieve very attractive mechanical properties of the experimental steels: tensile strength over 1.0 GPa and ductility level (total elongation) better than 15%.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 4; 2309-2315
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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