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Wyświetlanie 1-3 z 3
Tytuł:
Sensitivity change of the modified carbon paste electrodes for detection of chlorinated phenoxyacetic acids
Autorzy:
Białek, Arkadiusz
Skrzypczyńska, Katarzyna
Kuśmierek, Krzysztof
Świątkowski, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/185011.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
2,4-D
2,6-D
2,4,6-T
voltammetry
carbon paste electrode
adsorption
woltamperometria
elektroda pasty węglowej
adsorpcja
Opis:
Carbon paste electrode (CPE) was modified with F-300 commercial activated carbon or Norit SX- 2 powdered activated carbon. CPEs were prepared for detection of 2,4-dichlorophenoxyacetic acid (2,4-D), 2,6-dichlorophenoxyacetic acid (2,6-D) and 2,4,6-trichlorophenoxyacetic acid (2,4,6-T). The electrochemical behavior of these materials was investigated employing cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The modifier was found to enhance the electroactive surface area and the peak current in comparison to the bare (unmodified) carbon paste electrode. The intensity of the signal increased with the increase in adsorption ability of the modifiers. Compared to the unmodified electrode, all the new paste electrodes showed a much greater sensitivity for detection of chlorinated phenoxyacetic acids in water samples.
Źródło:
Chemical and Process Engineering; 2019, 40, 3; 315--325
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of bisphenol a from aqueous solutionsby activated tyre pyrolysis char – Effect of physicaland chemical activation
Autorzy:
Kuśmierek, Krzysztof
Świątkowski, Andrzej
Kotkowski, Tomasz
Cherbański, Robert
Molga, Eugeniusz
Powiązania:
https://bibliotekanauki.pl/articles/184855.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bisphenol A
adsorption
tyre pyrolysis
char
physical activation
chemical activation
bisfenol A
adsorpcja
piroliza opon
aktywacja fizyczna
aktywacja chemiczna
Opis:
This paper aims to show the effect of activation method of tyre pyrolysis char (TPC) on adsorptionof bisphenol A (BPA) from aqueous solutions. The TPC was produced from end-of-life-tyres (ELT)feedstock in a pilot plant at 773 K. Activation was accomplished using two classical methods: physicalactivation with CO2and chemical activation with KOH. The two produced adsorbents had pores rangingfrom micro- to macropores. Distinct differences in the BET surface areas and pore volumes betweenthe adsorbents were displayed showing better performance of the chemically activated adsorbent foradsorption of BPA from water.The results of the kinetic studies showed that the adsorption of BPA followed pseudo-second-orderkinetic model. The Freundlich, Langmuir, Langmuir–Freundlich and Redlich–Peterson isotherm equa-tions were used for description of the adsorption data. The Langmuir–Freundlich isotherm model bestfits the experimental data for the BPA adsorption on both adsorbents. The Langmuir–Freundlichmonolayer adsorption capacity,qmLF, obtained for the CO2-activated tyre pyrolysis char (AP-CO2)and KOH-activated tyre pyrolysis char (AP-KOH) were 0.473 and 0.969 mmol g
Źródło:
Chemical and Process Engineering; 2020, 41, 2; 129--141
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
ARMScope – the versatile platform for scanning probe microscopy systems
Autorzy:
Świadkowski, Bartosz
Piasecki, Tomasz
Rudek, Maciej
Świątkowski, Michał
Gajewski, Krzysztof
Majstrzyk, Wojciech
Babij, Michał
Dzierka, Andrzej
Gotszalk, Teodor
Powiązania:
https://bibliotekanauki.pl/articles/221551.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Scanning probe microscopy
AFM
Kelvin Probe force microscopy
scanning tunnelling microscopy
Opis:
Scanning probe microscopy (SPM) since its invention in the 80’s became very popular in examination of many different sample parameters, both in university and industry. This was the effect of bringing this technology closer to the operator. Although the ease of use opened a possibility for measurements without high labour requirement, a quantitative analysis is still a limitation in Scanning Probe Microscopes available on the market. Based on experience of Nano-metrology Group, SPM still can be considered as a tool for quantitative examination of thermal, electrical and mechanical surface parameters. In this work we present an ARMScope platform as a versatile SPM controller that is proved to be useful in a variety of applications: from atomic-resolution STM (Scanning Tunnelling Microscopy) to Multi-resonance KPFM (Kelvin Probe force microscopy) to commercial SEMs (Scanning electron microscopes).
Źródło:
Metrology and Measurement Systems; 2020, 27, 1; 119-130
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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