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    Wyświetlanie 1-9 z 9
    Tytuł:
    A novel technique to investigate the bubble coalescence in the presence of surfactant (MIBC) and electrolytes (NaCl and CaCl2)
    Autorzy:
    Gungoren, C.
    İslek, E.
    Baktarhan, Y.
    Kursun, I.
    Ozdemir, O.
    Powiązania:
    https://bibliotekanauki.pl/articles/110886.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    surface tension
    salt
    Bubble Coalescence Time Measurement
    Opis:
    An efficiency of flotation process is strongly dependent upon the collecting ability of air bubbles. On the other hand, the liquid film formed beetween two fully or partially mobile air/liquid interfaces being in contact has low stability, which leads to fast liquid drainage. Therefore, when they approach to each other, they tend to coalescence. Therefore, bubble coalescence is usually controlled with frothers in flotation process. Meanwhile, it is known that dissolved ions inhibit bubble coalescence. In this study, the bubble coalescence in the presence of MIBC was determined using a novel technique with a modified bubble-particle attachment timer. Additionally, the effect of NaCl and CaCl2 on bubble behavior was investigated along with surface tension and bubble coalescence time aspects. As a result of study, it is seen that the bubble coalescence time can be successfully determined with a bubble-bubble coalescence timer.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1215-1222
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    An investigation of air/water interface in mixed aqueous solutions of KCl, NaCl, and DAH
    Autorzy:
    Gungoren, Can
    Powiązania:
    https://bibliotekanauki.pl/articles/110641.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bubble coalescence
    surface tension
    KCl
    NaCl
    DAH
    Opis:
    Flotation of soluble salts such as borax, potash, and trona is carried out in their saturated solutions. The high ion concentration of the flotation suspension can affect the floatability of the minerals as well as the coalescence behaviors of the bubbles. The bubble coalescence can be inhibited in the presence of dissolved ions at high ion concentrations as well as with the use of surfactants. In this study, the effect of the mixtures of KCl, NaCl, and dodecyl amine hydrochloride (DAH) on air/water interface was investigated with surface tension and bubble coalescence time measurements for potash flotation. The surface tension measurements indicated that lower surface tension values obtained with mixed KCl and NaCl solutions than their single solutions. In addition, the surface tension of the mixed KCl and NaCl solutions increased with the NaCl and the ionic strength of the solution. The dynamic surface tension measurements indicated that while ion adsorption on air/water interface was so fast, DAH molecules required more time for adsorption probably related to the viscosity of the solution. In addition, the bubble coalescence time measurements showed that the bubble coalescence could be inhibited with the use of DAH in the absence and presence of KCl and NaCl. In the absence of DAH, the bubble coalescence time was determined as 100 ms, 270 ms, and 650 ms, respectively for 100% KCl, 100% NaCl, and 50%KCl+50% NaCl salt solutions. Therefore, the trend in the success of the salt solutions for the inhibition of bubble coalescence can be written as 100%KCl<50%KCl+50%NaCl<100% NaCl according to the bubble coalescence time. The results of this study indicated that there was no clear relationship between the surface tension and the inhibition of the bubble coalescence. However, the bubble coalescence time measurements showed that while the bubble coalescence time was 650 ms in the presence of Na+ ions, it was 100 ms in the presence of K+ ions 100 ms. It can be concluded from the results obtained from this study that the bubble coalescence phenomena may be managed by the specific ion pairing types in solutions which significantly affect the flotation recovery of minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1259-1270
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Physicochemical mechanisms of mineral nanoparticles effects on pulmonary gas/liquid interface studied in model systems
    Autorzy:
    Kondej, D.
    Sosnowski, T. R.
    Powiązania:
    https://bibliotekanauki.pl/articles/110409.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    inhalation
    nanoparticles
    gas-liquid interface
    dynamic surface tension
    Opis:
    Inhaled mineral nanoparticles which are deposited on the lung surface may influence the gas/liquid barrier and the pulmonary surfactant (PS) which constitutes the vital element of the respiratory system. This research is focused on the physicochemical effects caused by selected clay nanoparticles (bentonite, halloysite, montmorillonites) interacting with PS and changing its original surface activity. Using three measuring methods (pulsating bubble technique, Langmuir balance and drop shape analysis), we demonstrated the influence of different mineral nanoparticles on the dynamic surface tension of animal-derived PS material (Survanta®) and main surfactant phospholipid (DPPC). The results which are dependent on material properties and concentration allow to hypothesize possible pathways of health effects from inhalation of mineral nanoparticles. This may help to set the guidelines in defining occupational safety standards and methods of protection of the respiratory system against inhaled mineral dusts.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 1; 57-69
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparison of components and parameters of some sulfide minerals surface tension with regards to stability of mineral-air bubble system
    Autorzy:
    Jańczuk, Bronisław
    Zdziennicka, Anna
    Powiązania:
    https://bibliotekanauki.pl/articles/1450639.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    contact angle
    wettability
    surface tension
    detachment force
    sulfide minerals
    Opis:
    The measurements of the advancing contact angle of water, glycerol, formamide, ethylene glycol, diiodomethane, α-bromonaphthalene, 1,2,3-tribromopropane on unoxidized and oxidized galena, pyrite, chalcopyrite, djurleite, bornite and covellite at the temperature equal 293 K were made. Additionally, the measurements of the force air bubble detachment from these sulfide minerals including also chalcocite in water were performed. Using the values of the obtained contact angle of water, glycerol, formamide, ethylene glycol, diiodomethane, α-bromonaphthalene, 1,2,3-tribromopropane the components and parameters of the unoxidized and oxidized sulfide minerals surface tension were calculated. For this calculation the van Oss et al. method was applied after analysis of the components and parameters of the surface tension of liquids used for contact angle measurements. Taking into account the contact angle of water on the sulfide minerals, the detachment force of air bubble from these minerals in water was determined using our equation and comparing to that of measured one. As follows from the measurements and calculations the wetting properties of sulfide minerals and the stability of mineral-air bubble depends to a larger extent on the degree of sulfide minerals oxidation than on the type of mineral.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 6; 22-31
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A fundamental study of monovalent and divalent ions on froth properties in the presence of terpenic oil
    Autorzy:
    Li, Yubiao
    Wang, Hongduo
    Li, Wanqing
    Song, Shaoxian
    Powiązania:
    https://bibliotekanauki.pl/articles/110301.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    surface tension
    froth stability
    dynamic foamability index
    Gibbs adsorption isotherm
    Opis:
    In order to minimize fresh water usage, much attention has been paid to the flotation using saline or sea water. However, the effects of various ions in these waters on froth properties in flotation are not fully understood. In this study, the effects of electrolyte solutions containing NaCl, KCl, CaCl2, and MgCl2 at different concentrations in the presence of terpenic oil as a frother were investigated on froth performance, dynamic froth stability (DFS). It was found that KCl had the best synergistic effects with terpenic oil in reducing the solution surface tension. In the presence of terpenic oil, the DFS and half-life time were reduced with the increased ion concentration. Dynamics foamability index measurements (DFI) confirmed that the increased ion concentration increased the foamability, as frother did. In addition, Gibbs adsorption isotherm suggested that the amount of terpenic oil adsorbed at the gas-liquid interface was increased with the increased ion concentration. This study therefore indicated that the presence of ions can reduce the froth stability but not decline foamability due to terpenic oil, enlighting the application of saline or sea water in defoaming process in flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 3; 643-654
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation of copper-bearing shale at different pH values of solutions and sodium chloride concentrations
    Autorzy:
    Sajewicz, Jakub
    Ratajczak, Tomasz
    Powiązania:
    https://bibliotekanauki.pl/articles/27323644.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    shale
    salt flotation
    zeta potential
    surface tension
    hydrodynamics
    entrainment
    thin films
    Opis:
    Flotation of copper-bearing shale in aqueous solutions of NaCl at their different pH values was investigated. The tests were carried out in a laboratory flotation machine. The pH range was between 5 and 10 while NaCl concentrations were 0.5M, 1.0M and 2.0M. It was observed that the flotation recovery of the copper shale was increasing with the increase of pH and concentration of the salt solution. On the basis of thermodynamic and hydrodynamic considerations it was postulated that the increasing surface tension was responsible for better shale flotation observed with increasing salt concentration. The observed improved shale flotation caused by increasing pH is most likely due to changes in the properties of the thin film between particle and bubble including mosaic structure of water on the surface of shale. It was shown that the zeta potential of shale particles, zeta potential of air bubbles, solution surface tension, and shale hydrophobicity were not responsible for the increasing with pH recoveries.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 176242
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Components and parameters of synthetic chalcocite surface tension and its wettability by aqueous solution of n-octyl-β-D-glucopyranoside
    Autorzy:
    Jańczuk, B.
    Zdziennicka, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/110743.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    contact angle
    wettability
    surface tension
    chalcocite
    n-octyl-β-D-glucopyranoside
    Opis:
    The measurements of advancing contact angle of water, glycerol, formamide, ethylene glycol, diiodomethane, α-bromonaphthalene, 1,2,3-tribromopropane and aqueous solution of n-octyl-β-D-glucopyranoside (OGP) on unoxidized and oxidized synthetic chalcocite at the temperatures equal to 293, 303 and 313 K were made. Using the obtained contact angle values of the pure liquids the components and parameters of the unoxidized and oxidized synthetic chalcocite surface tension were calculated. For this calculation, different methods based on the Young equation were applied. It follows that the surface tension of both forms of chalcocite does not practically depend on the temperature in the range from 293 to 313 K. Taking into account the calculated values of components and parameters of unoxidized and oxidized chalcocite surface tension their wettability by the aqueous solution of n-octyl-β-D-glucopyranoside was considered. It appeared that wettability of the unoxidized chalcocite by aqueous solution of OGP can be predicted on the basis of the chalcocite surface tension components and parameters.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 1; 19-30
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption of hexane and cyclohexane vapours at the water drop surface
    Autorzy:
    Miller, R.
    Aksenenko, E. V.
    Kovalchuk, V. I.
    Tarasevich, Y. I.
    Fainerman, V. B.
    Powiązania:
    https://bibliotekanauki.pl/articles/110244.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    water-heptane vapour interface
    drop profile analysis tensiometry
    dynamic surface tension
    adsorption kinetics
    Opis:
    The dependence of the dynamic surface tension of water at the interface with saturated hexane and cyclohexane vapours was measured by the drop profile analysis method. The surface tension for the adsorption layers of cyclohexane at different temperatures was compared with the results reported earlier for the adsorption of hexane and other alkanes from the vapour phase on water drops. It is shown that cyclohexane is adsorbed significantly slower than the adsorption of hexane occurs, and is characterised by a much larger induction time. The error in the drop radius measurements at 40 ºC attains 45 m. The experimental rheologic characteristics of the adsorbed layers are studied and the results are compared with the model developed to describe an adsorption process governed by a kinetic mechanism.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 1; 54-62
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synergistic mechanism of dodecylamine/octanol mixtures enhancing lepidolite flotation from the self-aggregation behaviors at the air/liquid interface
    Autorzy:
    Bai, Yang
    Xu, Mengxu
    Wen, Weixiang
    Zhu, Shifei
    Mo, Weichen
    Yan, Pingke
    Powiązania:
    https://bibliotekanauki.pl/articles/27323641.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    DDA/OCT mixtures
    self-aggregation behaviors
    flotation foam
    molecular dynamics simulations
    surface tension
    air interface
    liquid interface
    Opis:
    Surface tension measurements and molecular dynamics (MD) simulations were used to explore the flotation foam properties and self-aggregation behaviors of dodecylamine (DDA)/octanol (OCT) mixtures formed with different mole ratios at the air/liquid interface. Based on the surface and thermodynamic parameters, the DDA/OCT mixtures exhibited greater interfacial activities and adsorption capacities than their individual components. The MD simulations showed that DDA and OCT were aggregated through hydrogen bonding, coulombic forces and hydrophobic association. OCT was inserted into the DDA adsorption layer, causing the alkyl chains of both DDA and OCT to extend from water to air at varying heights and angles. The addition of OCT improved the hydration of the amino groups and reduced the overall number of hydrogen bonds. The stability of the flotation foam decreased, and the high viscosity and difficult defoaming of the DDA flotation foam were significantly improved. When the DDA/OCT mole ratio was 2:1, the included angle formed between the alkyl chains and the interface was maximized, leading to enhanced compatibility among the alkyl chains, and the hydrogen bond energy was relatively large, which showed a strong synergistic effect. The MD simulation findings were consistent with the results obtained from the lepidolite flotation and surface tension experiments conducted in this study; our results could provide a theoretical foundation for the selection of superior mixed collectors and frothers.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 176510
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-9 z 9

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