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    Wyświetlanie 1-6 z 6
    Tytuł:
    Adsorption of Zn2+, Cd2+ and Cu2+ on zeolites coated by manganese and iron oxides
    Autorzy:
    Irannajad, M.
    Hhaghighi, H. K.
    Soleimanipour, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/110138.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    wastewater
    manganese oxide
    iron oxide
    zeolite
    Opis:
    Adsorption of copper, cadmium and zinc on manganese and iron oxide coated zeolite from aqueous solution was investigated in a batch mode. Experiments were conducted to investigate the effects of the initial concentration of metals, initial pH, contact time and temperature on the adsorption of ions. According to the results, adsorption of ions on manganese and iron oxide coated zeolite increased with the enhancement of initial Cu2+, Zn2+ and Cd2+ concentrations and contact time and also with increase of temperature. The results showed that at the beginning, the adsorption rate of Cu2+ and Cd2+ was more than 90 %. This rate continued to be slower for Zn2+ in both zeolites. Furthermore, the amount of Cu2+, Zn2+, and Cd2+ adsorption on the manganese oxide coated zeolite (qe) was equal to 14 mg/g, 9 mg/g and 16 mg/g and on the iron oxide coated zeolite it was 11 mg/g, 7 mg/g and 13mg/g, respectively. It was shown that at the concentrations below 100 mg/dm3 adsorption was rapid and almost all heavy metals were adsorbed. As a result, the significant factor affecting qe is the proportion of weight to liquid and pH in the solutions. Finally, the results showed that the adsorption of Zn2+, Cu2+ and Cd2+ onto the manganese oxide coated zeolite followed both the Langmuir and Freundlich isotherm models.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 894-908
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Buffering of pulp pH and its influence on process water chemistry during iron ore flotation
    Autorzy:
    Tang, Min
    Xiao, Qingfei
    Powiązania:
    https://bibliotekanauki.pl/articles/1446441.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    pulp pH
    buffering
    water chemistry
    mineral dissolution
    iron oxide
    Opis:
    It is inevitable for the occurrences of pulp pH buffering during pH control in flotation as the minerals with acidic/alkali properties tend to interact with pH modifiers and restore the pulp pH. This could result in some disturbing ions and alter the water/pulp chemistry. The purpose of this study was to identify the influences of pulp pH buffering on process water chemistry through a series of pH buffering tests, bench flotation experiments, ore dissolution tests, zeta potential measurement, and Xray diffraction (XRD) analysis. The built-up and distribution of the dominant cations in the process water from different locations in an industrial flotation system of the iron ore were analyzed and recorded by Inductively Coupled Plasma-Optical Emission (ICP-OES) at a period of about six months when the operations were stable. The data showed that a near five-minute buffer of pulp pH at a range from near 7.9 to 8.9 occurred before it reached a stable value. At this period, the dissolution of Ca/Mg from the iron ore was dominant. And, the pulp pH at a lower value tended to induce more dissolved $Ca^{2+}$ and $Mg^{2+}$ ions. These divalent cations seem to have different influences on the flotation properties of iron oxides at the same concentrations, indicating a positive effect on the recovery of iron oxides with the presence of $Mg^{2+}$ ions but an opposite effect if $Ca^{2+}$ ions occurred. The presence of sulfate, however, tended to restore the floatability of silicate depressed by $Ca^{2+}$ ions.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 157-167
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Significance of reagents addition sequence on iron anionic reverse flotation and their adsorption characteristics using QCM-D
    Autorzy:
    Hou, Ying
    Sobhy, Ahmed
    Wang, Yue
    Powiązania:
    https://bibliotekanauki.pl/articles/1448929.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    iron oxide
    adsorption
    pH modifier
    starch
    reverse flotation
    QCM-D
    Opis:
    To explore the influence of reagents addition sequence of the pH regulator and the starch depressant on the anionic reverse flotation of iron oxide, flotation conditional experiments were performed on mixed low-intensity and high-gradient magnetic concentrates which is the flotation feed acquired from the iron processing plant. Besides, quartz crystal micro-balance with dissipative (QCM-D) was conducted to detect the adsorption phenomena of the flotation reagent on iron oxide sensors at different addition orders. The outcomes showed that the flotation performance using the pH regulator prior to the depressant was the best. For example, at 1.6 kg/Mg starch dosage, the recovery and separation efficiencies were improved by 18.3% and 21.2%, respectively, with keeping the concentrate Fe grade as high as 69.5%. Also, QCM-D frequency shifted by -41 Hz from 17 Hz to -24 Hz with increased dissipation from -2.6 x 10-6 to 8.2 x 10-6, indicating an increase in the mass of slightly-rigid starch adsorption layer on the surface of iron oxide under a strong alkaline condition with adsorption density of about 0.46 mg/cm2. On the other hand, under weak alkaline conditions, starch was adsorbed, and then the starch was desorbed upon the addition of the strong alkaline solution. Whereas, adding the pH modifier to create a strong alkaline condition enhanced the starch adsorption significantly with coordination and hydrogen bonds, and prevented the following adsorption of the anionic collector for more efficient reverse flotation of iron oxide minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 284-293
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of uniform test design in optimizing the flotation reagents of iron anionic reverse flotation circuit
    Autorzy:
    Hou, Ying
    Sobhy, Ahmed
    Powiązania:
    https://bibliotekanauki.pl/articles/2146945.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    iron oxide
    quartz
    uniform test design
    reverse flotation
    optimization
    flotation reagents
    Opis:
    Most iron reserves are low in grade with quartz as the main gangue mineral, and anionic reverse flotation has become the most crucial separation method in the processing plants of iron ore. Thus, a flotation feed sample that is a mixture of low-intensity and high-gradient magnetic separators concentrates was acquired from a processing plant. The sample characterizations with X-ray diffraction (XRD), X-ray fluorescence (XRF), laser particle size analyzer, and mineral liberation analysis (MLA) confirmed that the sample consists of iron oxide as a valuable mineral and quartz as a gangue mineral with adequate liberation degree. In the anionic reverse flotation, the interaction of the flotation reagents with the constituents of the feed makes the flotation a complex system. Thus, the selection and optimization of regent dosages were performed using a uniform experimental design to estimate the optimum separation efficiency. The optimum reagent system was 1.6 kg/Mg starch depressant, 1.0 kg/Mg calcium oxide (lime) activator, and 0.8 kg/Mg TD-II anionic collector. At the optimum, 68.90% iron grade with 92.62% recovery was produced.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 1; 37--49
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimizing the removal of iron oxide from Egyptian feldspar ore
    Autorzy:
    Yassin, E. Khaled
    Elbendari, A.M.
    Hassan, El-Sayed R. E.
    Powiązania:
    https://bibliotekanauki.pl/articles/27323643.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    feldspar ore
    iron oxide contamination
    ball mill
    Carpco magnetic separator
    acid leaching
    whiteness
    Opis:
    The demand for feldspar as a raw material for various industrial applications continuously increases. Feldspar is a primary raw material in manufacturing ceramics, glass, fillers, welding electrodes, and enamel. Feldspar is often associated with iron oxide, which decreases its economic value and hinders its industrial application. The present work aimed at reducing iron oxide content in Egyptian feldspar ore from the Wadi Zerabi locality. Ball milling was used for preparing feldspar feed of size -250+45μm. Carpco dry high-intensity magnetic separation followed by acid leaching processes were carried out in order to decrease the iron contamination and increase the feldspar content. A Box-Behnken statistical design was used to optimize the magnetic separation results. From a feldspar feed containing 1.40% Fe2O3, a non-magnetic concentrate of 0.25% Fe2O3 was obtained. The Fe2O3 removal reached up to 82% with a high yield as the % weight of non-magnetic feldspar reached up to 97.5%. The leaching process further reduced the iron oxide content down to 0.19 %. Also, the feldspar whiteness was improved from 65.17% in the original ore to 85.60% in the leached product.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 176420
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Micaceous iron oxide production by application of magnetic separation
    Autorzy:
    Tanriverdi, M.
    Sen, S.
    Ciçek, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/110370.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    micaceous iron oxide (MIO)
    magnetic separation
    belt type high gradient magnetic separator
    high gradient magnetic separator
    pulsating high gradient magnetic separator
    Opis:
    In this study, different flowsheet options were evaluated to achieve the best upgrading conditions for a micaceous iron oxide ore. The first option included the recovery of micaceous iron oxide particles using a double stage magnetic separation circuit after the grinding and classifying of the ore into coarse (-1000+106 μm) and fine (-106 μm) size fractions. A belt type dry high gradient magnetic separator (BHGMS) was used to beneficiate the coarse fraction. The concentrate of the BHGMS was ground to -106 μm, and combined with the fine fraction produced at screening stage, and subjected to high gradient magnetic separation (HGMS) at 1.2 T. A concentrate grading about 61.33% Fe with 60.3% recovery was obtained applying the separation process incorporating BHGMS and HGMS. A single stage separation circuit considering the use of HGMS after the grinding the ore below 106 μm was employed as the second concentration option. A concentrate having 63.80% Fe with 37.1% weight recovery was obtained in this test. As the highest Fe grade and the lowest S concentration was obtained by application of HGMS after the grinding the ore below 106 μm, and it was decided to conduct a pilot scale study using pulsating HGMS. A concentrate assaying 69.45% Fe with 60.1% weight recovery was produced by operating the pulsating HGMS at 0.6 T. The results showed that it was possible to obtain a micaceous iron oxide concentrate to be used in pigment production using magnetic separation method.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 546-553
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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