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Wyświetlanie 1-15 z 41
Tytuł:
Inhibiting effect of citric acid on the floatability of serpentine activated by Cu(II) and Ni(II) ions
Autorzy:
Huang, Jun-wei
Zhang, Cheng-qiang
Powiązania:
https://bibliotekanauki.pl/articles/110224.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper ion
nickel ion
serpentine
floatation
activation
inhibiting
Opis:
The laboratory researches about the inhibiting effect of citric acid on the flotation performance of serpentine activated by Cu2+ and Ni2+ were carried out through micro flotation tests, zeta potential measurements, collector adsorption capacity measurements and solution chemistry analysis. The flotation results showed that Cu2+ and Ni2+ could remarkably activate the flotation of serpentine when the pH value was more than 6, however, this activation could be effectively weakened by adding citric acid. Zeta potential measurement and adsorption capacity measurement indicated that the presence of citric acid could prevent the adsorption of Cu2+ and Ni2+, and therefore reduce the adsorption amount of potassium butyl xanthate on serpentine surface. Furthermore, solution chemical analysis of the flotation system showed that copper hydroxide Cu(OH)2(s) and the nickel hydroxide Ni(OH)2(s) were the main component in the pH range of 9 to 10, which adsorbed onto serpentine surface and made it activated; while the citric acid could effectively prohibit the formation of these metal hydroxide in slurry so as to inhibit the activation impact.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 4; 960-968
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improvement of metal separation process from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction and ion exchange
Autorzy:
Nguyen, Viet Nhan Hoa
Lee, Man Seung
Powiązania:
https://bibliotekanauki.pl/articles/1446393.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
spent lithium-ion batteries
solvent extraction
ion exchange
separation
Opis:
Spent lithium-ion batteries (LIBs) are good secondary resources for recycle and reuse. To develop a process for the separation of Cu(II), Co(II), Mn(II), Ni(II) and Li(I) with high purity from spent LIBs and circumvent some drawbacks of the previous work, solvent extraction and ion exchange experiments were done in this work. The synthetic hydrochloric acid leaching solution of 3 M was employed. Compared to Aliquat 336 (N-Methyl- N, N, N-trioctyl ammonium chloride), extraction with Cyanex 301 (bis(2,4,4-trimethylpentyl) dithiophosphinic acid) led to selective extraction of Cu(II) over other metal ions. Employing ion exchange with TEVA-SCN resin can completely separate Co(II) over Mn(II). After adjusting the pH of Co(II) free raffinate to 3, Mn(II) was quantitatively extracted by the mixture of Alamine 336 (mixture of tri-octyl/decyl amine) and PC 88A (2-ethylhexyl hydrogen-2-ethylhexylphosphonate) with two stage cross-current extraction. The synthesized ionic liquid (ALi-CY) was used for complete extraction of Ni(II), whereas Li(I) remained in final raffinate. The metal ions in the loaded organic phase were completely stripped with the proper agents (5% aqua regia for Cu(II), 5% $NH_3$ for Co(II), weak $H_2SO_4$ solution for Mn(II) and Ni(II) stripping, respectively). The experimental results revealed that purity of the metal ions in stripping solution was higher than 99.9%. A flowsheet was suggested to separate metal ions from the HCl leaching solutions of spent LIBs.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 1-17
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of quartz flotation from decarburized vanadium bearing coal
Autorzy:
Ren, L.
Zhang, Y.
Bian, Y.
Liu, X.
Liu, C.
Powiązania:
https://bibliotekanauki.pl/articles/110937.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
mica
vanadium-bearing coal
flotation
quartz
ion dissolution
calcium ion
Opis:
Ether diamine (Fm 2835-2L) was used as a collector for flotation of quartz. It allows flotation of quartz from mica and calcite. The adsorption mechanism of Fm 2835-2L on quartz was investigated by flotation tests, zeta-potential measurements and infra-red (FTIR) spectra measurements. Results show that Fm 2835-2L adsorbs on the quartz surface in physical adsorption with no new products, changing its zeta potentials, and increasing its hydrophobicity. The effect of calcium ions on flotation of quartz was investigated by flotation tests and zeta-potential measurements. Results show that under neutral or weakly acidic conditions calcium cation can adsorb onto the surfaces of quartz, increase the zeta potential of quartz particles, which in turn causes weaker aggregation of quartz particles and lower flotation recovery of quartz. Under the alkaline conditions the hydrolytic components of calcium are also adsorbed on the quartz surface and increase the zeta potential of quartz particles, which causes stronger aggregation of quartz particles and higher flotation recovery of quartz. However, the hydrolytic components such as CaOH+, Ca(OH)2(aq) and Ca(OH)2(s) were not formed in significant amounts in the best flotation tests.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 755-767
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of Al(III) and Fe(III) ions on the flotation behavior of Kfeldspar with sodium oleate as the collector
Autorzy:
Chen, Yi
Zhou, Jikui
He, Guichun
Hu, Hongxi
Liu, Chao
Yang, Jiping
Lyu, Xianjin
Powiązania:
https://bibliotekanauki.pl/articles/27323648.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
K-feldspar flotation
aluminum ion
iron ion
sodium oleate
action mechanism
Opis:
The present study investigates the effects and mechanisms of aluminum (Al(III)) and iron (Fe(III)) ions on the flotation efficiency of potassium feldspar (K-feldspar) within oleate collector systems. The study employs micro-flotation experiments, solution chemistry calculations, zeta potential measurements, and FT-IR and XPS analyses to demonstrate that Al(III) and Fe(III) ions can significantly improve the flotation recovery of K-feldspar by altering its surface charge, bonding properties, and adsorption modes. The study also develops adsorption models for the flotation of K-feldspar activated by Al(III) and Fe(III), revealing the synergistic impacts of metal ion hydrolysis products and sodium oleate in the formation of hydrophobic complexes.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174724
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of lizardite on talc flotation using carboxymethyl cellulose as a depressant
Autorzy:
Deng, Jie
Yang, Siyuan
Zhang, Wencai
Liu, Cheng
Li, Hongqiang
Powiązania:
https://bibliotekanauki.pl/articles/1449414.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
talc
lizardite
flotation
CMC
magnesium ion
Opis:
The effect of lizardite on talc flotation when using carboxymethyl cellulose (CMC) as a depressant was studied by micro-flotation experiments and adsorption measurements, zeta-potential measurements, magnesium ion dissolution analysis, and solution chemistry calculation. The results for the micro-flotation experiments showed that the addition of lizardite further decreased the floatability of talc at pH 8.5 when using CMC as the depressant. The mechanism was that magnesium ions dissolved from lizardite lattice, then formed hydrolyzed species of magnesium cations and interacted with talc surfaces, which promoted CMC adsorption, and thus decreasing talc floatability.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 4; 702-709
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of ovalbumin on pyrite flotation in the absence and presence of metal ions
Autorzy:
Guler, T.
Sahbudak, K.
Akdemir, U.
Cetinkaya, S.
Powiązania:
https://bibliotekanauki.pl/articles/110499.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
ovalbumin
metal ion
flotation
redox potential
Opis:
Recovery of gangue pyrite and its accidental activation are vital issues in flotation of complex sulfide ores. This work was performed by cyclic voltammetry (CV) and flotation tests to elucidate applicability of ovalbumin (OVA) as depressant for pyrite. The synergetic effect of metal ions in addition to its possible use in case of accidental activation by metal ions. CV tests stated that OVA adsorbed irreversibly on pyrite, and restricted electron transfer up to moderately oxidizing potentials due to electrostatic interaction together with weak hydrophobic interactions. At highly oxidizing potentials, adsorption occurred through electrochemical mechanisms through formation of metal-OVA chelates. Rate of pyrite depression with OVA was found to be potential dependent reaching its peak point around moderately oxidizing potentials both in absence and presence of metal ions. Electrochemically active metals display synergetic effect with OVA on pyrite depression, whereas noble metals activate pyrite and reduced depressing potency of OVA.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 31-40
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Role of dissolved mineral species in quartz flotation and siderite solubility simulation
Autorzy:
Luo, X.
Wang, Y.
Ma, M.
Song, S.
Zhang, Y.
Deng, J.
Liu, J.
Powiązania:
https://bibliotekanauki.pl/articles/109459.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quartz
solubility
siderite
calcium ion
temperature
flotation
Opis:
Quartz is, in most cases, the major gangue mineral found in the iron ores. Although it can be activated by calcium at strong alkaline pH, quartz nevertheless, reports to the concentrate with Fe when the iron ores contain siderite. It causes a poor concentrate grade and separation between quartz and iron minerals. The effect of siderite on reverse anionic flotation of quartz from hematite was studied in our previous investigations. In this work, the effect of siderite dissolution on the quartz recovery in the froth product and the effect of pH, ions and temperature on siderite dissolution were investigated. Microflotation, PHREEQC simulation, solution chemistry calculation and Fourier transform infrared spectroscopy (FTIR) measurements were conducted. It was observed that the dissolved species of siderite exhibited negative impact on quartz flotation. This influence became weak to some extent by either stripping the dissolved species or shortening dissolution time. Siderite was easily dissolved in the presence of calcium ion under strong alkaline conditions and its solubility increased with increasing the calcium ion concentrate and temperature. When the calcium ion was added as an activator of quartz under strong alkaline conditions (pH>9.96), calcium existed mainly in the CaCO3 precipitation form according to the solubility rule in the presence of siderite. This form could adsorb onto quartz surfaces and further the chemical reaction between starch and quartz was monitored by FTIR measurements. This study provides a further supplement for previous study. A potential strategy is suggested that finding a collector used at low temperature or flotation under neutral (or weak alkaline) medium is helpful to the reverse flotation of iron ores containing siderite.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1241-1254
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Beneficial effects and mechanism of lead ion on wolframite flotation
Autorzy:
Yang, S.
Qiu, X.
Peng, T.
Chang, Z.
Feng, Q.
Zhong, C.
Powiązania:
https://bibliotekanauki.pl/articles/109484.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activator
wolframite
lead ion
benzohydroxamic acid
flotation
Opis:
In this study the effects and mechanism of lead ions influence on wolframite flotation with benzohydroxamic acid (BHA) were studied through micro-flotation, adsorption experiments, zeta potential measurements, logarithmic concentration diagram, and X-ray photoelectron spectroscopy. It was observed that lead ions could significantly enhance the recovery of wolframite in flotation and adsorption density of collector BHA onto the wolframite surface. The results showed that Pb existed in the forms of lead ion, monohydric lead, and lead hydroxide at the water-wolframite interface respectively, at three pH ranges. They increased the zeta potential of wolframite. However, the zeta potential of wolframite was still negative, resulting in repulsive electrostatic force to anionic collector BHA. Combining with XPS spectra, it revealed the chemisorption of BHA onto the wolframite surface. In addition, PbO or Pb(OH)2 was observed on the wolframite surface due to the reaction between lead ions and wolframite. These reaction products increased the adsorption site of BHA on the wolframite surface because Pb-hydroxamate was found on the wolframite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 855-873
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of copper ions on malachite sulfidization flotation
Autorzy:
Yin, Wanzhong
Sheng, Qiuyue
Ma, Yingqiang
Sun, Haoran
Yang, Bin
Tang, Yuan
Powiązania:
https://bibliotekanauki.pl/articles/110331.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
malachite
sulfidization flotation
Cu2+ ion
depression
Opis:
In this study, the effects of copper ions (Cu2+) on the sulfidization (Na2S) flotation of malachite was investigated using micro-flotation experiments, zeta-potential measurements, X-ray photoelectron spectroscopy (XPS) analysis, adsorption experiments, and Materials Studio simulation. The results indicated that the flotation recovery of malachite decreased after the pretreatment of the mineral particles with Cu2+ ions prior to the addition of Na2S. The results for zeta-potential measurements and XPS analysis revealed that less sulfide ion species in the pulp solution transferred onto the mineral surface, the sulfidization of malachite surface weakened. The adsorption amount of collector on the mineral surface decreased, and this finding was confirmed by the results of the zeta-potential and adsorption experiments. Materials Studio simulation revealed that the adsorption energy of HS- ions and C4H9OCSS- ions on malachite surface increased after the adding of Cu2+ ion. The competitive adsorption made Cu2+ ions depress sulfidization flotation of malachite, the dissolution of mineral surface affected the adsorption of reagents on it, and decreased the floatability of malachite.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 2; 300-312
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, structure and performance of calcium silicate ion exchangers from recycled container glass
Autorzy:
Coleman, N. J.
Li, Q.
Raza, A.
Powiązania:
https://bibliotekanauki.pl/articles/109960.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
tobermorite
sorbent
hydrothermal synthesis
cullet
recycling
ion exchange
Opis:
Numerous technical, economic and societal factors limit the recycling of waste soda-lime-silica glass back into the primary production process and accordingly alternative applications for this material are sought. This study demonstrates that waste soda-lime-silica container glass is a suitable feedstock material for the production of tobermorite, a calcium silicate cation exchanger. Tobermorites were synthesised at 100 °C from stoichiometric mixtures of container glass and lime under alkaline hydrothermal conditions. Increasing concentrations of sodium hydroxide (between 1.0 M and 4.0 M) in the reaction mixture promoted the formation and crystallisation of tobermorite, and also resulted in greater fragmentation of the silicate chains along the b-axis direction. The maximum removal capacities of these tobermorite specimens for Cd2+ (441 mg g-1) and Zn2+ (122 mg g-1) compared well with those of other waste-derived sorbents. Superior Cd2+- and Zn2+-uptake capacities and kinetics were observed for the least crystalline tobermorite specimen, indicating that stacking defects facilitate the transport and exchange of cations within the lattice.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 5-16
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Specific ion effect of chloride salts on collectorless flotation of coal
Autorzy:
Ozdemir, O.
Powiązania:
https://bibliotekanauki.pl/articles/110238.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
coal
salt
froth stability
ion-specific effect
Opis:
Separation of naturally hydrophobic particles, such as coal, by flotation is known to be enhanced with the addition of salt solutions into the system. In this study, the flotation of bituminous coal in the presence of NaCl, KCl, CaCl2 and MgCl2 without use of any flotation chemicals was investigated in detailed. In addition, zeta potential and foam stability tests were performed. The results from this study showed that the flotation behaviour of coal was influenced by these dissolved salts, and determined by the specific effect of these ions, while MgCl2 and KCl solutions showed the highest and the lowest flotation performance improvements, respectively. The ash content of the products also increased with the salt concentration. This can be attributed to the entrainment of the ash minerals in the salt solutions, particularly at higher salt concentrations. Meanwhile, the froth stability tests at 1 M salt concentration also indicated that there is a correlation between the flotation recovery and stability profile of the froth. These results also clearly indicated that Na+, K+, Ca2+, Mg2+ ions have a strong ion specific effect on the flotation recovery of the coal particles, and there is an optimum salt concentration to produce a clean coal in these salt solutions.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 511-524
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influences of process water chemistry on reverse flotation selectivity of iron oxides
Autorzy:
Tang, Min
Wang, Dong
Wu, Yan
Liu, Dianwen
Powiązania:
https://bibliotekanauki.pl/articles/2175429.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
water chemistry
ion distribution
iron oxides
reverse flotation
Opis:
It is critical for water quality in flotation as it dramatically influences the chemical/electrochemical properties of mineral surfaces and their interactions with reagents. Many potential variations could alter the water chemistry: water recirculation, mineral dissolutions, reagent additions, etc. This study aimed to identify the key elements from the recycled water sources affecting the separation efficiency in a typical industrial flotation circuit of iron oxides through a series of bench/micro flotation tests, zeta potential measurement, etc. The built-up and distribution of the dominant cations/anions in the process water from the roughers in the flotation system was also analyzed and recorded by Inductively Coupled Plasma-Optical Emission (ICP-OES) for a period of about three months when the operations were stable. The flotation results pointed out that a concentrate with a sharp increase of 6.0% Fe recovery and 2.5% SiO2 content was obtained by using the recycled tailing water only in comparison by using fresh water. In contrast, a slight uptrend in the grade of Fe but a substantial loss of near 6.5% Fe recovery occurs by using the treated sewage water alone instead. This could attribute to the ion distributions in these water sources, in which Ca2+, Fen+, Mg2+ or SO42ions were determined as the key ions influencing the flotation behaviors of the iron ore. But the competitive effects of Fe3+ ions were more significant than the ones of Ca2+ or Mg2+ ions. And the occurrence of starch could deteriorate the dilution of silicates in concentration induced by Fe3+/Fe2+ ions. It can be explained by zeta potential measurement or solution chemistry of those ions, indicating that at 8.5-9.0, the coating of the precipitates of Fe(OH)3(s) induced by iron ions alters a reverse on the zeta potentials of quartz. The presence of SO42-ions, however, has a positive role in reducing the possibility of slime coating on silicates due to acting as a chelating agent of iron ions.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151839
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of manganese ions addition orders on the flotation behavior of scheelite
Autorzy:
Lu, Kuanwei
Chen, Rong
Zhang, Ying
Luo, Hongying
Yang, Hu
Cai, Jiaozhong
Powiązania:
https://bibliotekanauki.pl/articles/1845215.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
manganese ion
addition order
scheelite
sodium silicate
flotation
Opis:
In this study, the effect of MnCl2 on scheelite flotation with sodium oleate (NaOL) as a collector and sodium silicate as a depressant was assessed by a combination of flotation experiments, Fouriertransform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and solution chemistry. The flotation experiments confirmed that the addition of MnCl2 before sodium silicate showed an adverse effect on flotation and the recovery of scheelite gradually decreased as the amount of MnCl2 was increased. When MnCl2 was added afte r sodium silicate, the recovery of scheelite gradually increased with an increase in the amount of MnCl2. The results of FTIR, XPS, and solution chemistry indicated that MnCl2 acted on the surface of scheelite in the form of manganese ions. When MnCl2 was added before sodium silicate, manganese ions adsorbed on the surface of scheelite reacted with sodium silicate to form a hydrophilic silicate, which covers the surface of scheelite and blocks the adsorption of NaOL. However, when MnCl2 was added after sodium silicate, manganese ions are continued to be adsorbed on the surface of scheelite, which increases the cations on the surface of scheelite, and hence the condition becomes conducive for the interaction between scheelite and NaOL.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 5; 860-873
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Numerical modeling of field-assisted Ag+–Na+ ion-exchanged channel waveguides using varied explicit space charge density approach
Autorzy:
Mrozek, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/173835.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
numerical modeling
channel waveguide
field-assisted ion-exchange
Opis:
This article presents a numerical model of field-assisted Ag+–Na+ ion exchange in glass, used to determine Ag+ ion concentration contours in cross-sections of channel waveguides. Space charge density was used as a modeling parameter, with different values adopted separately under the mask and in the region of the mask window. Based on the results of simulations, it can be stated that the space charge distribution under the mask has a decisive influence on the diffusion range of Ag+ ions into the glass and on the shape of silver ion concentration contours corresponding to the maximum range of Ag+ ions diffusion. Charge generated within the diffusive structure influences the shape of silver ion concentration contours near the mask’s edge and affects the thickness of the polarized layer under the mask within the waveguide’s optical structure. Modeling results indicate a significant influence of factors affecting space charge density distribution in glass on the results of forming channel waveguides in the field-assisted process.
Źródło:
Optica Applicata; 2019, 49, 4; 641-653
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrothermal synthesis of zeolites from green container glass
Autorzy:
Maisuria, Jenika
Elmes, Victoria K.
Hurt, Andrew P.
Coleman, Aimee A.
Coleman, Nichola J.
Powiązania:
https://bibliotekanauki.pl/articles/1845221.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sodalite
cancrinite
container glass
Knoevenagel condensation
ion-exchange
Opis:
Landfilling and stockpiling unrecycled colored container glass represents a considerable failure in sustainability with respect to the conservation of energy and mineral resources. In this study, the single-step hydrothermal synthesis of low-silica zeolites from a mixture of waste green container glass and aluminum foil (Al:Si = 1) in 4 M NaOH(aq) at 125 °C was followed at 1, 3, 7 and 14 days. The principal phases, sodalite and cancrinite, appeared within 1 day accompanied by minor quantities of hydrogarnet and tobermorite arising from a stoichiometric excess of calcium ions in the parent glass. Products of 63, 67, 71 and 72% crystallinity were obtained at 1, 3, 7 and 14 days, respectively, with partial successive conversion of sodalite to cancrinite over time. Ion-exchange and catalytic applications of sodalite and cancrinite arise from the high anionic charge of the 1:1 ratio of alternating SiO44- and AlO45units within their aluminosilicate frameworks. In this respect, the uptake capacity of the 14-day zeolitic product for Cu2+ and Cd2+ ions (1.58 meq g-1 and 1.66 meq g-1, respectively) was within the expected range for zeolites and compared favorably with those reported for other inorganic sorbents derived from industrial and municipal wastes. The 14-day product was also found to be an effective basic heterogeneous catalyst for the Knoevenagel condensation reaction.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 5; 784-796
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
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