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    Wyświetlanie 1-2 z 2
    Tytuł:
    Adsorption behavior of surfactants on lignite particles with different densities in aqueous medium
    Autorzy:
    Wang, J.
    He, Y.
    Wen, B.
    Ling, X.
    Xie, W.
    Wang, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110538.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    interfacial surface free energy
    adsorption
    lignite
    surfactant
    Washburn equation
    Opis:
    Lignite is well known for its strong hydrophilicity and hard-to-float properties. However, the surface free energy of the solid is made up of two components, that is the Lifshitz-van der Waals and acid-base interaction energy. Differences in these two components between the low ash (lower density) and high ash fraction (higher density) provide a benefit for improving the separation efficiency through introducing surfactants in flotation. In this paper, thermodynamic characterization of three density lignite fractions was measured by a Washburn dynamic method. Combining the Washburn equation and Van Oss-Chaudhury-Good theory, the surface free energy components of three samples were calculated according to the wetting process by n-hexane, diiodomethane, deionized water and ethylene glycol. The Lifshitz-van der Waals part of surface free energy reduced with the coal density increase, especially between fractions of -1.45 g/cm3 and 1.45-1.80 g/cm3, while the Lewis base part increased slightly. The interfacial interaction free energies between the surfactant and lignite in aqueous medium indicated that the low hydrophilic index benefited for the stronger adsorption intensity. Increase of the surfactant Lifshitz-van der Waals component increases the adsorptive intensity on lower density lignite and the repulsive intensity on higher density lignite, which is beneficial for separation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 996-1008
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Structure and surface energy of both fluorite halves after cleaving along selected crystallographic planes
    Autorzy:
    Janicki, M. J.
    Drzymala, J.
    Kowalczuk, P. B.
    Powiązania:
    https://bibliotekanauki.pl/articles/110167.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    fluoride
    surface energy
    interfacial energy
    cleaving
    reorganization
    surface ions
    Opis:
    The density functional theory, supported with a commercial software, was used to compute the geometry and surface energy of fluorite cleaved along the (111), (110) and (100) planes. In the case of cleaving a piece of fluorite along the (111) plane the two newly created surfaces are identical consisting of fluorite ions with the surface energy equal to 0.384 J/m2. Cleaving fluorite along the (110) plane also provides identical halves and, both contain one Ca ion next to two F ions, with the surface energy equal to 0.723 J/m2. When cleaving takes place along the (100) plane, it creates two corresponding halves with different surface structures. One half, having only surface Ca ions (100Ca) has the surface energy equal to 0.866 J/m2, while the surface energy of the second half, having only F surface ions (100F), is 0.458 J/m2. Different structures and energies of the corresponding fluorite surfaces, that is (100Ca) and (100F) planes, should have an impact on their chemical properties, including hydrophobicity expressed by contact angle. The calculations performed in the paper also showed that reorganization of fluorite surfaces after cleaving was insignificant for all of the investigated planes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 451-458
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-2 z 2

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