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    Wyświetlanie 1-3 z 3
    Tytuł:
    Removal of fluoride ions by ultrafiltration in the presence of cationic surfactants
    Autorzy:
    Klimonda, A.
    Grzegorzek, M.
    Majewska-Nowak, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/208133.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ultrafiltration
    fluoride ions
    surfactant
    membrane
    ultrafiltracja
    jony fluorkowe
    fluor
    surfaktanty
    membrany
    Opis:
    The usability of surfactant-aided ultrafiltration for removal of fluoride ions from aqueous solutions has been investigated. The experiments were conducted with the use of cellulose and polyethersulfone membranes. Fluoride solutions containing 10 and 100 mg F–/dm3 and cationic surfactants: octadecylamine acetate (ODA) and hexadecylpyridium chloride (CPC) were used in the experiments. The concentration of surfactants amounted to 320–960 mg/dm3. Ultrafiltration process was run under a trans-membrane pressure of 0.2 MPa. In the course of experiments, the effects of initial fluoride concentration, surfactant concentration and membrane type on the fluoride retention coefficient as well as the permeate flux were studied. It was found that the increase of the surfactant concentration effected in improvement of the separation efficiency. On contrary, the permeate flux decreased upon increase of the surfactant concentration. The process efficiency was also strongly influenced by the membrane and surfactant type. The permissible concentration of fluoride in the final product (below 1.5 mg F–/dm3) was obtained for the test with initial solutions containing 10 mg F–/dm3, polyethersulfone membrane and CPC con-centration equal to 644 and 966 mg/dm3.
    Źródło:
    Environment Protection Engineering; 2017, 43, 2; 5-13
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Fabrication of fluoride nanocrystals and their spectroscopic properties
    Autorzy:
    Pawlik, N.
    Szpikowska-Sroka, B.
    Goryczka, T.
    Pisarski, W. A.
    Powiązania:
    https://bibliotekanauki.pl/articles/173278.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sol-gel method
    glass-ceramics
    fluoride nanocrystals
    europium ions
    Opis:
    In this work, the fabrication of glass-ceramic materials containing MF3:Eu3++ (M = La, Gd) nanocrystals dispersed in silica sol-gel hosts has been presented. The transformation from liquid sols towards bulk samples was also examined based on IR measurements. The crystallization temperatures and formation of MF3 phases were verified based on TG/DSC analysis and XRD measurements. The optical properties of prepared Eu3+5D05D0 → 7FJ (J = 1–4) emission bands, which were recorded within the reddish-orange spectral area under near-UV illumination (λexc = 393 nm). Recorded luminescence spectra and double-exponential character of decay curves for prepared glass-ceramic samples indicated the successful migration of Eu3+ dopant ions from amorphous silica framework to low-phonon energy MF3 nanocrystal phases.
    Źródło:
    Optica Applicata; 2019, 49, 3; 415-426
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Structure and surface energy of both fluorite halves after cleaving along selected crystallographic planes
    Autorzy:
    Janicki, M. J.
    Drzymala, J.
    Kowalczuk, P. B.
    Powiązania:
    https://bibliotekanauki.pl/articles/110167.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    fluoride
    surface energy
    interfacial energy
    cleaving
    reorganization
    surface ions
    Opis:
    The density functional theory, supported with a commercial software, was used to compute the geometry and surface energy of fluorite cleaved along the (111), (110) and (100) planes. In the case of cleaving a piece of fluorite along the (111) plane the two newly created surfaces are identical consisting of fluorite ions with the surface energy equal to 0.384 J/m2. Cleaving fluorite along the (110) plane also provides identical halves and, both contain one Ca ion next to two F ions, with the surface energy equal to 0.723 J/m2. When cleaving takes place along the (100) plane, it creates two corresponding halves with different surface structures. One half, having only surface Ca ions (100Ca) has the surface energy equal to 0.866 J/m2, while the surface energy of the second half, having only F surface ions (100F), is 0.458 J/m2. Different structures and energies of the corresponding fluorite surfaces, that is (100Ca) and (100F) planes, should have an impact on their chemical properties, including hydrophobicity expressed by contact angle. The calculations performed in the paper also showed that reorganization of fluorite surfaces after cleaving was insignificant for all of the investigated planes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 451-458
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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