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Wyszukujesz frazę "calcium carbonate" wg kryterium: Temat


Wyświetlanie 1-9 z 9
Tytuł:
Extracellular polymeric substance of Rhodococcus opacus bacteria effects on calcium carbonate formation
Autorzy:
Szcześ, A.
Czemierska, M.
Jarosz-Wilkołazka, A.
Magierek, E.
Chibowski, E.
Hołysz, L.
Powiązania:
https://bibliotekanauki.pl/articles/109802.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcium carbonate
exopolymer
mineralization
Opis:
An extracellular substance extracted from the bacterial strain Rhodococcus opacus was used as a template for calcium carbonate precipitation from CaCl2 and Na2CO3 solutions at 25 and 37 °C. Obtained crystals were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman spectroscopy. Kinetics of precipitation was investigated by conductivity measurements. The obtained results show that the used biopolymer does not affect the crystal structure but acts as a nucleation centers leading to the formation of calcite crystals with the regular size. This effect is concentration dependent i.e. the EPS concentration increase causes the crystal size decreases, and is greater if calcium chloride solution if mixed with EPS 15 min before the addition of sodium carbonate solution. The temperature increase strengthens this effect.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 1; 142-150
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calcium carbonate mineralization. Part 1, The effect of poly(ethylene glycol) concentration on the formation of precipitate
Autorzy:
Polowczyk, I.
Bastrzyk, A.
Kozlecki, T.
Sadowski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/110925.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcium carbonate
calcite
vaterite
mineralization
PEG
Opis:
In this study, the role of polymer in precipitation has been examined by studying the effect of poly(ethylene glycol) (PEG) on the formation of calcium carbonate particles. The CaCO3 particles were characterized by several techniques, such as FTIR, XRD, SEM, and particle size distribution analysis. In the absence of polymer, the mixing of reagents in an aqueous solution led to the formation of calcite crystals. Introduction of poly(ethylene glycol) molecules reduced the rate of crystallization process, and the effect was concentration dependent. In the presence of 0.05, 0.1, and 0.5 % of PEG, after 5 minutes of precipitation initiation, vaterite microspheres appeared in the system and which were transformed into calcite crystals after 24 hours. The calcium carbonate obtained with PEG was characterized by smaller sized particles in comparison with the ones without polymer.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 631-639
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Precipitated calcium carbonate production, synthesis and properties
Autorzy:
Erdogan, N.
Eken, H. A.
Powiązania:
https://bibliotekanauki.pl/articles/110023.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
precipitated calcium carbonate
waste marble powder
whiteness
Opis:
Calcium carbonate (CaCO3) is the most widely used filler material in paper, paint, plastic, food, ceramic, cosmetic, medicine and other industries. In the present paper, precipitated calcium carbonate (PCC) has been produced from waste marble powder (WMP) by the Calcination-Dissolution-Precipitation (CDP) method. Calcination, dissolution and precipitation experiments were carried out under various conditions including : calcination temperature (800, 850, 900, 950 and 1000 °C), dissolution time (2.5, 5.0, 7.5 and 10.0 min) and precipitation time (2.5, 5.0, 7.5, 10.0, 12.5 and 15.0 min). Then, XRF, XRD, SEM, particle size, whiteness, brightness and yellowness analyses were performed for the characterization of the produced PCC materials. The analyses showed that the precipitate was mainly micrometer-sized (d50 = 1.682 μm) rhombohedral calcium carbonate crystals with 54.5% CaO. The whiteness, brightness and yellowness tests of the precipitates, conducted by Datacolor Elrepho 450x spectrometer, were determined to be 91.28, 98.2 and 1.99%, respectively. It was finally concluded that the produced PCC material reasonably meets Turkish Standards (TS 11653/1995) and can be used in paper industry.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 57-68
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of process of removing impurities from calcium carbonate
Autorzy:
Hann, D.
Kortnik, J.
Powiązania:
https://bibliotekanauki.pl/articles/110465.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcium carbonate
flotation of graphite
ISO brightness
Opis:
Calcium carbonate is used as an additive in the production of paper and some other production processes. The aim of this study was to determine the chances of the calcite sample to be mechanically cleaned of impurities, so that the material can become commercially interesting, primarily to be sold to the paper and other-related industries. A mineralogical petrographic investigation carried out on a sample of calcite showed that an unfavorable impurity is, in particular, graphite – which is otherwise fairly easily to remove by flotation. Flotation was performed with samples of different particle size. The purpose of this was to find an optimal particle size for carrying out the flotation. In order to achieve an effective flotation results it is first necessary to achieve a proper liberation of grains. The second part of the study was to explore the optimal sequence of treatment procedures for tested calcite, using milling, flotation, and sedimentation.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 611-619
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of polyacrylic acid molar mass as a surface modifier on rheological properties of calcium carbonate suspensions
Autorzy:
Selim, Khaled Abdelaal
Farghaly, Mohamed Galal
Abdallah, Samah Saleh
Abdel-Khalek, Mohamed Abdel-Dayem
Powiązania:
https://bibliotekanauki.pl/articles/1446411.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcium carbonate
surface modification
poly-acrylic acid
rheology
adsorption
Opis:
Suspensions of calcium carbonate are of a major concern in various fields, such as coating, painting and ceramics and their rheological properties are very important. The effect of polyacrylic acid (PAA) of different molecular mass as a surface modifier on the surface and rheological properties of the aqueous suspension of calcium carbonate was investigated. The effect of the volume fraction of particles and polymer concentration on the viscosity at lower shear rate was discussed. The flow behavior of the concentrated suspension in the presence of PAA can be explained by the difference of the repulsive force among particles, induced by the adsorbed polymer. The results showed that the dispersibility is more pronounced by the steric hindrance behavior rather than the electrostatic behavior.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 18-26
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of polymers on the grinding and rheology of ultrafine Egyptian calcium carbonate suspension
Autorzy:
Mourad, Sabreen H
Khalil, Mostafa M. H.
Abdel-Khalek, N. A.
Abdel-Khalek, M. A.
Selim, K. A.
Hassan, El-Sayed R. E.
Powiązania:
https://bibliotekanauki.pl/articles/2175428.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fillers
calcium carbonate
ultra-fine grinding
surface modifications
Mechano-chemical
activation
polymers
Opis:
The investigation of surface modification of Egyptian calcium carbonate via polymers was achieved with simultaneous ultra-fine grinding. Attrition mill and planetary mill were used for wet and dry grinding, respectively. The parameters affecting the grinding were studied such as ball number, speed and grinding time. The rheological characteristics of the aqueous calcium carbonate suspensions were studied in the presence of different types of polymers. The results indicated that the mechanical force could clearly affect the modification characteristics of calcium carbonate due to its mechanochemical effects. The viscosity of calcium carbonate suspension depends on the volume percentage or weight percentage. The dispersing agent increases the solid concentration for a given particle fineness.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 152163
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
One step 3D printing of surface functionalized composite scaffolds for tissue engineering applications
Autorzy:
Kotlarz, M.
Jordan, R.
Wegner, E.
Dobrzyński, P.
Neunzehn, J.
Lederer, A.
Wolf-Brandstetter, C.
Pamula, E.
Scharnweber, D.
Powiązania:
https://bibliotekanauki.pl/articles/306484.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
druk 3D
PLGA
węglan wapnia
właściwości powierzchniowe
3D printing
calcium carbonate
amphiphilic poly(2-oxazoline)
degradation
surface properties
Opis:
A successful approach widely used in materials science to adapt approved materials to specific applications is to design their surface properties. A main challenge in this area is the development of processing routes enabling for a simple but efficient surface design of complex shaped geometries. Against this background, this work aimed at the implementation of self-assembly principles for surface functionalization of 3D-printed poly(lactic-co-glycolic acid) (PLGA)-based constructs with macro- and microporous geometries via precision extruding deposition. Methods: Three-component melts from PLGA, CaCO3 and amphiphilic polymers (poly(2-oxazoline) block copolymer) were printed and their bulk and surface properties were studied. Results: Melts with up to 30 mass % of CaCO3 could be successfully printed with homogeneously distributed mineral particles. PLGA degradation during the printing process was temperature and time dependent: the molecular weight reached 10 to 15% of the initial values after ca. 120 min of heat exposure. Filament surfaces from melts containing CaCO3 show an increasing microroughness along with increasing CaCO3 content. Surface roughness and amphiphilic polymer content improve scaffold wettability with both factors showing synergistic effects. The CaCO3 content of the melts affected the inner filament structure during in vitro degradation in PBS, resulting in a homogeneous mineral particle-associated microporosity for mineral contents of 20 mass % and above. Conclusions: These results provide novel insights into the behavior of three-component melts from PLGA, CaCO3 and amphiphilic polymers during precision extruding deposition and show for the first time that self-assembly processes can be used to tailor scaffolds surface properties under such processing conditions.
Źródło:
Acta of Bioengineering and Biomechanics; 2018, 20, 2; 35-45
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching behaviour of zinc from a smithsonite ore in sodium hydroxide solutions
Autorzy:
Ehsani, Ilhan
Ucyildiz, Ayse
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/110552.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline leaching
calcium zincate
nonsulfide zinc ore
smithsonite
zinc carbonate
Opis:
In this study, the leaching behaviour of zinc from a smithsonite ore sample (23.43% Zn) having goethite and calcite as main gangue minerals was investigated in sodium hydroxide solutions using Xray diffraction and chemical analyses. Within the studied NaOH concentration range (1-4 mole/dm3), higher leaching ratio values for Zn were obtained by leaching at 298 K because of the decreased stability of soluble zincate species in solution at higher temperatures. When the concentration of NaOH solution was increased from 1 to 3 mole/dm3 at 298 K, leaching ratio value of Zn increased from 3.8 to 70.1%. At 4 mole/dm3 NaOH concentration, Zn leaching ratio value (70.9%) levelled off due to the formation of solid hydrated calcium zincate phase in leaching solution. On the other hand, very low leaching ratio values of Zn were obtained by leaching in 1 mole/dm3 NaOH solution at 298 K (3.8%) and 363 K (1.4%) due to the formation of solid zinc hydroxide and solid zinc oxide phases, respectively. It was observed that increasing leaching time from 1800 to 14400 s at 3 mole/dm3 NaOH concentration, favoured the formation of hydrated calcium zincate phase and so decreased the leaching ratio of Zn to a lower value (60.6%). The effect of solid/liquid ratio was also investigated and it was found that when solid/liquid ratio was decreased, Zn leaching ratio values decreased at constant OH/Zn mole ratio and increased at constant NaOH concentration conditions. Besides, for some of the experiments, leaching ratio values of lead were also given.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 407-416
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of heating on structure and leaching characteristics of a zinc carbonate ore
Autorzy:
Kumas, Cavit
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/1446908.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcium zincate
smithsonite
sodium hydroxide leaching
zinc carbonate ore
zinc oxide
Opis:
In this work, the structural changes occurred in a zinc carbonate (smithsonite) ore sample following heating at temperatures between 523 K and 1173 K were investigated in detail using X-ray diffraction (XRD), thermal (TG/DTA) and Fourier-transform infrared (FT-IR) spectroscopy analyses. Afterwards, the leaching characteristics of zinc from the ore sample and the heated ore samples in sodium hydroxide solutions were determined. While heating at 523 K did not cause any structural change in the ore sample, heating at 723 K completely converted smithsonite $(ZnCO_3)$ in the ore sample to zinc oxide $(ZnO)$, which resulted lower zinc leaching efficiencies of 40.6% and 62.0% for 3 and 4 mol/dm3 NaOH concentrations, respectively, in comparison to zinc leaching efficiencies (67.2% and 70.7%) obtained for the unheated ore sample. On the other hand, due to neoformation of dissolution resistant $ZnFe_2O_4$, $Ca_2ZnSi2O_7$ and $Zn_2SiO_4$ phases during heating and formation of $CaZn_2(OH)_6∙2H_2O$ phase during leaching, the leaching efficiency of zinc further decreased to 22.2% and 31.3%, respectively, in 3 and 4 $mol$ / $dm^3$ NaOH solutions for the ore sample heated at 1173 K. The formation of zinc-containing dissolution resistant phases by high-temperature heating was observed to be the only reason for the reduction in the zinc leaching efficiency (49.4% at 1173 K) at the highest NaOH concentration (8 mol/dm3) studied. In this work, the comparative precipitation studies were also conducted and crystalline zinc oxides with different morphologies could be precipitated at considerably high efficiencies from the selected pregnant solutions obtained following leaching.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 23-32
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-9 z 9

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