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Wyszukujesz frazę "ammonia" wg kryterium: Temat


Wyświetlanie 1-9 z 9
Tytuł:
Ammonia level sensor using tapered optical fiber coated with titanium dioxide-incorporated porphyrin
Autorzy:
Parasuti, Frazna
Hikmawati, Dyah
Trilaksana, Herri
Yasin, Moh.
Powiązania:
https://bibliotekanauki.pl/articles/27310105.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ammonia sensing
tapered optical fibre
titanium dioxide
porphyrin
Opis:
Since ammonia is water-soluble, environmental studies have shown that the industrial waste such as fertilizer manufacturing, food products, palm oil, urea fertilizer industry can cause very serious damage to water body ecosystems if not properly managed, resulting in a decrease in water quality. Devices based on optical technology, especially devices that combine optical fibers and nanomaterials, are identified as highly sensitive to the species of interest by detecting changes in physicochemical properties. A practical, easy-to-use, inexpensive instrument for detecting ammonia level was proposed using tapered optical fiber (TOF) coated with titanium dioxide-incorporated porphyrin. TOF was fabricated by simultaneously stretching and heating. The preparation of TiO2/porphyrin/gelatine was prepared to coat tapered optical fiber by dipping. SEM analysis shows an increase in length and a decrease in diameter, also the successful coating of titanium dioxide and porphyrin in the taper region. The EDX analysis also proves the presence of the Ti element in the TOF layer. The TOF produces significant sensing performances toward the ammonia liquid concentration level. The TOF coated with titanium dioxide-incorporated porphyrin can detect a one ppm difference in ammonia concentration with a certain range of output voltage for every concentration has.
Źródło:
Optica Applicata; 2023, 53, 3; 353--361
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thiosulfate leaching of silver from a solid residue after pressure leaching of industrial copper sulfides flotation concentrates
Autorzy:
Wejman-Gibas, K.
Chmielewski, T.
Borowski, K.
Gibas, K.
Jeziorek, M.
Wodka, J.
Powiązania:
https://bibliotekanauki.pl/articles/109947.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
atmospheric leaching
silver
sodium thiosulfate
ammonia
Lubin copper concentrate
Opis:
Hydrometallurgical recovery of silver from a solid residue after pressure leaching of a flotation copper concentrate from the Lubin Concentrator (KGHM Polska Miedz S.A.) was investigated. Thiosulphate leaching was examined with regard to the highest possible leaching efficiency and optimization process parameters. The effect of thiosulfate ions concentration within the range from 0.25 to 1.00 mol/dm3 at a constant ammonia concentration, and ammonia concentration within the range from 0.40 to 1.00 mol/dm3 at a constant thiosulfate concentration on leaching recovery of selected metals were examined. Moreover, the effect of copper(II) ions addition on silver leaching was studied. It was shown that the leaching recovery of silver increased with increasing thiosulfate and ammonia concentration. At the highest thiosulfate ions concentration, the observed silver leaching recovery was 60%. The best results were obtained at an ammonia concentration of 0.80 mol/dm3, where the leaching recovery of Ag reached 75%. It was established that addition of Cu(II) did not affect silver leaching. Nearly 100% efficiency of thioslulohate silver leaching was achieved by pretreatment of the solid residue after pressure leaching with NaOH solutions.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 601-610
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct conversion of alkaline earth metal hydroxides and sulfates to carbonates in ammonia solutions
Autorzy:
Ehsani, Ilhan
Ehsani, Arman
Ucyildiz, Ayse
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/2146856.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline earth metal
ammonia leaching
direct conversion
dissolved carbonate
smithsonite
Opis:
In this study, the direct conversion behaviors of different alkaline earth metal solids (the hydroxides and the sulfates of alkaline earth metals Ca, Sr, Ba and Mg) to their corresponding carbonates in dissolved carbonate-containing pregnant solutions obtained by direct leaching of a smithsonite (ZnCO3) ore sample in aqueous ammonia solutions having different concentrations (4 M, 8 M and 13.3 M NH3) were investigated by using X-ray diffraction analyses at alkaline earth metal to dissolved carbonate mole ratios of 1:1 and 1:2, for revealing the conversion possibilities of dissolved carbonate in the pregnant solutions to solid carbonate by-products. The results of direct conversion experiments showed that Ca(OH)2, CaSO4•2H2O, Sr(OH)2•8H2O and Ba(OH)2•8H2O converted to their corresponding carbonates, SrSO4 partially converted to SrCO3 as observed by the presence of unreacted SrSO4 peaks in X-ray diffraction patterns of the converted solids, and BaSO4 did not convert to BaCO3 because of its lower solubility with respect to BaCO3. On the other hand, it was observed that Mg(OH)2 did not convert to MgCO3, but MgSO4•7H2O converted dominantly to an uncommon phase, which was tentatively identified as Mg5Zn3(CO3)2(OH)12•H2O. In the study, a complete discussion on the conversion behaviors of alkaline earth metal solids to their corresponding carbonates was given considering the differences between their solubility product constants and the changes in the free energies of the theoretical conversion reactions. In addition, infrared spectra and scanning electron microscope images of some of the converted solids were also presented for characterization purposes.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 169--180
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of different zinc compounds from a smithsonite ore through ammonia leaching and subsequent heat treatment
Autorzy:
Ehsani, Arman
Ehsani, Ilhan
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/1445772.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ammonia leaching
smithsonite
zinc ammine carbonate
zinc carbonate hydroxide
zinc oxide
Opis:
In this study, firstly, the effects of ammonia concentration, leaching time and solid/liquid ratio on the leaching behaviour of zinc from a smithsonite (ZnCO3) ore sample in aqueous ammonia solutions were investigated at room temperature by chemical, X-ray diffraction (XRD) and Fourier-transform infrared (FT-IR) spectroscopy analyses. It was found that leaching ratio of zinc steeply increased from 30.1 to 76.2% with increasing ammonia concentration from 1.0 to 4.0 M and maximum zinc leaching ratio of 79.7% was reached after leaching in 13.3 M NH3 solution. The XRD pattern of the residue obtained after leaching in 4.0 M NH3 solution for 90 min at solid/liquid ratio of 0.15 g/mL, the optimum condition, showed that smithsonite phase in the ore sample almost completely dissolved whereas the gangue minerals goethite and calcite remained unaffected, confirming the selectivity of ammonia solution for zinc dissolution. Together with zinc, leaching ratios of cadmium were also determined. In second part of the study, precipitation tests (by complete drying at different temperatures) were conducted on dissolved zinc, carbonate and ammonia containing pregnant solutions obtained after selected leaching experiments. By complete drying of the pregnant solutions at low temperatures, i.e. 50°C, relatively pure solid zinc ammine carbonate (Zn(NH3)CO3) precipitates and at higher temperatures, i.e. 150°C, quite pure solid zinc carbonate hydroxide (Zn5(CO3)2(OH)6) precipitates could be prepared. High-temperature heating of Zn(NH3)CO3 and Zn5(CO3)2(OH)6 precipitates at 450°C yielded single-phase zinc oxide (ZnO). The chemical compositions, FT-IR spectra and scanning electron microscope (SEM) photographs of some of the precipitates were also presented.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 96-106
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Activated biocarbons obtained from lignocellulosic precursors as potential adsorbents of ammonia
Autorzy:
Jedynak, Katarzyna
Charmas, Barbara
Powiązania:
https://bibliotekanauki.pl/articles/24085696.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activated biocarbon
various carbon precursors
physical activation
physicochemical properties
ammonia adsorption
Opis:
The investigated materials were new biocarbons: FC (Fir Cone), FS (Fir Sawdust), FB (Fir Bark), BS (Birch Sawdust), BB (Birch Bark), AS (Acacia Sawdust), AB (Acacia Bark), OS (Oak Sawdust), OB (Oak Bark), HS (Hornbeam Sawdust)) obtained via pyrolysis and CO2 activation of wood waste (lignocellulosic biomass). In order to study the influence of the carbon precursor on the physicochemical properties of biocarbons there were used the precursors: cones, sawdust, and bark of various tree species. The obtained adsorbents were characterized based on the results, of the N2 adsorption, scanning electron microscopy (SEM), elemental analysis (CHNS), thermogravimetry (TG), derivative thermogravimetry (DTG), and differential thermal analysis (DTA), Fourier Transform Infrared Spectroscopy FT-IR (ATR) and the Boehm’s titration method as well as pHpzc (the point of zero charge). The adsorption capacity and the temperature-programmed desorption (TPD) of ammonia were also studied. The obtained activated biocarbons were characterized by the large specific surface area (515 to 1286 m2/g) and the total pore volume (0.27 to 0.46 cm3/g) as well as the well-developed microporous structure (76 - 90%). The maximum NH3 adsorption capacity of the activated biocarbon was determined to be 2.93 mmol/g (FC (Fir Cone)). These results prove that the lignocellulosic precursors are appropriate for preparation of environmentally friendly and cost-effective biocarbons.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 4; art. no. 169835
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the duration of feeding phase on the genotypic structure of bacterial communities in two sequencing batch reactors treating reject water by partial nitritation and anammox
Autorzy:
Ziembińska-Buczyńska, A.
Cema, G.
Meresta, A.
Płonka, L.
Powiązania:
https://bibliotekanauki.pl/articles/208156.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activated sludge
anammox
ammonia
biocenosis
dynamics nitrification
osad czynny
amoniak
biocenoza
dynamika nitryfikacji
Opis:
Microbial community and physiochemical processes were monitored by means of denaturing gradient gel electrophoresis (PCR-DGGE) in two sequencing batch reactors (SBRs) running for partial nitritation-anammox and differing in the feeding phase durations (6 h 40 min for SBR1 and 40 min for SBR2). Both SBRs were treated with reject water with a high ammonia concentration (>600 mg for over 370 days. The aim of the experiment was to present the influence of this parameter on total bacterial and anammox bacterial community structure. Molecular analysis revealed that a drastic decrease in influent ammonia concentration to the studied communities caused a change of genotypic structure in their composition. The difference in the reactors working scheme can be the reason for divergence in the community structure though having no drastic influence on its performance and biodiversity level. Feeding time has stronger influence on the genotypic composition of the total bacterial community than on anammox biocenosis.
Źródło:
Environment Protection Engineering; 2016, 42, 4; 49-63
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigations on the effectiveness of wastewater purification in medium sand with assisting clinoptilolite layer
Autorzy:
Kalenik, Marek
Chalecki, Marek
Powiązania:
https://bibliotekanauki.pl/articles/208175.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydraulic conductivity
septic tank
infiltration
ammonia
phosphorus
adsorption
landfill
przewodność hydrauliczna
szambo
infiltracja
amoniak
fosfor
adsorpcja
odciek
Opis:
Model investigations of wastewater purification were carried out in a medium sand bed with an assisting natural clinoptilolite layer 0.10 or 0.25 m thick. The effectiveness of wastewater purification related to basic qualitative parameters was in accordance with the Polish standards on sewage disposal into grounds and surface water. Medium sand soil bed with the assisting natural clinoptilolite layer 0.25 m thick showed on average the removal efficiency regarding TSS higher by 3.3%, total nitrogen by 29.3%, total phosphorus by 25.9%, reduction efficiency regarding BOD5 by 1.1% and COD by 15.9% than that with the thinner clinoptilolite layer. The investigations confirmed that natural clinoptilolite with the granulation 1-5 mm can be used to enhance the removal of nitrogen and phosphorus compounds from wastewater with the application of infiltration drainage. However, very good effect of the TSS removal from the wastewater in the investigated soil beds can lead to their fast clogging under the infiltration drainage. Septic tanks should be designed in such a way that they retain as much TSS as possible, e.g., multi-chamber tanks instead of one-chamber ones.
Źródło:
Environment Protection Engineering; 2019, 45, 2; 117-126
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous removal of SO2 and NOx from sintering flue gas using ammonia-Fe(II)EDTA combined with electrolytic regeneration
Autorzy:
Liang, Y.
Yao, X.
Quin, L.
Chen, W.
Han, J.
Powiązania:
https://bibliotekanauki.pl/articles/208117.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ammonia
desulfurization
flue gases
nitrogen oxides
nitrogen removal
sintering sulfur dioxide
amoniak
odsiarczanie
gazy odlotowe
tlenki azotu
usuwanie azotu
spiekanie
ditlenek siarki
Opis:
Sulfur dioxide and nitrogen oxide are health hazardous gases, which contribute to the formation of submicron acidic particulates. To reduce SO2 and NOx emission from the sintering flue gas, the combination of ammonia-Fe(II)EDTA solution scrubbing with Fe(III) electrolytic regeneration is proposed. The above method has the following advantages: direct conversion of NOx and SO2 to harmless N2 and SO4 2−, recovery of the by-product (NH4)2SO4), simultaneous removal of NOx and SO2 emission from flue gas in the reactor. The effect of the pH, initial Fe(II)EDTA concentration, and voltage on the desulfurization and denitration efficiencies was investigated using a bench-scale reactor. The maximal desulfurization and denitration efficiencies were 98% and 52%, respectively. The optimum parameters were pH ˃ 5.0, 2.1 V, and 0.05 mol·dm–3 Fe(II)EDTA concentration. SO2 and NOx removal from the sintering flue gas by ammonia-Fe(II)EDTA solution scrubbing combined with electrolytic regeneration was also demonstrated in a pilot-scale reactor.
Źródło:
Environment Protection Engineering; 2018, 44, 2; 19-36
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Attapulgite suspension filter material for biological aerated filter to remove CODMn and ammonia nitrogen in micropolluted drinking water source
Autorzy:
Xu, Kai
Wang, Jiahao
Li, Jiacheng
Wang, Zijie
Lin, Zizeng
Wang, Zheng
Powiązania:
https://bibliotekanauki.pl/articles/2032905.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
drinking water
biofiltration
BAF
biological aerated filter
COVID-19
removal of ammonia
human stool
woda pitna
biofiltracja
biologiczny filtr napowietrzny
usuwanie amoniaku
kał ludzki
Opis:
An attapulgite suspended (AS) filter material was successfully prepared and used in combination with biological aerated filter (BAF) to pretreat excess organic matter and ammonia nitrogen in micropolluted water. The AS filter material was of low density and floated on the water surface, which is beneficial to optimize the hydraulic conditions. Through scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) It was found that the surface of the filter material was uneven, the pores were deep. When the hydraulic load is 4 m/h and the gas to water volume ratio is 2:1, the removal rates of permanganate index (CODMn) and ammonia nitrogen by ASBAF are up to 57.49 and 88.11%, respectively, and the effluent quality meets relevant standards. After backwashing, the pollutants removal rate will return to stable filtration after two hours. A short-term shutdown of the reactor has little effect on the processing performance of ASBAF, but a long-term shutdown will greatly affect the removal rate of CODMn. The complete organic matter degradation model can well fit the experimental effluent water quality.
Źródło:
Environment Protection Engineering; 2020, 46, 4; 21-40
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-9 z 9

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