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Tytuł:
Some applications of barium titanate prepared by different methods
Autorzy:
Sydorchuk, Volodymyr
Khalameida, Svitlana
Skwarek, Ewa
Biedrzycka, Adrianna
Powiązania:
https://bibliotekanauki.pl/articles/2146894.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
barium titanate
synthesis
physicochemical properties
photocatalytic properties
Opis:
The paper presents some application of barium titanate synthesized by different methods. Barium titanate samples were prepared by four procedures: solid state, mechanochemical as direct synthesis and modification as well as hydrothermal and microwave. The obtained samples were systematically studied using X-ray diffraction, nitrogen adsorption, Fourier transform infrared spectroscopy (FTIR), potentiometric titration, and quasi-elastic light scattering and zeta potential measurements. The values of pHpzc (point of zero charge) and pHIEP (isoelectric point) characteristic of the electrical double layer were determined. The prepared samples were tested as photocatalysts under visible light. As a result, relationship between the conditions of barium titanate synthesis, its physicochemical and electrokinetic parameters, as well as photocatalytic activity under visible light was first established.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2 (Special issue - selected papers conference: Physicochemistry of interfaces - instrumental methods); art. no. 147192
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Relationships between comminution and chemical, petrographic and mineralogical properties of ores, and their effect on concentration
Autorzy:
Deniz, Vedat
Powiązania:
https://bibliotekanauki.pl/articles/2146932.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ores
minerals
comminution
chemical properties
petrographic-mineralogical properties
Opis:
Especially in terms of energy costs, data on chemical, petrographical, and mineralogical analyses of ores or minerals can provide very important information for their production in the desired size distribution. Therefore, suitable crushing and grinding machines can be selected, taking into account the data affecting the comminution such as grain size, texture, metamorphism, and mineral or element contents. However, in most mineral processing plants, these data are rarely used to understand the response of ores or minerals to comminution. Analysis of the relationships between the chemistry, petrography, and mineralogy of ores and the breakage mechanism during crushing or grinding has been the subject of researchers in the comminution field in recent years. This study is a review of studies done so far on the relationships between the comminution and the chemical, petrographic, and mineralogical properties of different ores and minerals, and their effect on concentration.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 149892
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separation and physicochemical properties of residual carbon in gasification slag
Autorzy:
Fan, Xiaoting
Fan, Panpan
Liu, Xiaodong
Ren, Zhenyang
Bao, Weiren
Wang, Jiancheng
Dong, Lianping
Fan, Minqiang
Powiązania:
https://bibliotekanauki.pl/articles/2175447.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
waste treatment
gasification slag
physical properties
chemical properties
structural features
reaction kinetics
Opis:
Gasification slag is the solid waste produced in the coal gasification process, and its treatment and disposal problems are becoming more and more serious. In this study, the gasification slag produced in a chemical base in northern China and its residual carbon obtained by gravity separation of water medium were taken as the research objects, and their physicochemical properties were analyzed comprehensively. The residual carbon products, ash-rich products and high-ash products were obtained from the gasification slag after gravity separation. Under the optimal structure, the ignition loss of residual carbon products was reduced from 79.80% to 16.84%, and the yield was 11.64%. The high content of amorphous carbon and developed pores in the residual carbon provide the possibility of manufacturing high value-added materials. Raman spectrum showed that the residual carbon had lower aromaticity, higher content of small and medium aromatic ring structures, lower structural stability and easier combustion. Thermogravimetric combustion kinetics showed that the average combustion rate of residual carbon was 0.325(dm/dt)mean/%•min−1, the comprehensive combustion characteristic index was 1.41•10−9%2•min−2•°C−3. It has excellent performance and can be used as a raw material for mixed combustion in a circulating fluidized bed. The analysis of physical and chemical properties of residual carbon is of great significance for follow-up exploration of the resource utilization and high-value utilization of the residual carbon.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 154928
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of Ti-6Al-7Nb titanium alloy nitrocarburized under glow discharge conditions
Autorzy:
Kajzer, A.
Grzeszczuk, O.
Kajzer, W.
Nowińska, K.
Kaczmarek, M.
Tarnowski, M.
Wierzchoń, T.
Powiązania:
https://bibliotekanauki.pl/articles/306236.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Ti-6Al-7Nb alloy
diffusive nitrocarburized layer
mechanical properties
electrochemical properties
Opis:
The paper presents the results of physicochemical and mechanical properties of the Ti-6Al-7Nb alloy with surface modified by formation of a diffusive nitrocarburized layer deposited in a low-temperature plasma process. The main aim of the study was to evaluate the influence of steam sterilization and exposure to Ringer’s solution on the utility properties of the alloy. Methods: Based on the study of the microstructure, roughness, wettability, resistance to pitting corrosion, ion infiltration and mechanical properties, the usefulness of the proposed method of surface treatment for clinical application was proven. Results: Deposition of the nitrocarburized layer increased the surface roughness and surface hardness, but also reduced the contact angle, and corrosion resistance with respect to the polished surfaces. The nitrocarburized layer is a barrier against the infiltration of ions to the solution and sterilization and exposure to Ringer solution have greater effect on the physicochemical properties rather than on the mechanical ones. Conclusion: It was found that sterilization, and exposure to Ringer’s solution greatly affect the change of physicochemical properties rather than mechanical properties for both nitrocarburized layers and the Ti-6Al-7Nb alloy of mechanically polished surface.
Źródło:
Acta of Bioengineering and Biomechanics; 2017, 19, 4; 181-188
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The wettability, mechanical and antimicrobial properties of polylactide/montmorillonite nanocomposite films
Autorzy:
Rapacz-Kmita, A.
Pierchała, M. K.
Tomas-Trybuś, A.
Szaraniec, B.
Karwot, J.
Powiązania:
https://bibliotekanauki.pl/articles/307050.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
montmorylonity
nanokompozyty
właściwości antybakteryjne
właściwości mechaniczne
montmorillonite
nanocomposite films
antibacterial properties
mechanical properties
Opis:
The aim of this study was to evaluate the effect of the not activated (unmodified) montmorillonite (MMT) filler on the antibacterial properties of polymer nanocomposites with a biodegradable polylactide (PLA) matrix. The subject of research was selected to verify the reports on the lack of antibacterial properties of unmodified montmorillonite in nanocomposites and to investigate the potential condition of their manufacturing which are decisive for the resulting properties. Evaluation of antibacterial and mechanical properties of both the starting materials and the obtained nanocomposites filled with layered silicates, as well as the wettability of the materials measured by a sitting drop method, was made on samples in the form of a film. The results show that the surface wettability of the polymer nanocomposites did not exhibit significant change compared to the film of neat PLA. However, a significant improvement in the mechanical and antimicrobial properties of the nanocomposite films obtained in a specific solvent casting process of the nanocomposite preceded by exfoliation of the film in an ultrasonic homogenizer was demonstrated. The antibacterial activity against Gram-positive bacteria Staphylococcus aureus and Enterococcus faecalis was also observed, and moreover, the montmorillonite-containing films revealed a zone of inhibition of bacterial growth when tested against the lactose-positive bacteria of the Enterobacteriaceae family, which are present in the waste water. The advantageous properties of the obtained PLA/MMT nanocomposites suggest, that the unmodified montmorillonite may be potentially used as filler for polymer films in the packaging industry.
Źródło:
Acta of Bioengineering and Biomechanics; 2017, 19, 4; 25-33
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Co(II) ions adsorption in the hydroxyapatite/aqueous NaClO4 solution system on particles electrokinetics
Autorzy:
Janusz, W.
Skwarek, E.
Powiązania:
https://bibliotekanauki.pl/articles/110335.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydroxyapatite
adsorption Co(II)
electrokinetic properties
Opis:
The study of the kinetics and statics of cobalt adsorption at the hydroxyapatite/electrolyte interface using radioactive isotope 60Co was conducted. The course of adsorption kinetics indicates that at the beginning adsorption proceeds quickly and then slowly. Such adsorption kinetics is best described by a multiexpotential equation. The analysis of cobalt adsorption as a function of pH and the results of H+ ions desorption/adsorption confirmed that cobalt adsorption proceeds due to ion exchange with calcium ions in the crystal lattice and hydrogen ions in the surface groups of hydroxyapatite. Cobalt ions adsorption results in the increase of the electrokinetic potential but for the solution of the initial concentration of 0.001 mol/dm3 at pH = 8.17 a reversal of the charge due to overloading of the compact layer (edl) is observed.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 1; 31-39
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transparent yttrium oxide ceramics as potential optical isolator materials
Autorzy:
Kruk, A
Wajler, A
Mrozek, M
Zych, L
Gawlik, W
Brylewski, T
Powiązania:
https://bibliotekanauki.pl/articles/173500.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
transparent ceramics
optical properties
yttrium oxide
Opis:
The objective of the presented study was to investigate the usefulness of transparent, sintered yttrium oxide for application as optical isolators, i.e., materials with high Verdet constant. The study utilizes the magneto-optical Faraday effect. To obtain yttrium oxide sinters, a commercial Y2O3 powder was applied, with LiF added to facilitate sintering. As a result of hot-press sintering and heating, transparent, dense sinters were obtained. The structure and morphology of the powders and bulk samples and the optical properties of the latter were investigated by means of X-ray diffraction, scanning electron microscopy, visible and near-infrared reflectance spectroscopy, and a study of magneto-optical (Faraday) effects. Measurements of the Faraday effect in the wavelength range of 500–1000 nm indicate high Verdet constants for the above-described materials, which means that they can be effectively applied in laser optics.
Źródło:
Optica Applicata; 2015, 45, 4; 585-594
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evolution properties of multi-Gaussian Schell model beams propagating in uniaxial crystal orthogonal to the optical axis
Autorzy:
Lu, X.
Shen, Y.
Zhu, X.
Zhao, C.
Cai, Y.
Powiązania:
https://bibliotekanauki.pl/articles/173654.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
propagation properties
partially coherent
uniaxial crystal
Opis:
An analytical formula for the multi-Gaussian Schell model is derived for the beam propagating in a uniaxial crystal orthogonal to the optical axis. The propagation properties of multi-Gaussian Schell model beams in a uniaxial crystal orthogonal to the optical axis is investigated by using the analytical formula. Some results are illustrated by numerical examples related to the propagation properties of multi-Gaussian Schell model beams. It is found that the propagation properties of the multi-Gaussian Schell model beams are very different from the propagation properties in the free space. They are closely related to the initial coherence and the ratio of the extraordinary and ordinary refractive indices. The results provide a way for studying the propagation properties of the multi-Gaussian Schell model beams in the uniaxial crystal orthogonal to the optical axis.
Źródło:
Optica Applicata; 2016, 46, 1; 19-34
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Focusing of linearly polarized helico-conical Lorentz beam with sine-azimuthal variation wavefront
Autorzy:
Bao, Y.
Lan, J.
Miao, Y.
Zhang, D.
Gao, X.
Powiązania:
https://bibliotekanauki.pl/articles/174305.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Lorentz beam
focusing properties
optical vortex
Opis:
In this article a theoretical research is described into focusing of a linearly polarized helico-conical Lorentz beam with a sine-azimuthal variation wavefront. The simulation results show the vortex charge on the axis, which has an obvious modulation effect on the focal modes of the Lorenz beam under certain beam parameters and phase parameters. Both the phase parameter and the vortex charge are zero, the focal spot appears round. The focal spot is symmetric about y axis when the charge is 0 and the phase parameter is adjusted. And the focal evolution patterns vary remarkably under different beam parameters and the phase parameters. In the process of focus evolution, there appears some novel focal patterns, such as a circle, a “T”, a butterfly, a small running humanoid, a whale tail, a flower of four leaves, a serpentine, a goldfish, a Chinese knot and an octopus, which indicates that the focus mode of the optical vortex Lorentz beam can be altered by changing the phase parameters and vortex charge.
Źródło:
Optica Applicata; 2018, 48, 3; 373-387
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Role of nitrogen in carrier confinement potential engineering and optical properties of GaAs-based quantum wells heterostructures
Autorzy:
Pucicki, D.
Bielak, K.
Dawidowski, W.
Ściana, B.
Tłaczała, M.
Powiązania:
https://bibliotekanauki.pl/articles/174427.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
dilute nitrides
optical properties
carrier confinement
photoluminescence
Opis:
In this work, the authors present the results of optical characterization of GaAs-based multiple quantum well heterostructures, together with energy band structure analysis. The optical properties were investigated by applying photoluminescence spectroscopy. Structures with GaInNAs, GaInAs and GaNAs multiple quantum wells emitting around 1 μm, grown by atmospheric pressure metalorganic vapor phase epitaxy, were compared in this work. The role of nitrogen in quantum well carriers confinement potential was analysed. The photoluminescence intensities of the samples were correlated with the analysis of energy band structures and the overlaps of the carriers’ wave functions. In addition, the main carrier activation energies were estimated based on photoluminescence temperature dependence and the Arrhenius plots analysis. It was deduced that the thermal photoluminescence decay is most probably related to the escape of electrons whereas the holes, independently of the potential well depth, are additionally confined by the local inhomogeneities or by the Coulomb interaction with the confined electrons.
Źródło:
Optica Applicata; 2016, 46, 2; 255-263
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ultrasonic waves and strength reduction indexes for the assessment of the advancement of deterioration processes in travertines from Pamukkale and Hierapolis (Turkey)
Autorzy:
Bobrowska, A.
Domonik, A.
Powiązania:
https://bibliotekanauki.pl/articles/178309.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
travertine
deterioration
geomechanical properties
ultrasonic diagnosis
strength
Opis:
In constructions, the usefulness of modern technical diagnostics of stone as a raw material requires predicting the effects of long-term environmental impact of its qualities and geomechanical properties. The paper presents geomechanical research enabling presentation of the factors for strength loss of the stone and forecasting the rate of development of destructive phenomena on the stone structure on a long-time basis. As research material Turkish travertines were selected from the Denizli–Kaklık Basin (Pamukkale and Hierapolis quarries), which have been commonly used for centuries in global architecture. The rock material was subjected to testing of the impact of various environmental factors, as well as European standards recommended by the author of the research program. Their resistance to the crystallization of salts from aqueous solutions and the effects of SO2, as well as the effect of frost and high temperatures are presented. The studies allowed establishing the following quantitative indicators: the ultrasonic waves index (IVp) and the strength reduction index (IRc). Reflections on the assessment of deterioration effects indicate that the most active factors decreasing travertine resistance in the aging process include frost and sulphur dioxide (SO2). Their negative influence is particularly intense when the stone material is already strongly weathered.
Źródło:
Studia Geotechnica et Mechanica; 2015, 37, 3; 3-9
0137-6365
2083-831X
Pojawia się w:
Studia Geotechnica et Mechanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Advanced biocomposites based on silica and lignin precursors
Autorzy:
Klapiszewski, Ł.
Nowacka, M.
Szwarc-Rzepka, K.
Jesionowski, T.
Powiązania:
https://bibliotekanauki.pl/articles/110719.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
biocomposites
silica
lignin
physicochemical and structural properties
Opis:
A new method is proposed for obtaining biocomposites based on a combination of silica and lignin precursors. Amorphous silica was produced by two methods: one based on hydrolysis and condensation of tetraethoxysilane (sol–gel method) and the other involving precipitation in a polar medium. Additionally, the commercial silica known under the name of Syloid®244 was used. The silica surface was modified to ensure better affinity of the support to activated lignin. The biocomposites obtained were carefully characterised by determination of their physicochemical and dispersive–morphological properties. Electrokinetic stability of the biocomposites was evaluated on the basis of zeta potential dependence on pH. Thermal stability of the biocomposites and their porous structure parameters (surface area, pore diameter and pore volume) were established. The results indicate that silica/lignin biocomposites are much promising for application in many areas of science and industry.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 497-509
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of waste materials as fillers in polymer composites-synthesis and thermal properties
Autorzy:
Gargol, Mateusz
Podkościelna, Beata
Powiązania:
https://bibliotekanauki.pl/articles/109774.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
waste materials
composites
thermal properties
UV-polymerization
Opis:
This paper presents the synthesis and characterization of new polymeric materials in form of composites. As a fillers, waste materials of inorganic origin (ash and silica gel), were used. In the synthesis of composites, two derivatives of bisphenol A (glycerolate diacrylate, and epoxy resin, Epidian® 5), were applied. The compositions were prepared with an increasing amount of fillers 0-40% w/w in both tested systems. Composites were analyzed using the thermogravimetric analysis (TG/DTG), which showed the influence of different fillers on their thermal properties. Moreover, the proper course of the polymerization reaction was confirmed by spectroscopic analysis (ATR/FT-IR). It has been shown that new resistant materials can be obtained, using cheap and waste materials, by simple synthesis which does not require monitoring of the reaction course or expensive polymerization initiators.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1549-1556
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on quantifying the hydrophilicity of leached coals by FTIR spectroscopy
Autorzy:
Wang, J.
He, Y.
Yang, Y.
Xie, W.
Ling, X.
Powiązania:
https://bibliotekanauki.pl/articles/110191.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemical-structural properties
macerals
hydrophilicity
functional group
Opis:
Surface properties play important roles in characterization of structural parameters and the hydrophilicity index. Accurate analysis of the macerals rather than the average properties of the macerals and minerals are crucial for these parameters and indexes. In order to improve the accuracy of analyzing coal surface property, HF/HCl acid leaching was applied to eliminate the interference of minerals. FTIR was used to characterize the differences in surface chemical composition between raw and processed coal. Moreover, each functional group was analyzed quantitatively. Based on these quantitative data, the structural parameters and hydrophilicity indexes were calculated. From the results of FTIR, the peaks of mineral cover up the types of the organic peaks, such as -COOH and aromatic CH stretching. In addition, they decrease the intensity of the peak such as C=C and aromatics CHx out-of-plane deformation in the spectra of raw coals. However, it provided the accurate types and contents of organic functional groups of the macerals after acid leaching. The structural parameter results indicate that the values cannot reflect the coal ranks through the surface properties of raw coals while they show a good relationship with the degree of coalification in the analysis of processed coals. Besides, the hydrophilicity indexes are verified by the natural floatability of coal macerals of the processed coals. It is also found that the processed lignite coal cannot be floated despite elimination of the hydrophilic minerals. The main reason of hard-to-float property of lignite coal lies in a strong hydrophilicity of macerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 227-239
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterization of polymer biocomposites with lignin
Autorzy:
Goliszek, Marta
Podkościelna, Beata
Powiązania:
https://bibliotekanauki.pl/articles/110212.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lignin
biocomposites
physicochemical properties
eco-filler
photopolymerization
Opis:
A new method of synthesis of polymer biocomposites with lignin using the photopolymerization method has been proposed. Bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BAGDA) was used as a main monomer and 2-ethylhexyl acrylate (EHA) as a reactive diluent. Lignin (L) was applied as an eco-filler. The influence of the increasing lignin content (0; 2.5; 5; 10; 20% w/w) on the properties of the obtained biocomposites was investigated. The chemical structure of biomaterials was investigated by the attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FT-IR) method while the thermal properties were studied by the differential scanning calorimetry (DSC) and thermogravimetric analysis (TG/DTG). Their hardness was measured by the Shore D method. Incorporation of the biopolymer into the structure of polymer composites could be a promising alternative to synthetic materials and would contribute to better lignin utilization. The results of the study are of practical importance in prospective applications of biocomposites with lignin.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1375-1381
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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