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Wyszukujesz frazę "AOP" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Degradation of toluene using UV/hydrogen peroxide process
Autorzy:
Cai, Shaokang
Sun, Yue
Gao, Canzhu
Li, Pengfei
Cheng, Zhongfa
Powiązania:
https://bibliotekanauki.pl/articles/2032937.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
AOP
toluene
hydrogen peroxide
spectrofotometer
toluen
nadtlenek wodoru
spektrofotometria
Opis:
Toluene in wastewater is volatile and difficult to degrade, and the longer it stays in the water, the higher is the risk. An advanced oxidation process (AOPs) has been used to degrade toluene rapidly and efficiently in wastewater by using ultraviolet light and hydrogen peroxide. Toluene in solution (initial concentration – 180 mg/dm3) with hydrogen peroxide (H2O2 dose – 2022 mg/dm3) was almost decomposed within 150 min. pH as well as the presence of various ions in waste water did not affect the degradation process. However, under strongly acidic conditions (pH less than 3), the chloride ions reduced the degradation efficiency of toluene. Based on the UV spectrophotometer and GC-MS analyses, the degradation pathways were observed: first, the methyl group was oxidized leading to the generation of benzoic acid, the benzene ring was subsequently opened by the action of hydroxyl radical, followed by the gradual decomposition of the intermediate products into small molecules such as water and carbon dioxide.
Źródło:
Environment Protection Engineering; 2021, 47, 1; 5-15
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessing some advanced oxidation processes in the abatement of phenol aqueous solutions
Autorzy:
Jaramillo-Sierra, Bethsabet
Mercado-Cabrera, Antonio
Peña-Eguiluz, Rosendo
Hernández-Arias, Alma Neli
López-Callejas, Régulo
Rodríguez-Méndez, Benjamín Gonzalo
Valencia-Alvarado, Raúl
Powiązania:
https://bibliotekanauki.pl/articles/207453.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
AOP
oxidation of phenol
Advanced Oxidation Processes
utlenianie fenolu
zaawansowane metody utleniania
Opis:
In this work, phenol oxidation in aqueous solution promoted by the effect of the oxidizing agents H2O2, O3 and UV radiation and their synergy in four different advanced oxidation processes (O3, O3/UV, H2O2/O3 and O3/H2O2/UV) were assayed. Studies were performed with a closed-loop hydraulic circuit set up with a relatively high volume of solution (500 cm3) during 90 min of treatment time. Parameters such as concentration for oxidizing species, pH, presence of UV irradiation were evaluated. The resulting degradation efficiencies were evaluated using GC-MS. The agents here used were selected considering their ease of handling and low toxicity, generation of deposited matter or sludge, so a filtration treatment for the analysis of the samples was not required. In all cases, it was observed that with increasing treatment time better degradation efficiencies were obtained. The best results were obtained with the combination of O3/H2O2/UV where up to 95% degradation was attained at pH 9, which is due to active species generated in the process, e.g., O3 and OH˙, on the contaminant. SPE was performed for determining the presence of several by-products, mainly: catechol, resorcinol and hydroquinone, which were identified.
Źródło:
Environment Protection Engineering; 2019, 45, 3; 23-38
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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