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    Wyświetlanie 1-4 z 4
    Tytuł:
    Strengthening the rough selection effect of n-ethyl o-isopropyl thionocarbamate (Dow: Z-200) on chalcopyrite by ultrasonic pretreatment
    Autorzy:
    Wang, Yan
    Wang, Yubin
    Yu, Bo
    Wang, Xin
    Ma, Xiaoxiao
    Powiązania:
    https://bibliotekanauki.pl/articles/1448798.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ultrasonic pretreatment
    Z-200
    action mechanism
    chalcopyrite flotation
    Opis:
    In this study, the properties of $(CH_3)_2CHOC(S)NHC_2H_5$(Dow: Z-200) after the ultrasonic pretreatment was characterized by employing surface tension, viscosity, and Fourier transform infrared (FTIR) spectroscopy, and its influence on chalcopyrite rough selecting was investigated. The results indicate that the pretreated Z-200 can improve the index of chalcopyrite roughing. And, under the same reagent system, the recovery of copper reached 82.84% which was an increase of 24.44% compared with the untreated when Z-200 after ultrasonic pretreatment was applied to the rough separation of chalcopyrite. The reason why ultrasonic can strengthen the flotation effect of Z-200 on chalcopyrite is that ultrasonic pretreatment can decrease the surface tension and viscosity of Z-200 and enhance its foaming performance. Meanwhile, the ultrasonic cavitation destroys the molecular structure of Z-200, so that the relative proportion of methyl absorption peak and amine absorption peak in Z-200 increases. This also further improves the collection performance and foaming performance of Z-200 and strengthens its separation effect on chalcopyrite. The research provides a new idea for Z-200 to act on chalcopyrite and improve its flotation efficiency, reduce the amount of flotation reagent, and its pollution to the environment. It also provides a theoretical basis for expanding the application of ultrasonic technology in the field of flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 64-74
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Tubular biofilter treatment of isobutanol emissions under various organic loading rates
    Autorzy:
    Chen, Hong
    Peng, Liang
    Wei, Yanxiao
    Yu, Lie
    Jiang, Bo
    Wang, Hong
    Yu, Guanlong
    Zhang, Guijin
    Powiązania:
    https://bibliotekanauki.pl/articles/207774.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    biofiltration
    pollutants removal
    volatile compounds
    biofiltracja
    usuwanie zanieczyszczeń
    związki lotne
    Opis:
    Isobutanol in waste gas streams was treated by a tubular biofilter (TBF) which continuously operated for 364 days under various organic loading rate (OLR) from 11 g·m–3·h–1 to 66 g·m–3·h–1. Results show that within 60 days, the TBF successfully started up even after changing the OLR from 31.3 to 15.6 g·m–3·h–1. The average removal efficiencies (REs) were totally higher than 90% when OLRs ranged from 12.14 to 66.45 g·m–3·h–1. Two distinct performance deterioration periods were observed at days 186–253 and days 280–334, both of which recovered without additional measurement. During these periods, the larvae and adult moth flies, been identified as Psychodinae infested the TBF, greatly affected the TBF performance. When the number of adult Psychodinae decreased, TBF performance recovered. The elimination capacity (EC) was 60.42 g·m–3·h–1 at the inlet OLR of 66.45 g·m–3·h–1, with the critical EC being around 50 g·m–3·h–1. Even under a low gas empty bed residence time of 15 s, the preferable REs and ECs under middle or low OLRs were still obtained by the TBF.
    Źródło:
    Environment Protection Engineering; 2020, 46, 1; 15-29
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Counterion effects on the alkali dissolution mechanism of quartz
    Autorzy:
    Yao, Yu-yun
    Tang, Yun
    Yang, Yong
    Li, Guo-hui
    Wu, Bo
    Dai, Wen-zhi
    Powiązania:
    https://bibliotekanauki.pl/articles/2200337.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quartz
    counterion
    quantum chemistry
    hydrolysis
    mechanism
    Opis:
    In gold ore, quartz plays an important role in mineral formation by acting as the follower. Understanding counterion release, transport, and deposition in alkali solution is a prerequisite for evaluating the potential role of gold separate from quartz deposits in pretreatment. In this work, the aggregation, retention, and release of counterion in alkali solution media were investigated by kinetic research and pure mineral experiments, the correlation and mechanism of these processes were revealed by combining geochemical theory, interaction energy calculation, and quantum chemistry. The results showed that the retention and release of counterion were closely related to the dissolution and corrosion rate of quartz. The NH4+ and Fe2+ with higher mineral affinity reduced the quartz stability, and the dispersion stability and mobility of the quartz were greatly improved by an alkaline substance due to the enhancement of steric hindrance effects. Quantum chemical calculation results show that ammonium ion promotes the dissolution of quartz stronger than ferrous ion, which is mainly reflected in reducing the activation energy required for the formation of transition state (TS1), which can be verified by kinetic calculation. These findings provide essential insight into the extraction of gold coated by quartz as well as a vital reference for the experiment of gold-loaded quartz leaching in mineral processing.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 160038
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Preparation of α-calcium sulfate hemihydrate from industrial by-product gypsum: a review
    Autorzy:
    Guan, Qingjun
    Sui, Ying
    Zhang, Fang
    Yu, Weijian
    Bo, Yongjie
    Wang, Ping
    Peng, Wenqing
    Jin, Jiao
    Powiązania:
    https://bibliotekanauki.pl/articles/1448527.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    α-calcium sulfate hemihydrate
    industrial by-product gypsum
    FGD gypsum
    phosphogypsum
    preparation method
    Opis:
    In recent years, the massive accumulation of industrial by-product gypsum, especially flue gas desulfurization (FGD) gypsum and phosphogypsum (PG), not only encroaches on lands but also causes serious environmental pollution. The preparation of α-calcium sulfate hemihydrate (α-HH) from industrial by-product gypsum is an important way to solve the massive accumulation. α-HH possessing larger, dense and well-grown crystals with fewer cracks and pores has high added value and a wide range of application. Hitherto the preparation methods of α-HH from industrial by-product gypsum mainly include the autoclave process, salt/acid solution process, or alcohol-water solution process. Thereinto, the autoclave process is the only method to realize industrialization. In order to solve the high energy consumption and unfavorable continuous operation of the autoclave process, researchers suggested alternative approaches, such as salt/acid solution process and alcohol-water solution process. However, these methods are basically in the laboratory stage or pilot scale test at present. Compared with FGD gypsum, the utilization rate of PG with a larger emission is very low owing to the high impurity content. And combining the preparation of α-HH with the recovery of valuable impurities from PG seems a promising way to solve the bulk deposition of PG.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 168-181
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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