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    Wyświetlanie 1-6 z 6
    Tytuł:
    Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor
    Autorzy:
    Yang, Xiao-Feng
    Xu-Zhao
    Liu, Yao-Yao
    Powiązania:
    https://bibliotekanauki.pl/articles/24085868.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ethyl thioglycolate
    chalcopyrite
    molybdenite
    inhibitor
    separation
    Opis:
    The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162824
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on seawater scrubbing for SO2 removal from ships power plant exhaust gas
    Autorzy:
    Ma, Yiping
    Xu, Leping
    Su, Penghao
    Feng, Daolun
    Yang, Kailiang
    Powiązania:
    https://bibliotekanauki.pl/articles/207540.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sulfur dioxide
    absorption
    seawater
    dwutlenek siarki
    adsorpcja
    woda morska
    Opis:
    The mechanism of SO2 absorption in seawater is investigated, and the experiment was carried out accordingly. Emphasis is on applications of seawater scrubbing of ship’s power plant exhaust gas containing SO2. The formulated model is used to predict the influence of various parameters on both pH of tailwater and seawater desulfurization capability, e.g., the partial pressure of SO2, the partial pressure of CO2, tailwater temperature, pH and alkalinity of seawater. Experiment results indicated that the seawater desulfurization capacity increases with both increasing partial pressure of SO2, pH and alkalinity and decreasing partial pressure of CO2 and temperature. The study shows the desulfurization capacity of seawater with 3.5% salinity is approximately twice that of freshwater. Different scenarios in which the required absorbent supply rate for a given SO2 removal efficiency are studied. It is observed a 97% removal efficiency, corresponding to meeting the SOx limits in the SOx emission control areas (SECA) while operating on a heavy fuel oil containing sulfur 3.5 wt. %, requires a minimum water supply rate of 0.0407–0.0683 m3/kWh, depending mainly on the water composition in terms of alkalinity and salinity. Such data are important in assessing the operation cost of the water scrubbing system.
    Źródło:
    Environment Protection Engineering; 2020, 46, 1; 31-47
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Relationship between flotation and Fe/Mn ratio of wolframite with benzohydroxamic acid and sodium oleate as collectors
    Autorzy:
    Yang, S.
    Feng, Q.
    Qiu, X.
    Gao, Y.
    Xie, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/109666.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    wolframite
    flotation
    collector mixture
    benzohydroxamic acid
    sodium oleate
    Opis:
    Several studies revealed that flotation of wolframite changes with different Fe/Mn ratios, but they did not reach a consensus. This relationship in the presence of benzohydroxamic acid (BHA) and sodium oleate (NaOl) as collectors was studied in this paper through comparison of probability distribution curve of wolframite with different Fe/Mn ratios between the raw ore and the flotation concentrate, the pure mineral flotation and solution chemistry of flotation. The results showed that wolframite with high Fe/Mn ratio showed higher flotation with BHA as a collector while the flotation behavior of wolframite was completely opposite with NaOl as a collector. Besides, the calculations of chemical equilibrium in the solution were plotted as ΔG°-pH graphs. The results revealed that the flotation of wolframite may be determined by the interaction between BHA and ferric(II) ion or between NaOl and manganous ion. From the perspective of collector mixture, the results also explain the high collecting capability of the BHA/NaOl collector mixture, which can be defined as “functional complementation”.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 2; 747-758
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Beneficial effects and mechanism of lead ion on wolframite flotation
    Autorzy:
    Yang, S.
    Qiu, X.
    Peng, T.
    Chang, Z.
    Feng, Q.
    Zhong, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/109484.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    activator
    wolframite
    lead ion
    benzohydroxamic acid
    flotation
    Opis:
    In this study the effects and mechanism of lead ions influence on wolframite flotation with benzohydroxamic acid (BHA) were studied through micro-flotation, adsorption experiments, zeta potential measurements, logarithmic concentration diagram, and X-ray photoelectron spectroscopy. It was observed that lead ions could significantly enhance the recovery of wolframite in flotation and adsorption density of collector BHA onto the wolframite surface. The results showed that Pb existed in the forms of lead ion, monohydric lead, and lead hydroxide at the water-wolframite interface respectively, at three pH ranges. They increased the zeta potential of wolframite. However, the zeta potential of wolframite was still negative, resulting in repulsive electrostatic force to anionic collector BHA. Combining with XPS spectra, it revealed the chemisorption of BHA onto the wolframite surface. In addition, PbO or Pb(OH)2 was observed on the wolframite surface due to the reaction between lead ions and wolframite. These reaction products increased the adsorption site of BHA on the wolframite surface because Pb-hydroxamate was found on the wolframite surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 855-873
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on the cleanliness of super clean coal prepared by water-only cyclone
    Autorzy:
    Liu, Peikun
    Wang, Hui
    Jiang, Lanyue
    Zhang, Yuekan
    Yang, Xinghua
    Li, Xiaoyu
    Li, Feng
    Powiązania:
    https://bibliotekanauki.pl/articles/24085799.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cyclone separating
    chemical deashing
    super clean coal
    surface characteristics
    comparative study
    Opis:
    Maintaining clean and pristine nature is the key to the use of super clean coal (SCC) for coal-based materials or energy combustion. Herein, SCC is prepared by a new water-only cyclone method, and compared the surface characteristics with the SCC products obtained by conventional chemical deashing method. The results indicate that: FTIR analysis revealed that the chemical method changed the original functional group of coal; BET analysis revealed that the SCC products prepared by the water-only method maintained the micropore volume of the raw coal and yielded a uniform and concentrated distribution of pore sizes, however, the chemical method destroying the original pore structure in the coal; SEM-EDS analysis indicated that the surface of SCC particles that were deashed using the water-only cyclone method was smooth and neat, whereas those obtained using the chemical method were seriously corroded, had a rough surface, and the SCC particles were prone to acid residues and precipitates. This study opens an innovative, simple, and clean method for the preparation of SCC, which further expands and enhances the potential application value of SCC.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 168129
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Phytochelatins of Cladophora rupestris in Pb2+ absorption and its detoxification
    Autorzy:
    Zhang, Lu-Sheng
    Yang, Liu
    Li, Lingsheng
    Feng, Xiaoyu
    Cao, De-Ju
    Liu, Zhao-Wen
    Powiązania:
    https://bibliotekanauki.pl/articles/27323982.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    phytochelatins
    heavy metals
    detoxification
    Cladophora rupestris
    Pb+
    fitochelatyny
    metale ciężkie
    detoksykacja
    Opis:
    Phytochelatins (PCs) exist widely in plants and are closely related to plant resistance to heavy metals (HMs). Glutathione (GSH) and nonprotein thiols (NPTs) are the major components of PCs. This study investigates the role of the PCs of Cladophora rupestris in Pb2+ accumulation and detoxification. The distribution of Pb2+ in the PCs of C. rupestris was studied. FTIR and XPS are used to characterize the chelating power of Pb2+ with PCs in C.rupestris. The curve fitting of the secondary protein structure is used to identify the functional groups with Pb2+. Results showed that the content of Pb2+ in the PCs of C. rupestris increased with an increase in Pb2+ stress. Pb content increased to 352 and 314 mg/kg in NPTs and GSH, respectively, when Pb stress concentration reached 7.5 mg/dm3 . The Pb2+ fraction of C. rupestris PCs reached a maximum of 10.8 and 9.3% in NPTs and GSH, respectively. The Pb2+ uptake by GSH and NPTs was 40–48% and 52–60%, respectively. Pb2+ bound with the PCs of C. rupestris, forming complexes that contained Pb–OOC, Pb–C=O, CO–Pb, –N=Pb, Pb–NH2, Pb–O, Pb–N–, Pb–C–, Pb–S, and Pb2+ with multiple groups of PCs as bridging ligand atoms.
    Źródło:
    Environment Protection Engineering; 2023, 49, 3; 31--42
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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