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    Wyświetlanie 1-14 z 14
    Tytuł:
    Removal of quinoline from aqueous solutions by lignite, coking coal and anthracite. Adsorption isotherms and thermodynamics
    Autorzy:
    Xu, H.
    Huagn, G.
    Li, X.
    Gao, L.
    Wang, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/110016.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quinoline adsorption
    coking coal
    adsorption isotherms
    thermodynamics
    Opis:
    Based on the concept of circular economy, a novel method of industrial organic wastewater treatment by using adsorption on coal is introduced. Coal is used to adsorb organic pollutants from coking wastewaters. After adsorption, the coal would be used for its original purpose, its value is not reduced and the pollutant is thus recycled. Through systemic circulation of coking wastewater zero emissions can be achieved. Lignite, coking coal and anthracite were used as adsorbents in batch experiments. The quinoline removal efficiency of coal adsorption was investigated. The coking coal and anthracite exhibited properties well-suited for adsorption onto both adsorbents. The experimental data were fitted to Langmuir and Freundlich isotherms as well as Temkin, Redlich–Peterson (R-P) and Dubinin-Radushkevich (D-R) models. Both Freundlich Isotherm and D-R model provided reasonable models of the adsorption process. The thermodynamic parameters of quinoline adsorption on coking coal were calculated. The thermodynamic parameters indicated that the adsorption process is exothermic and is a physical adsorption. The △S° value indicated that the adsorption entropy decreased because the adsorbate molecule was under restrictions after it adsorption on the coal surface. The coal adsorption method for removing refractory organic pollutants is a great hope for achieving zero emission waste water for a coking plant.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 214-227
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Pretreatment of coking wastewater by an adsorption process using fine coking coal
    Autorzy:
    Gao, L.
    Li, S.
    Wang, Y.
    Gui, X.
    Xu, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/110417.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    coking coal
    coking wastewater
    adsorption
    COD
    phenol
    Opis:
    A new technique for pretreatment of coking wastewater is introduced based on the concept of circular economy. Coal is fed into a coking system after adsorption. This study validates the feasibility of using coking coal to adsorb organic pollutants in coking wastewater. The sorption kinetics and equilibrium sorption isotherms of coking coal for removal of chemical oxygen demand (COD) and phenol from coking wastewater was also discussed in this paper. Gas chromatograph/mass spectroscopy (GC/MS) was used to detect changes in the quality of coking wastewater. The results showed that when coking coal dosage was 120 g/dm3, 65% of COD and 34% of phenol in waste water can be removed after 40 min of agitation. The surface functional groups of coking coal before and after adsorption were observed with a Fourier transform infrared spectrometer. The kinetics of COD and phenol adsorption from coking wastewater by coking coal fitted the pseudo second-order model. The adsorption process of coking coal can be classified into two categories, namely, rapid and slow. The Freundlich isotherm provided a better fit with all adsorption isotherms than the Langmuir isotherm. Coking coal could be a suitable low-cost adsorbent for recalcitrant organic pollutants.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 422-436
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Energy feature of a multi-flow column flotation process
    Autorzy:
    Cheng, G.
    Yu, Y.
    Ma, L.
    Xia, W.
    Xu, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/109768.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation column
    turbulent kinetic energy
    turbulent dissipation rate
    bubble
    Opis:
    A cyclonic-static micro-bubble flotation column (FCSMC) has been widely used in mineral separation. FCSMC includes countercurrent, cyclone and jet flow mineralization zones in a single column. In this study, the energy feature of the three different zones was compared. The turbulent flow was evaluated in terms of the turbulent kinetic energy (k) and the turbulent dissipation rate (ε). An appropriate computing model was determined by comparing the flow field value measured by PIV with the results of the Fluent numerical simulation. Jet flow separation exhibited the maximum k and ε values among the three columns, whereas counter-current separation displayed the minimum values. The high circulating volumetric flowrate means great energy input and turbulent intensity. The higher turbulent dissipation rate, the smaller the bubble is. The better performance of the FCSMC was mainly attributed to the multiple mineralization steps. The floatability of mineral particles gradually decreases with an increase in flotation time, the mineralization energy gradually increased to overcome the decrease in mineral floatability. By contrast, the countercurrent was beneficial for recovering the coarse particles, and the jet flow was beneficial for recovering the fine particles.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1266-1284
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption mechanism of sodium oleate on titanium dioxide coated sensor surface using quartz crystal microbalance with dissipation
    Autorzy:
    Fan, G.
    Liu, J.
    Cao, Y.
    Feng, L.
    Xu, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/110014.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    QCM-D
    TiO2 coated sensor surface
    sodium oleate
    adsorption mechanism
    Opis:
    Quartz Crystal Microbalance with Dissipation (QCM-D) was firstly applied to investigate the adsorption mechanism of sodium oleate on TiO2 coated sensor surface. The effects of pH value, sodium oleate concentration, and temperature on TiO2 coated sensor surface were evaluated systematically using the QCM-D technique. Zeta potential, surface tension, adsorption isotherms, and adsorption thermodynamics were employed to characterize the adsorption process. The results showed the advantages of QCM-D on the investigation of the adsorption process. Additionally, the electrostatic equilibrium adsorption data was well matched to the Langmuir isotherm. Based on the thermodynamic analysis, adsorption was a spontaneous and endothermic physisorption process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 597-608
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of gas holdup on the efficiency of cyclonic-static microbubble flotation column for oily wastewater treatment
    Autorzy:
    Ning, K.
    Huang, G.
    Xu, H.
    Wu, L.
    Li, X.
    Wang, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/208139.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bubble columns
    efficiency
    flotation
    wastewater treatment
    oil water separation
    kolumna flotacyjna
    efektywność
    flotacja
    oczyszczanie ścieków
    separacja wody
    Opis:
    A cyclonic-static microbubble flotation column of a novel construction was used in oil-water separation fields and has high efficiency for oil-water separation. The gas holdup is a key parameter for the evaluation of the performance of a flotation column. The gas holdup, closely related to the bubble size, bubble velocity and superficial gas velocity, is one of the most important parameters characterizing the hydrodynamics of a bubble column. The effect of gas holdup in a cyclonic-static microbubble flotation column was investigated. In addition, several operating parameters such as the circulating pressure, superficial gas velocity, and frother consumption were also investigated. The gas holdup was positively correlated to the superficial gas velocity. The gas holdup of clean water and oil wastewater increased along with the increase of the frother consumption. The separation mechanism of cyclonic-static microbubble flotation column was analyzed.
    Źródło:
    Environment Protection Engineering; 2018, 44, 2; 5-17
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A study of bubble-particle interactions in a column flotation process
    Autorzy:
    Cheng, G.
    Shi, C.
    Yan, X.
    Zhang, Z.
    Xu, H.
    Lu, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/109635.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    particle
    bubble
    column flotation
    collision
    attachment
    detachment
    Opis:
    Bubble-particle interactions play an important role in flotation. This study examines the behaviour of bubble clusters in a turbulent flotation cell. Particularly, the bubble-particle interaction characteristics in flotation are investigated. The bubble size in a flotation column was measured using an Olympus i-SPEED 3 high-speed camera. Relationships between the circulating volume, bubble size and bubble terminal velocity were discussed. Probabilities of collision, attachment, detachment and acquisition between bubbles and particles in different circulating volumes were calculated based on the flotation kinetic theory. Using the extended Derjaguin–Landau–Verwey–Overbeek (EDLVO) theory, the relationship between the potential energy and distance in bubble-particle interaction was analysed. The results demonstrated that as the circulating volume increased, the bubble size and velocity decreased. When the circulating volume increased from 0.253 to 0.495 m3/h, the bubble diameter decreased from 511 to 462 μm, and the corresponding bubble velocity decreased from 43.1 to 37.5 mm/s. When the circulating volume remained constant as the particle size increased, probabilities of collision, attachment, detachment and acquisition increased. When the particle size remained constant as the circulating volume increased, these probabilities also increased. At a constant circulating volume as the particle size increased, the absolute value of the total potential energy between the particle and bubble increased. When the distance between the bubble and particle was 30 nm, the energy barrier appeared.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 17-33
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of quinoline from aqueous solutions by lignite, coking coal and anthracite. Adsorption kinetics
    Autorzy:
    Xu, H.
    Wang, Y.
    Huagn, G.
    Fan, G.
    Gao, L.
    Li, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/110664.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quinoline adsorption
    coking coal
    kinetics
    adsorption activation energy
    coal adsorption
    Opis:
    Basing on the concept of circular economy, a novel method of industrial organic wastewater treatment by using adsorption on coal is introduced. Coal is used to adsorb organic pollutants from coking wastewaters. After adsorption, the coal would be used in its original purpose, as its value was not reduced and the pollutant was reused. Through the systemic circulation of coking wastewater zero emissions can be achieved. Lignite, coking coal and anthracite were used as adsorbents in batch experiments. The quinoline removal efficiency of coal adsorption was investigated. Both the coking coal and anthracite exhibited properties well-suited for quinoline adsorption removal. The experimental data were fitted to the pseudo-first- order and pseudo-second-order kinetic equations as well as intraparticle diffusion and Bangham models. An attempt was made to find the rate-limiting step involved in the adsorption processes. Both boundary-layer diffusion and intraparticle diffusion are likely involved in the rate-limiting mechanisms. Effect of pH on coal adsorptions by coking coal was investigated. The process of quinoline adsorption on coal was researched. The coal adsorption method for removing refractory organic pollutants is a great hope for achieving wastewater zero emission for coking plants.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 397-408
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetic research of quinoline, pyridine and phenol adsorption on modified coking coal
    Autorzy:
    Sun, X.
    Xu, H.
    Wang, J.
    Ning, K.
    Huang, G.
    Yu, Y.
    Ma, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/110365.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption kinetics
    modification
    coking coal
    coking wastewater
    Opis:
    Adsorption is widely used in wastewater treatment. In this work, the removal of quinoline, pyridine and phenol from coking wastewater by using modified coking coal, which was treated by four different modification methods i.e. acidification sodium hydroxide (5 mol/dm3), hydrochloric acid (5 mol/dm3) and acetic acid (5 mol/dm3) and low-temperature (105 oC) oxidation, was investigated. The modified coal was characterized by the surface area analysis, SEM, total acidity and basicity and FT-IR. The results showed that the surface area from high to low follows the order: modification with acetic acid, modification with hydrochloric acid, raw coal, modification with sodium hydroxide and modification with low-temperature. Experimental data were fitted to pseudo-first-order, pseudo-second-order and intra-particle diffusion. The adsorption of all followed pseudo-second-order kinetics. The result showed that the removal efficiency of coal modified by hydrochloric acid and acetic acid are higher than raw coal, while modified by sodium hydroxide and low-temperature are lower than raw coal., The coal modified by hydroxide acid had the best adsorption capacity.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 965-974
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Double tunneling induced transparency in the asymmetry quantum dot molecules
    Autorzy:
    Yu, C.
    Huang, H.
    Zhang, L.
    Xu, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/173599.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quantum dot molecule
    slow light
    tunneling induced transparency
    Opis:
    Using the density matrix theory, we have studied the double tunneling induced transparency slow light in the double asymmetry quantum dot molecules. With applied electric field, double tunneling induced transparency occur in the same time. Four absorption peaks are found near the resonance energy level in the absorption spectrum and the absorption peak can be tuned by the applied electric field. The velocity and bandwidth of the multiple-windows slow light can also be controlled by the applied electric field. In our model, with Te =0.1meV, we can get about 0.001c and 20GHz bandwidth in each transparency window. Such a property may be applied in all optical buffers, optical switching and filter.
    Źródło:
    Optica Applicata; 2016, 46, 3; 473-481
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Polarization dependence of patterning effects in quantum well semiconductor optical amplifier-based wavelength conversion
    Autorzy:
    Qin, C
    Shen, W
    Zhao, J.
    Yu, H.
    Xu, E
    Powiązania:
    https://bibliotekanauki.pl/articles/173469.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    semiconductor optical amplifiers
    polarization
    patterning effect
    Opis:
    In this paper, polarization dependence of patterning effects in quantum well semiconductor optical amplifier-based wavelength conversion is experimentally and theoretically investigated. The carrier and photon density rate equations are numerically solved by using the time-domain traveling wave model. The material gain calculation, including the strain effect in the active layer, is based on the k·p method. By comparing experimental and computational results, it is demonstrated that the polarization of the injection signal has a significant influence on the gain recovery time of quantum well semiconductor optical amplifier. Under the cross-polarized signals injection, the output signals suffer the weakest and strongest patterning effects both for unstrained and tensile strained quantum well semiconductor optical amplifiers.
    Źródło:
    Optica Applicata; 2015, 45, 2; 163-172
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analysis of the influence of the transducer and its coupling layer on round window stimulation
    Autorzy:
    Liu, H.
    Xu, D.
    Yang, J.
    Yang, S.
    Cheng, G.
    Huang, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/306655.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    słuch
    stymulacja
    przetwornik
    RW
    FEM
    implantable middle ear hearing device
    round window stimulation
    transducer
    coupling layer
    finite element analysis
    Opis:
    Purpose: In this work, a finite element study is proposed to evaluate the effects of the transducer and its coupling layer on the performance of round window (RW) stimulation. Methods: Based on a set of micro-computer tomography images of a healthy adult’s right ear and reverse engineering technique, a coupled finite-element model of the human ear and the transducer was constructed and verified. Then, the effect of the cross-section of the transducer, the elastic modulus of the coupling layer, the mass of the transducer, and the preload of the transducer were studied. Results: The increase of the transducer’s cross-section area deteriorates the RW stimulation, especially at the lower frequencies. This adverse effect of the cross-section area’s increase of the transducer can be reduced by adding a coupling layer between the transducer and the RW. However, the coupling layer’s improvement on the RW stimulation is reduced with the increase of its elastic modulus. Moreover, the mass loading of the transducer decreases the RW stimulation’s performance mainly at higher frequencies and applying a static preload on the transducer enhances its hearing compensating performance at higher frequencies. Conclusions: The influence of the transducer’s mass, the mass of the transducer, the applied static preload and the properties of the coupling layer must be taken into account in the design of the RW stimulation type implantable middle ear hearing device.
    Źródło:
    Acta of Bioengineering and Biomechanics; 2017, 19, 2; 103-111
    1509-409X
    2450-6303
    Pojawia się w:
    Acta of Bioengineering and Biomechanics
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Truncated two-stage compound parabolic concentrator for collecting human diffuse transmission light
    Autorzy:
    Gao, J.
    Han, G.
    Lu, Q.
    Ding, H.
    Xu, J.
    Sun, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/174488.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    optical design
    compound parabolic concentrator
    CPC
    non-imaging optics
    near infrared spectroscopy
    medicine optical instrument
    Opis:
    We propose an optical system employing a compound parabolic concentrator for near infrared spectroscope in noninvasive blood components testing. A truncated two-stage compound parabolic concentrator system is designed, which consists of a normal first-stage compound parabolic concentrator and a truncated second-stage compound parabolic concentrator. Using advanced ray tracing technique, the optical efficiencies of truncated two-stage compound parabolic concentrator system, ellipsoidal mirror system and non-optical-focusing mirror system are calculated to be 25.4%, 22.4% and 4.0%, respectively. Furthermore, the total length of truncated two-stage compound parabolic concentrator is only about 68 mm while the ellipsoidal mirror is 110 mm. It indicates that the truncated two-stage compound parabolic concentrator system enhances the ability of concentrating human diffuse transmission light, and it is a benefit to improve signal-to-noise ratio of noninvasive biochemical analysis system efficiently. Due to the advantage of small size, it tends to achieve a miniature instrument.
    Źródło:
    Optica Applicata; 2018, 48, 2; 325-335
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of flotation behavior and mechanism of cervantite activation by copper ions
    Autorzy:
    Wang, J.
    Wang, Y.
    Fu, K.
    Xu, L.
    Wang, Z.
    Sun, H.
    Xiao, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/110228.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    cervantite
    copper ions
    activation mechanism
    Opis:
    Copper-ion activation plays a highly important role in cervantite (Sb2O4) flotation. Without metal-ion activation, cervantite cannot be floated by sodium oleate. In this study, flotation tests were conducted to study the effect of Cu2+ on the flotation behaviours of cervantite and quartz (SiO2) as the main gangue mineral. Metal-ion adsorption capacities, zeta potentials, solution chemistry and X-ray photoelectron spectra were analyzed to study the adsorption behavior and mechanism of copper ions and sodium oleate interaction with the minerals surfaces. The results demonstrate that under weakly acidic conditions, cervantite can be flotated and separated from quartz by the addition of copper ions. The reason is that copper ions can be selectively adsorbed on the cervantite surface under weakly acidic conditions, thereby promoting the adsorption of sodium oleate onto the cervantite surface by chemical adsorption. Conversely, copper ions are weakly adsorbed on quartz surfaces below pH 6.1, and sodium oleate cannot be adsorbed on quartz surfaces by chemical adsorption. The hydroxy copper species are integral to the selective activation of cervantite over quartz.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 814-825
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Phase features of several typical blood cells and their identification without unwrapping
    Autorzy:
    Wang, Y.
    Chen, Y
    Lü, C.
    Shang, X.
    Xu, Y.
    Wu, H.
    Zhu, X.
    Jin, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/173588.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    digital holographic phase
    nucleated cell
    phase model
    wrapped phase features
    identification
    Opis:
    The digital holographic phase microscopy (DHPM) technique which has been proposed for cellular morphology and dynamic analysis yielded highly desirable results. However, for nucleated cells (especially white blood cells (WBCs)), their submicroscopic structure has not yet been deconstructed through a phase unwrapping method due to the heterogeneity of an internal phase. By analyzing the phase heterogeneity of subclasses of WBCs, the typical phase models of them are built first in this paper; using the simulation method, the wrapped phase distributions of these models are obtained. However, by optimizing the wrapped phase maps and analyzing the relationships between them and typical blood cells, their features are selected and extracted. Then the models built are sorted out from each other successfully without unwrapping via analyzing these extracted features, which provides a valuable approach and technological base for the classification and identification of blood cells.
    Źródło:
    Optica Applicata; 2013, 43, 3; 505-514
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-14 z 14

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