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    Wyświetlanie 1-5 z 5
    Tytuł:
    Changes in the flotation kinetic of bituminous coal before and after natural weathering processes
    Autorzy:
    Xia, W.
    Peng, Y.
    Ren, C.
    Xie, G.
    Liang, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/951864.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation kinetic
    classical first-order rate constant
    natural weathering processes
    XPS
    contact angle
    Opis:
    Natural weathering processes can make coal surface more hydrophilic due to the increase of content of hydrophilic functional groups (C-O, C=O, and COOH) and the decrease of content of hydrophobic functional groups (C-C and C-H) on coal surface, and hence the flotation recovery of fine coal is reduced. In this paper, a series of flotation tests were conducted in order to investigate the changes in the flotation kinetic of bituminous coal before and after natural weathering processes. Additionally, XPS was used to indicate the changes in surface properties of bituminous coal. In the investigations the flotation kinetic was changing. The classical first-order rate constant (k) of bituminous coal flotation was reduced after the natural weathering processes. A relationship between the classical first-order rate constant (k) and the hydrophilicity ability (HA) was given.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 2; 401-410
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetics of flotation. Order of process, rate constant distribution and ultimate recovery
    Autorzy:
    Bu, X.
    Xie, G.
    Peng, Y.
    Ge, L.
    Ni, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/110034.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    kinetic mode
    kinetic order
    rate constant distribution
    ultimate recovery
    overfitting
    Opis:
    Kinetic models can be used to characterize the flotation process. In this paper, three primary parameters, namely, distribution of flotation rate constant f(K), order of flotation process n and ultimate recovery R∞ are presented to perform analysis of flotation kinetics. The flotation rate constant f(K) is a function of both the size and hydrophobicity of particles. Though the more commonly used distributions are Delta function as well as Rectangular, Kelsall and Gamma models, there is no agreement in the literature as to which distribution function better characterize the floatability distribution. The first-order models can be used to describe most mineral flotation processes, while there is also evidence that the non-integral-order equation is capable of representing the kinetic characteristics of the batch flotation process. The order is lower than 1 in the initial moments of the flotation process. The solution of ultimate recovery calculated by the least squares method is greater than 100% (R∞ >100%). An empirical model was proposed to avoid the improper phenomenon in the solution of ultimate recovery, which can improve the availability and validity of kinetic models. Finally, more attention should be paid to the overfitting resulting from the increase in the number of parameters in the statistical analysis of kinetic models.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 342-365
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation of long flame coal pretreated by polyoxyethylene sorbitan monostearate
    Autorzy:
    Ni, C.
    Xie, G.
    Li, Z.
    Bu, X.
    Peng, Y.
    Sha, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/110299.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    hydrophobicity
    low rank coal
    Tween 60
    pretreatment
    Opis:
    In this investigation, polyoxyethylene sorbitan monostearate (Tween 60) was used to improve flotation of fine long flame coal. The flotation recovery of long flame coal could be increased when long flame coal was either pretreated or conditioned with Tween 60 in a flotation cell for a period before the addition of collector. Fourier Transform Infrared (FTIR) technique was used to indicate surface properties of long flame coal. The results of FTIR show that there are many oxygen functional groups on the sur-face. Contact angle measurements were used to indicate changes in hydrophobicity of coal surface before and after Tween 60 and/or diesel pretreatments. The results of contact angle measurements show that hydrophobicity of coal can be increased by Tween 60. Tween 60 can also enhance adsorption of diesel on the coal surface, and hence floatability of long flame coal can be further improved. Tween 60 primarily enhances the flotation recovery of low density coal fractions (<1.5 and 1.5-1.8 kg/dm3). However, the increase in flotatation recovery is less significant with an excessive addition of Tween 60.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 317-327
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Theoretical investigation of vanadium oxide film with surface microstructure
    Autorzy:
    Hong, W.
    Wang, Z.
    Chen, Q.
    Sheng, C.
    Gu, G.
    Luo, P.
    Xie, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/174416.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    vanadium oxide
    VO2
    film
    surface microstructure
    photonic band edge
    dispersion material
    Opis:
    This paper presents a method to design a surface microstructure of vanadium oxide to enhance optical absorption. This method, using a density of eigenfrequency, can be calculated by a planar wave expand method, to indicate the absorption efficiency of a dispersion material, which can be used as an approach method for further design. Based on this, a nanostructure-based vanadium oxide film is designed and simulated to validate this method. The simulation results show that the tendency of density of eigenfrequency is corresponding to the tendency of optical absorption enhancement. Moreover, this structure can achieve high optical broadband absorption when the material dispersion is considered. High optical absorption enhancement can be achieved by adjusting the geometrical parameters; our maximum overall enhancement absorption ratio was 31.84% at the metal phase, which can be attributed to the enhancement effect of a photonic band edge.
    Źródło:
    Optica Applicata; 2017, 47, 4; 601-609
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparison of float-sink and progressive release flotation of ground products of coal middlings
    Autorzy:
    Xie, W.
    He, Y.
    Luo, C.
    Zhang, X.
    Li, H.
    Yu, J.
    Wang, H.
    Shi, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/109500.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    coal middlings
    float-sink
    progressive release flotation
    XPS
    EDX
    Opis:
    An additional recovery of coking coal middlings can be utilized for increasing of the concentrate yield of coking coal. A combined flow sheet of comminution and flotation can realize this target. To investigate the effect of grinding process on further flotation of ground products, progressive release flotation tests were used to compare with the float-sink tests, which were regarded as a criterion. Coal middlings were ground by wet-milling with iron balls to <0.5 mm. Curves of ash vs. cumulative yields of sized products indicated that the concentrate yield of coal separated by progressive release flotation was lower than that of coal benefited by the float-sink test, with the same ash for four size fractions (0.5-0.25 mm, 0.25-0.125 mm, 0.125-0.074 mm and <0.074 mm). Distributions of elements conducted by energy disperse spectroscopy (EDX) showed that associated kaolinite was liberated and exposed on the surface. It led to the shift of local surface property from hydrophobicity to hydrophilicity. Meanwhile, analyses of chemical property performed by an X-Ray photoelectron spectrometer (XPS) depicted that the hydrophilic mineral FeOOH, which generated in the grinding process, was adsorbed on the coal surface. Flotation of the ground products were worsened due to the increase of hydrophilicity of the coal surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 2; 675-684
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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