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    Wyświetlanie 1-8 z 8
    Tytuł:
    Adsorption of quaternary ammonium salt hydrophobic modifiers on the α-quartz (001) surface: a density functional theory study
    Autorzy:
    Liu, Chunfu
    Wang, Weitao
    Wang, Han
    Zhu, Chenyu
    Ren, Bao
    Powiązania:
    https://bibliotekanauki.pl/articles/24085768.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    α-quartz (001) surface
    quaternary ammonium salt
    density functional theory
    adsorption mechanism
    Opis:
    To investigate the adsorption mechanism of quaternary ammonium salt on the α-quartz (001) surface, the adsorption models of hydrophobic modifiers 1231, 1431, 1631 and 1831 were constructed and simulated using the density functional theory (DFT). Results indicate that the adsorption energy of quaternary ammonium salt increases with the increase of carbon chain length, and the adsorption en-ergy reaches the maximum at 18 carbon atoms; however, the adsorption capacity of 1631 is weak owing to the carbon chain deflection. Based on the Mulliken bond population analysis, reagent 1831 has the strongest interaction with α-quartz (001) surface compared with 1231, 1431 and 1631; and during the adsorption process, charge transfer and electrostatic attraction occur between the reagent and α-quartz (001) surface with similar degrees of charge transfer observed. This study emphasizes that electrostatic attraction plays a key role in the adsorption process, while the week hydrogen bonding plays a second-ary role.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 170260
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on bubble characteristics of flotation column in hematite reverse cationic flotation process
    Autorzy:
    Wang, Weizhi
    Han, Jikang
    Powiązania:
    https://bibliotekanauki.pl/articles/1450070.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    column flotation
    bubble generator
    GE-609
    circularity
    bubble diameter
    bubble Sauter diameter
    Opis:
    In the self-designed flotation column simulation system, the foaming characteristics of the micro-bubble countercurrent contact flotation column used in the hematite cation column flotation process are systematically studied. The objective of this study is to investigate the bubble generation by a bubble generator in the flotation column. The bubble image was obtained by the high-speed camera recorder, and the bubble diameter was calculated and analyzed by image processing software. The distribution characteristics of the bubble size under different aeration conditions and with different reagent concentrations were investigated. The results show that as the aeration increases, the average diameter bubbles increases, the bubble size distribution changes from narrow to wide, and the number of small bubbles decreases. The cationic collector GE-609 can change the bubble shape. As the concentration increases, the bubble shape gradually changes from an irregular shape to a standard spherical shape. When the concentration of GE-609 exceeds 2.5 mg/dm3, the average circularity C of the bubbles in the bubble group stabilizes at 1, and the increase in concentration no longer changes the bubble shape. GE-609 also has an efficient foaming effect, as the concentration increases, the bubble diameter distribution changes significantly, the proportion of small bubbles increases, and the proportion of large bubbles decreases significantly. When the critical concentration is exceeded, the bubble diameter distribution probability density peak width no longer changes significantly. Compared with the two types of alcohol foaming agents, GE-609 produces a bubble Sauter diameter close to that of 2-octanol and slightly lower than terpineol.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 1; 64-75
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on gas holdup characteristics of micro-bubble countercurrent contacting flotation column
    Autorzy:
    Han, Jikang
    Wang, Weizhi
    Li, Ran
    Powiązania:
    https://bibliotekanauki.pl/articles/1449071.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    column flotation
    conductance method
    pressure drop method
    gas holdup
    GE-609
    Opis:
    In order to explore the gas holdup distribution of the microbubble countercurrent contact flotation column in the hematite column cationic reverse flotation process, respectively using conductance method and pressure drop method for air and water as experimental medium characteristics research of flotation column, the research group carries on the gas holdup, examines the aeration quantity, the fill medium and cation collector alkyl polyamine ether (An amine collector―GE609 which consists of four elements: carbon, hydrogen, oxygen and nitrogen)within the column on the influence of the axial and radial gas holdup. The results show that the axial gas holdup from the bottom of the column to the top of the column increases with the increase of height in the range of 0.050.07dm3/s. The radial distribution of gas holdup generally shows the distribution law of “intermediate high, low on both sides”. After the filling medium is added into the column, the radial gas holdup is evenly distributed compared with the empty column, and the gas holdup is increased. Due to the high foaming performance of GE-609, the gas holdup in the column can be increased by changing the amount of aeration and the concentration of the reagent, which can exceed 60% at the maximum. Like other alcohol foaming agents, as time passes, the effect of GE-609 weakens and the gas holdup in the column gradually decreases. The addition of quantitative HCl can improve the foaming performance of GE-609, and the gas holdup in the column is significantly improved and the stability is enhanced.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 665-675
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of optical Airy transform on non-diffracting propagation distance of finite energy Airy beams
    Autorzy:
    Chu, Xingchun
    Liu, Rongjiang
    Wang, Xiang
    Han, Zhongxiang
    Ni, Yanhui
    Powiązania:
    https://bibliotekanauki.pl/articles/2033885.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    physics optics
    non-diffracting beam
    finite energy Airy beam
    non-diffracting propagation distance
    optical Airy transform
    Opis:
    Finite energy Airy beams (FEAB) generated in laboratory have a short non-diffracting propagation distance (NDPD), which restricts its application in laser communication, laser detection and other fields. Effects of optical Airy transform (OAT) on NDPD of FEAB is analyzed. By comparing the theoretical formulas of the FEAB before and after the OAT, we find that when the transform parameter α of the OAT is larger than zero, the transverse scaling factor of the transformed FEAB is greater than that before the transformation, while the transformed exponential decay factor is smaller than that before the transformation. Using the Huygens–Fresnel diffractive integral, we derive the propagation formula of the transformed FEAB. Initial intensity distribution of FEAB before and after the OAT is compared. Propagation dynamics of the transformed FEAB with different α is numerically simulated and its NDPD is quantitatively evaluated. Results show that: with the increase of α, side lobes of the transformed FEAB increase, its main lobe and side lobes become wider than that before the transformation, and the inclination of the propagation trajectory decreases. When α is greater than half of the transverse scaling factor, the NDPD of the transformed FEAB increases rapidly.
    Źródło:
    Optica Applicata; 2021, 51, 4; 473-482
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of polysorbate 80 on the flotation of zinc oxide ores with amines
    Autorzy:
    Xie, Qiaoling
    Wang, Dandan
    Han, Zhichao
    Tao, Huchun
    Liu, Sitong
    Powiązania:
    https://bibliotekanauki.pl/articles/2146852.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    polysorbate 80
    pretreated amines
    zinc oxide
    flotation
    Opis:
    In this study, the influence of polysorbate 80 on zinc oxide flotation was investigated with an amine collector. The results indicated that the pretreatment of amines with polysorbate 80 enhanced the Zn grade and recovery obtained using zinc oxide flotation. Desliming prior to flotation is not suggested based on the results of this study. The appropriate temperature for flotation was as low as 8 °C, and this flotation method also could be applied to different types of zinc oxide ores. Under optimum flotation conditions, a concentrate with a Zn grade of 48.34% and a Zn recovery of 95.97% was obtained.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 1; 149--158
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Research on the mechanism of a mixed collector onto magnesite surface to improve the flotation separation of magnesite from hornblende
    Autorzy:
    Wang, Enlei
    Li, Xiaoan
    Dai, Shujuan
    Li, Zhao
    Zhao, Tonglin
    Song, Baoxu
    Han, Baisui
    Powiązania:
    https://bibliotekanauki.pl/articles/1445774.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    magnesite
    hornblende
    mixed collector
    flotation separation
    Opis:
    Low-grade magnesite is not effectively used mainly due to high silicon content, especially the separation of magnesite and hornblende. In this research, a novel mixture of sodium oleate and dodecyl phosphate collector was used to increase the flotation difference between magnesite and hornblende. Artificially mixed mineral concentrates grade 47.10% (MgO content) concentrate recovery of 84.45% was obtained by micro flotation test, the results showed that the mixed collector of sodium oleate and dodecyl phosphate played a better selective promotion role in the flotation of magnesite. The interaction mechanism of this mixed collector with hornblende and magnesite surfaces was investigated using Fourier transform infrared spectroscopy (FTIR), zeta potential, and X-ray photoelectron spectroscopy (XPS), which showed that the mixed collector in terms of magnesium selection was mainly adsorbed on these magnesium sites of magnesite, and the surface of magnesite thus became hydrophobic, allowing magnesite to float and separate from hornblende.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 125-138
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetics of simultaneous recovering of Au and Ag from CTs by chloridizing volatilization methods
    Autorzy:
    Weiwei, Wang
    Zhengyao, Li
    Shanshan, Yang
    Kai, Ma
    Xin, Gao
    Shaoqi, Han
    Shaochun, Hou
    Hecheng, Miao
    Powiązania:
    https://bibliotekanauki.pl/articles/27323663.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cyanide tailings
    chloridizing volatilization
    gold
    silver
    kinetics
    Opis:
    Cyanide Tailings (CTs) are known as hazardous resources that accumulate hundreds of millions of tons, threatening the ecological environment. This work proposes an eco-friendly and efficient way to recover gold and silver from CTs. The effects of calcium chloride dosage, silicon dioxide dosage, pellet moisture content, roasting temperature, and roasting time on Au and Ag chloridizing volatilization were studied. The kinetics of simultaneously recovering of gold and silver from cyanide Tailings by chlorination roasting was investigated. It was determined that the chloridizing volatilization rates increased with increasing calcium chloride dosage, temperature and decreasing silicon dioxide dosage, pellet moisture content. The chloridizing volatilization kinetics followed a shrinking core model, with inter-diffusion through gangue layer as the rate determining step. This finding is in accordance with the apparent activation energy (Ea) of 24.01 kJ•mol-1 (Au) and 24.62 kJ•mol-1 (Ag). The orders of reaction with respect to moisture content, temperature, calcium chloride dosage and silicon dioxide dosage were also achieved. The rate of reaction based on diffusion-controlled process can be expressed by semi-empirical equations. The control steps of the gold and silver recovery process were investigated by the kinetic study, which provided theoretical guidance for the optimization of the method.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 172522
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Research on new process for separation of silicon wafers and glass from decommissioned photovoltaic module
    Autorzy:
    Zhang, Jian wen
    Wang, Hai dong
    Zhang, Sheng guang
    Liang, Han
    Guo, Hui
    Tao, Si-yao
    Powiązania:
    https://bibliotekanauki.pl/articles/2175425.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    crystalline silicon photovoltaic modules
    decommissioned photovoltaic modules
    silicon
    solar cell
    tempered glass
    vibration separation
    Opis:
    In view of the disadvantages of the existing electrostatic separation process of decommissioned photovoltaic modules, which can only achieve the separation of fine silicon wafers and glass and has high energy consumption, a new process to solve the efficient dry separation of coarse silicon wafers and glass in decommissioned photovoltaic modules is proposed- the vibration separation method. Based on the theoretical analysis of the vibration separation of flaky silicon wafer and polyhedral glass particles, the effects of feed size, feed amount, vibration voltage, vibration frequency, horizontal inclination angle and longitudinal inclination angle on the product indexes of wafer and glass separation were investigated by single factor experiment. The optimal experimental conditions were obtained as follows: feed particle size +0.83mm, feed amount 0.15 t/h, vibration voltage 190 V, vibration frequency 48 Hz, horizontal inclination Angle 8°, longitudinal inclination Angle 3°. Under this optimized condition, the content of metal Si in the obtained silicon wafer product is 84.47%, the recovery rate of is 83.73%, the content of impurity SiO2 is 1.09%, and the content of SiO2 in the obtained glass product is 65.69%, and the recovery rate is 98.95%, the impurity metal Si content is 0.56%. This study provides a research idea for the industrial separation of silicon wafers and glass from decommissioned photovoltaic modules.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151679
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-8 z 8

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