- Tytuł:
- Thermodynamic analysis of the influence of potassium on the thermal behavior of kaolin raw material
- Autorzy:
-
Hernández-Chávez, Macaria
Vargas-Ramírez, Marissa
Herrera-González, Ana Maria
García-Serrano, Jesús
Cruz-Ramírez, Alejandro
Romero-Serrano, José Antonio
Sánchez-Alvarado, Ricardo Gerardo - Powiązania:
- https://bibliotekanauki.pl/articles/1448343.pdf
- Data publikacji:
- 2021
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
kaolin
thermal treatment
thermodynamic analysis
viscosity - Opis:
- The mineralogy and thermal properties of two kaolin clay samples from Agua Blanca (Hidalgo-México) were determined by XRD, SEM-EDS, TGA-DSC techniques. Kaolin clay A contains a higher $Al_2O_3$ and lower impurities $(K_2O, TiO_2, Fe_2O_3)$ amount than kaolin clay B, while the SiO2 amount is similar for both kaolin clays. A theoretical approach was carried out by a thermodynamic analysis considering the chemical composition of both kaolin clay samples with the FactSage 7.3 software. Stability phase diagrams were obtained to different K2O content from 0.1 to 3 wt % and temperatures in the range from 600 to 1600°C based on the chemical composition of the kaolin clay samples. The main mineralogical compounds predicted are andalusite $(Al_2O_3•SiO_2)$, K-Potash feldspar $(K_2O•Al_2O_3•6SiO_2)$, and the $SiO_2$ polymorphs (quartz, tridymite, and cristobalite) with small amounts of ferric-pseudobrookite $(Fe_2O_5Ti)$, and rutile $(TiO_2)$. As $K_2O$ content is increased, the amounts of mullite and tridymite decrease meanwhile the potash feld spar is increased at high temperatures. A liquid phase is formed at around 1350 and 1400°C for the kaolin clay samples A and B, respectively. The viscosity of the melt is increased for the evaluated $K_2O$ additions to 1400, 1500, and 1600°C.
- Źródło:
-
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 39-52
1643-1049
2084-4735 - Pojawia się w:
- Physicochemical Problems of Mineral Processing
- Dostawca treści:
- Biblioteka Nauki
Artykuł