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    Wyświetlanie 1-6 z 6
    Tytuł:
    Separation of rare earth elements from the leaching solution of waste phosphors by solvent extraction with Cyanex 272 and its mixture with Alamine 336
    Autorzy:
    Xing, Weidong
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/1449503.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    phosphors
    rare earth elements
    HCl solution
    solvent extraction
    Cyanex 272
    Opis:
    Waste phosphors contain rare earth elements (REEs) such as yttrium (Y), europium (Eu), cerium (Ce), terbium (Tb) and lanthanum (La). Separation of these REEs from the leaching solution of waste phosphors was investigated by solvent extraction with single Cyanex 272, binary mixture (mixture of Cyanex 272 and Alamine 336), ionic liquid (prepared by Cyanex 272 and Aliquat 336) in kerosene. The effect of solution pH and extractants concentration was mainly investigated. The results indicated that Y(III) was selectively extracted by single Cyanex 272 over the other four REEs from the HCl solution with initial pH range from 3 to 5. Synergistic extraction with the binary mixture was enough for the extraction of Y(III), Tb(III) and Eu(III) with a small amount of Ce(III). Scrubbing with pure Y(III) solution with intermediate acidity was effective in scrubbing Ce(III) from the loaded binary mixture organic phase. Stripping behavior of the Y(III), Tb(III) and Eu(III) by HCl solution was similar to each other. Tb(III) and Eu(III) can be separated by extraction with the binary mixture followed by scrubbing with pure Tb(III) solution. McCabe-Thiele diagrams were constructed for the extraction of Y(III) by single Cyanex 272 and that of Tb(III) by the mixture. A process was proposed for the separation of REEs from the leaching solution of waste phosphors by solvent extraction.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 1; 184-194
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Improvement of metal separation process from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction and ion exchange
    Autorzy:
    Nguyen, Viet Nhan Hoa
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/1446393.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    spent lithium-ion batteries
    solvent extraction
    ion exchange
    separation
    Opis:
    Spent lithium-ion batteries (LIBs) are good secondary resources for recycle and reuse. To develop a process for the separation of Cu(II), Co(II), Mn(II), Ni(II) and Li(I) with high purity from spent LIBs and circumvent some drawbacks of the previous work, solvent extraction and ion exchange experiments were done in this work. The synthetic hydrochloric acid leaching solution of 3 M was employed. Compared to Aliquat 336 (N-Methyl- N, N, N-trioctyl ammonium chloride), extraction with Cyanex 301 (bis(2,4,4-trimethylpentyl) dithiophosphinic acid) led to selective extraction of Cu(II) over other metal ions. Employing ion exchange with TEVA-SCN resin can completely separate Co(II) over Mn(II). After adjusting the pH of Co(II) free raffinate to 3, Mn(II) was quantitatively extracted by the mixture of Alamine 336 (mixture of tri-octyl/decyl amine) and PC 88A (2-ethylhexyl hydrogen-2-ethylhexylphosphonate) with two stage cross-current extraction. The synthesized ionic liquid (ALi-CY) was used for complete extraction of Ni(II), whereas Li(I) remained in final raffinate. The metal ions in the loaded organic phase were completely stripped with the proper agents (5% aqua regia for Cu(II), 5% $NH_3$ for Co(II), weak $H_2SO_4$ solution for Mn(II) and Ni(II) stripping, respectively). The experimental results revealed that purity of the metal ions in stripping solution was higher than 99.9%. A flowsheet was suggested to separate metal ions from the HCl leaching solutions of spent LIBs.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 1-17
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Separation of Co(II), Cu(II), Ni(II) and Mn(II) from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction
    Autorzy:
    Nguyen, Viet Nhan Hoa
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/1449331.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    spent lithium-ion batteries
    divalent metal ions
    solvent extraction
    separation
    Opis:
    Spent lithium ion batteries contain valuable critical metals such as cobalt, copper, lithium and nickel. In order to develop a process for the separation of the divalent metal ions from spent lithium ion batteries, solvent extraction experiments were performed by employing synthetic hydrochloric acid leaching solution. The synthetic solution contained Cu(II), Co(II), Mn(II) and Ni(II) and its acidity was 3 M HCl. Extraction with Aliquat 336 led to selective extraction of Cu(II) with a small amount of Co(II). After adding NaCl to the Cu(II) free raffinate to enhance the complex formation of Co(II), Co(II) was selectively extracted into Aliquat 336 together with Mn(II). The small amount of Mn(II) in the loaded Aliquat 336 was scrubbed by pure Co(II) solution. After adjusting the pH of the raffinate to 3, 91,3% of Mn(II) was selectively extracted over Ni(II) by the mixture of D2EHPA and Alamine 336. In this extraction, the mole fraction of D2EHPA in the mixture affected the extraction of Mn(II). McCabe-Thiele diagrams for the extraction of Cu(II) and Co(II) were constructed. Batch simulation experiments for the three stage counter-current extraction verified the selective extraction of the target metal ions in each extraction step. Namely, the total extraction percentage of Cu(II) and Co(II) was 71.6% and 98.8% respectively. Most metals in the loaded organic phase were stripped completely with the appropriate agents (1.0 M $H_2SO_4$ for Cu(II), 0.1 M H2SO4 for Co(II) and 0.3 M $HCl$ for Mn(II) stripping). A process was proposed to separate the metal ions by solvent extraction.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 599-610
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Recovery of pure palladium compound from the spent electroplating solutions by hydrometallurgical method
    Autorzy:
    Nguyen, Viet Nhan Hoa
    Song, Si Jeong
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/2146854.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    leaching
    solvent extraction
    palladium
    separation
    precipitation
    Opis:
    Electroplating of palladium (Pd) is practiced in the manufacture of electronic materials. The increasing demand for Pd metal necessitates the recovery of Pd(II) from the spent electroplating solutions. In this work, the recovery of Pd compound was studied from the cemented Pd by zinc (Zn) metal from spent electroplating solutions. Initially, the selective extraction ability of ionic liquids synthesized from commercial extractants for Pd(II) over Zn(II) from the synthetic HCl solution was investigated. Pd(II) was selectively extracted over Zn(II) from 9 M HCl solution by ALi-CY301(Nmethyl-N,N,N-trioctylammonium bis(2,4,4-trimethylpentyl) dithiophosphinic) and by ALi-I (N-methylN,N,N-trioctylammonium iodide) from weak HCl solution (pH 1). Since 9 M HCl was needed to completely dissolve Pd from the cemented Pd, ALi-CY301 was employed for the separation of Pd(II) and Zn(II) from the real HCl leaching solution of the cemented Pd. Two-stages counter-current extraction of the real HCl solution with ALi-CY301 resulted in selective extraction of Pd(II). Pd(II) was effectively stripped from the loaded ALi-CY301 by a mixture of HCl and NaClO. After oxidizing Pd(II) in the stripping solution to Pd(IV) by adding NaClO, Pd(IV) compound was synthesized by adding NH4Cl as a precipitant. By comparing leaching and extraction efficiency between hydrochloric and sulfuric acid solutions, a hydrometallurgical process consisted of HCl leaching, extraction with ALiCY301 and precipitation with NH4Cl was recommended for the recovery of pure (NH4)2PdCl6 from the cemented Pd.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 1; 88--100
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Deashing and desulphurization of fine oxidized coal by falcon concentrator and flotation
    Autorzy:
    Zhu, X.
    Tao, Y.
    Sun, Q.
    Man, Z.
    Xian, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/951856.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fine oxidized coal
    desulphurization
    deashing
    flotation
    enhanced gravity separation
    Opis:
    Flotation and enhanced gravity separation based on different separation principles were carried out to investigate the desulphurization and deashing efficiency of fine oxidized coal. Surface properties of fresh and oxidized coals were tested by XPS and results showed that the contents of hydrophobic functional groups decreased while the content of hydrophilic functional groups increased after oxidization. Floatability and density analysis results showed that the floatability of coal samples decreased sharply because of oxidation, however, density composition of coal sample only had slight changes. Separation results showed that yields of gravity concentrates outclassed that of flotation concentrates, meanwhile, ash contents and sulfur contents of gravity concentrates were far lower than that of flotation concentrates. Yields and ash contents increased with the collector dosage and achieved to be 17.83 and 26.94% respectively when the collector dosage was 1600 g•Mg-1. Yields and ash contents of gravity concentrates decreased with the centrifugal force and increased with the recoil water flow with similar sulfur content. Clean coal with yield of 53.86%, ash content of 9.81%, sulfur content of 1.47% and with a corresponding desulphurization efficiency of 44.53% was achieved at centrifugal force of 107 g and recoil water flow of 13.3 dm3•min-1. For fine oxidized coal, enhanced gravity separation has a significant advantage of the separation efficiency compared with flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 634-646
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Solvent extraction of Terbium(III) from chloride solution using organophosphorus extractant, its mixture and ionic liquid in the presence of organic acids
    Autorzy:
    Tran, Thanh Tuan
    Song, Si Jeong
    Oh, Chang Geun
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/24085863.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    extraction
    Terbium(III)
    organic acid
    ionic liquid
    buffer effect
    Opis:
    Addition of organic acids to dilute hydrochloric acid solution can improve the extraction of rare earth elements by single cationic extractants. However, the correlation between the chemical structure of organic acids and the extraction of REEs as well as the variation in equilibrium pH has not been elucidated. In this study, we investigated the extraction of Tb(III) from dilute HCl solutions containing an organic acid like formic, lactic, fumaric, or maleic acid. As extractants, single Cyanex 272, a mixture of Cyanex 272 and Alamine 336 (Ala336-Cy272), and an ionic liquid (ALi-Cy272) synthesized by Cyanex 272 and Aliquat 336 were used. The speciation of Tb(III) in dilute HCl solutions containing organic acids was analyzed. In extraction of Tb(III), organic acids showed two roles as complexing and buffering agent, which depended on the chemical structure of the acids. There was some difference in the extraction of Tb(III) between single Cyanex 272 and ionic liquid, ALi-Cy272. During extraction with ALi-Cy272, formic and lactic acid negatively affected the extraction of Tb(III). The fact that the chemical structure of organic acids affected the extraction of Tb(III) from dilute HCl solution by the studied extractants can provide important information on the selection of suitable extraction systems.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162714
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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