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Wyświetlanie 1-2 z 2
Tytuł:
Prężność par butanolu jako komponentu benzyn silnikowych
Vapour pressure of butanol as a component of gasoline
Autorzy:
Rogowska, Delfina
Powiązania:
https://bibliotekanauki.pl/articles/1834265.pdf
Data publikacji:
2020
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
benzyna E10
biobutanol
liczby blendingowe prężności par
E10 gasoline
biobuthanol
vapour pressure blending numbers
Opis:
The policy on motor fuels decarbonizastion results in a steady increase in interest in biofuels. Among them, the most popular gasoline components are ethanol and ETBE ether. However, because of advantageous performance properties and new production technologies of biobuthanol, this gasoline component is gaining importance. During gasoline blending, (bio-)buthanol as well as ethanol shows nonlinear effects in case of many parameters, it is that parameter value calculated based on the share and properties of components that is different than that measured in a laboratory. This applies mainly to such parameters as octane numbers, distillation parameters, vapour pressure. It should be noticed that linear programming is used very often for optimization and production planning, which requires a set to be linear. Having the above in mind, blending numbers (additive mixing factors) are calculated for the above parameters, which reflect “behavior” of a given component in specific component set. In this article, the blending number for vapour pressure of n-buthanol and i–buthanol in combination with other oxygen components and gasoline components for gasoline containing above 2.7% (m/m) of oxygen were assessed. The experiment was planned according to modified Andreson’s and McLean’s methodology of planning of experiments. In order to establish the blending numbers, the “regression” statistical data analysis function, which is a component of Excel sheet Analysis ToolPak, was used. In the set of such components as ethanol, ETBE, buthyl alcohols and hydrocarbon components, the vapor pressure blending number of ethanol is much higher than its real vapor pressure value (98.0 kPa vs 16.1 kPa), the ETBE blending value is lower (the blending number is 15.7, the determinate number is 32.0 kPa). In turn, the established vapour pressure blending value of both n-buthanol and i-buthanol is close to the determinate value (the determinate value for n-buthanlo is 1.3 kPa, the blending number is 2.0 kPa, for i-buthanol the determine value is 2.6 kPa, the blending number is 3.0 kPa).
Źródło:
Nafta-Gaz; 2020, 76, 5; 340-348
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Problemy kompatybilności rop naftowych
Crude oil compatibility problems
Autorzy:
Krasodomski, Wojciech
Altkorn, Beata
Duda, Anna
Szuflita, Sławomir
Krasodomski, Michał
Powiązania:
https://bibliotekanauki.pl/articles/1834263.pdf
Data publikacji:
2020
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
ropa naftowa
kompatybilność
test plamkowy
p-value
równoważnik ksylenowy
liczba nierozpuszczalności
liczba rozpuszczalności
crude oil
compatibility
spot test
xylene equivalent
Insolubility Number
Solubility Blending Number
Opis:
Crude oil processed in refineries is a complex mixture of hydrocarbons in which some heteroorganic compounds are dissolved or suspended. These types of systems are usually characterized by some instability, associated with precipitation of multiphase structures depending on the chemical nature of the oil components. These phenomena affect the proper course of refinery processes. The formed suspensions, and consequently sediments, associated with a change in the chemical nature of the matrix (mixtures of hydrocarbons derived from petroleum), can block the refinery infrastructure – tanks and pipelines – as well as heat exchangers. These deposits can be transferred to the liquid phase only by increasing matrix polarity. Therefore, to prevent thermally irreversible peptization and sedimentation of asphaltene – resin structures and aggregates, it is necessary to assess the compatibility of processed oil as precisely as possible. When composing the charge, it is necessary to assess and test the compatibility of mixed crude oils. This work summarizes information on both the practical and the theoretical aspects of crude oil compatibility. The principles of petroleum classification, contemporary views on the construction of colloidal structures suspended in a hydrocarbon environment, theoretical basis of knowledge about the properties of hydrocarbons as solvents were discussed, and the techniques and methods used to assess the compatibility of petroleum raw materials were analyzed. Blotter tests are presented, from the simplest spot test, originally developed for testing the presence of insoluble particles in asphalt and its variants, to automated methods (the PORLA analyzer). Parameters characterizing compatibility are compared, the method of determining parameters such as the p-value, the xylene equivalent or the Heithaus coefficients and their use is presented. The article also discusses other parameters describing the petroleum compatibility model and their components, such as solubility parameters, defined as the Insolubility Number (IN), which is also a measure of the solubility of the asphaltenes, and the solubility blending number Solubility Blending Number (SBN), determining the oil’s ability to dissolve asphaltenes.
Źródło:
Nafta-Gaz; 2020, 76, 5; 332-339
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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