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Wyświetlanie 1-2 z 2
Tytuł:
Microwave plasma for hydrogen production from liquids
Autorzy:
Czylkowski, D.
Hrycak, B.
Miotk, R.
Jasiński, M.
Mizeraczyk, J.
Dors, M.
Powiązania:
https://bibliotekanauki.pl/articles/148564.pdf
Data publikacji:
2016
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
dry reforming
ethanol
hydrogen production
isopropanol
kerosene
microwave plasma
Opis:
The hydrogen production by conversion of liquid compounds containing hydrogen was investigated experimentally. The waveguide-supplied metal cylinder-based microwave plasma source (MPS) operated at frequency of 915 MHz at atmospheric pressure was used. The decomposition of ethanol, isopropanol and kerosene was performed employing plasma dry reforming process. The liquid was introduced into the plasma in the form of vapour. The amount of vapour ranged from 0.4 to 2.4 kg/h. Carbon dioxide with the fl ow rate ranged from 1200 to 2700 NL/h was used as a working gas. The absorbed microwave power was up to 6 kW. The effect of absorbed microwave power, liquid composition, liquid fl ow rate and working gas fl ow rate was analysed. All these parameters have a clear infl uence on the hydrogen production effi ciency, which was described with such parameters as the hydrogen production rate [NL(H2)/h] and the energy yield of hydrogen production [NL(H2)/kWh]. The best achieved experimental results showed that the hydrogen production rate was up to 1116 NL(H2)/h and the energy yield was 223 NL(H2) per kWh of absorbed microwave energy. The results were obtained in the case of isopropanol dry reforming. The presented catalyst-free microwave plasma method can be adapted for hydrogen production not only from ethanol, isopropanol and kerosene, but also from different other liquid compounds containing hydrogen, like gasoline, heavy oils and biofuels.
Źródło:
Nukleonika; 2016, 61, 2; 185-190
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of alpha and gamma radiolysis on Pu retention in the solvent TBP/kerosene
Autorzy:
Gao, Y
Zheng, W.
Cao, X.
Chen, S.
Powiązania:
https://bibliotekanauki.pl/articles/148296.pdf
Data publikacji:
2014
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
purex process
TBP solvent
alpha radiolysis
gamma radiolysis
Pu retention
Opis:
In light of the issue of radiolysis of the solvent system in PUREX process, alpha and gamma radiation stability of tributyl phosphate (TBP)/kerosene (OK) have been studied in this paper, in which 238Pu dissolved in the organic phase and 60Co are selected as alpha and gamma irradiation sources, respectively. The amount of the degradation products not easily removed after the washing process has been measured by the plutonium retention. The effects of the absorbed dose, the TBP volume fraction, the cumulative absorbed dose and the presence of UO2 2+ and Zr4+ on the radiolysis of the solvents have been investigated. The results have indicated that the Pu retention increases with the increase of the absorbed dose after alpha or gamma irradiation, and is larger for the solvent containing less TBP. There is competition between UO2 2+ and Pu4+ to complex with the degradation products, and Zr4+ accelerates the radiolysis of the system.
Źródło:
Nukleonika; 2014, 59, 4; 123-128
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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