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Wyszukujesz frazę "Kinetic analysis" wg kryterium: Wszystkie pola


Wyświetlanie 1-2 z 2
Tytuł:
Critical analysis of underground coal gasification models. Part II: Kinetic and computational fluid dynamics models. Literary studies and comparison of models
Autorzy:
Żogała, A.
Powiązania:
https://bibliotekanauki.pl/articles/91950.pdf
Data publikacji:
2014
Wydawca:
Główny Instytut Górnictwa
Tematy:
coal gasification
kinetic models
CFD models
zgazowanie węgla
model kinetyczny
model CFD
Opis:
Purpose Underground coal gasification, as a complex and technically difficult process, in many aspects requires the support provided by computer simulations. There are a lot of mathematical models of UCG, some of them are concentrated with the forecast of syngas composition. The most important may be divided into three groups: equilibrium, kinetic and CFD models. The purpose of this work was the detailed critical analysis of more advanced approaches (than equilibrium considerations) applied in simulations of the coal conversion process – both kinetic and based on computational fluid dynamics. The other aim of this paper was the comparative analysis of the most important models of underground coal gasification. Methods Literary studies, concerned with the features and mathematical description of kinetic and CFD models of coal gasification, were used as the research method applied in the work presented. Compilation of the kinetic parameters of gasification reactions was an important part of this article. For that purpose the analysis of Polish and foreign papers, monographs and university handbooks was undertaken. Results Critical analysis of kinetic and CFD models of coal gasification (together with their mathematical formulation) was the result of considerations presented in this article. Kinetic equations were shown separately for pyrolysis, homogenous and heterogeneous reactions. In the case of CDF models, except for the presentation of the conservation equation, the most important methods of modeling turbulence are described (for the reason that this phenomenon may have significant inflence on the final results). Practical implications The work presented describes practical issues connected with kinetic and CFD models, focusing on their capabilities, drawbacks and possible application problems. Originality/ value This paper presents state of art in the field of coal gasification modeling using kinetic and computational fluid dynamics approach. The paper also presents own comparative analysis (concerned with mathematical formulation, input data and parameters, basic assumptions, obtained results etc.) of the most important models of underground coal gasification.
Źródło:
Journal of Sustainable Mining; 2014, 13, 1; 29-37
2300-1364
2300-3960
Pojawia się w:
Journal of Sustainable Mining
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of kinetic parameters of coal pyrolysis to simulate the process of underground coal gasification (UCG)
Autorzy:
Urych, B.
Powiązania:
https://bibliotekanauki.pl/articles/92059.pdf
Data publikacji:
2014
Wydawca:
Główny Instytut Górnictwa
Tematy:
underground coal gasification
pyrolysis
thermogravimetric analysis
kinetic parameters
podziemne zgazowanie węgla
piroliza
analiza termograwimetryczna
parametry kinetyczne
Opis:
Purpose The aim of the research presented in this paper was to determine the values of the kinetic parameters of coal pyrolysis from two areas of the planned experiment, UCG, i.e. the Barbara Experimental Mine of the Central Mining Institute and the Wieczorek Mine. Methods The thermal decomposition of coal analysis used the thermogravimetric technique. The test was carried out in a temperature range of 298-1173 K in a nitrogen atmosphere for three fixed heating rates, β – 5, 10, and 15 K/min. A selection of sample heating rates of coal and reaction environments were designed to reflect the conditions seen during the process of underground coal gasification. The kinetic parameters were determined by using modified Coats-Redfern, Kissinger and Mianowski-Radko methods. Results The values of the activation energy, E, and the pre-exponential factor, A, were determined for a given model of the first order decomposition reaction of coal. The study successfully compared kinetic parameters of the tested coals. Practical implications Designated kinetic parameters may be used to model the process of pyrolysis and – as preliminary data – for installation design of pilot underground coal gasification. Originality/ value The devolatilization of a homogenous lump of coal is a complex issue. Currently, the CFD technique (Computational Fluid Dynamics) is commonly used for the multi-dimensional and multiphase phenomena modelling. The mathematical models, describing the kinetics of the decomposition of coal, proposed in the article can, therefore, be an integral part of models based on numerical fluid mechanics.
Źródło:
Journal of Sustainable Mining; 2014, 13, 1; 3-9
2300-1364
2300-3960
Pojawia się w:
Journal of Sustainable Mining
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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