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Wyszukujesz frazę "Arulkumaran, R." wg kryterium: Autor

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    Wyświetlanie 1-7 z 7
    Tytuł:
    Synthesis and Hammett spectral correlation studies of some substituted cyanopyridine compounds
    Autorzy:
    Arulkumaran, R.
    Manikandan, V.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1179260.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Hammett constants
    IR and NMR spectra
    Single and multi-correlation analysis
    Substituted cyanopyridine
    Opis:
    About ten substituted cyanopyridine compounds have been synthesized and the purities of these pyridines were examined with their physical constants, analytical and spectroscopic data provided in the literature. They are characteristic infrared stretches and NMR chemical shifts were assigned and they are correlated with Hammett substituent constants using single and multi-linear regression analysis. From the results, the effect of substituents on the spectral data of cyanopyridine has been discussed.
    Źródło:
    World Scientific News; 2017, 80; 239-255
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines
    Autorzy:
    Arulkumaran, R.
    Manikandan, V.
    Christuraj, P.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182844.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (e)-1-benzylidene-2-(diphenylmethylene) hydrazine
    ir and nmr spectra
    hammett correlations
    Opis:
    About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.
    Źródło:
    World Scientific News; 2017, 62; 93-110
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Hammett spectral LFER of some antioxidant substituted benzylidene hydrazines
    Autorzy:
    Thirunarayanan, G.
    Manikandan, V.
    Arulkumaran, R.
    Rajarajan, M.
    Sathiyendiran, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182556.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-(2
    5-dinitrophenyl)-2-(substituted benzylidene)hydrazines
    Hammett correlations
    IR spectra
    NMR spectra
    antioxidant activity
    hydroxy apatite
    Opis:
    About nine (E)-(2,5-dinitrophenyl)-2-(substituted benzylidene)hydrazines have been synthesized by hydroxy apatite catalyzed condensation of 2,4-dinitrophenyl hydrazine and substituted benzaldehydes under microwave irradiation conditions. The obtained yields of these hydrazines are more than 85%. The purities of synthesized hydrazines are examined by the analytical and spectroscopic data reported earlier. The infrared spectral C=N, NH frequencies (v, cm-1) and the NMR spectral chemical shifts of CH, NH protons and carbons are assigned and are correlated with Hammett substituent constants, F and R parameter using single and multi-regression analysis. From the results of statistical analysis the effects of substituent on the group frequencies have been discussed. The antioxidant activities of these synthesized hydrazines were measured using DPPH radical scavenging method. The hydroxy- and methoxy- substituted hydrazines shows significant antioxidant activity.
    Źródło:
    World Scientific News; 2017, 69; 201-219
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Hammett spectral QSAR analysis of some (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
    Autorzy:
    Vijayakumar, S.
    Manikandan, V.
    Arulkumaran, R.
    Christuraj, P.
    Sundararajan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1076503.pdf
    Data publikacji:
    2019
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
    IR
    NMR spectra
    QSAR study
    UV
    regression analysis
    Opis:
    About nine substituted (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones have been synthesized by solvent-free method. These enones were analyzed by spectral techniques. The characteristic spectral frequencies were correlated through Hammett equation with Hammett substituent constants, F and R parameters using single and multi-regression analysis method. From the statistical analysis results, the quantitative structure activity relationships have been discussed by means of effects of substituents on the spectral frequencies.
    Źródło:
    World Scientific News; 2019, 115; 52-67
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Infrared and 13C NMR Spectral Correlation Analysis of Some Substituted Oxazepin Based Ketone and Thione Derivatives with Hammett Constant
    Autorzy:
    Sathiyamoorthi, K.
    Kamalakkannan, D.
    Suresh, R.
    Sakthinathan, S. P.
    Arulkumaran, R.
    Sundararajan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1193044.pdf
    Data publikacji:
    2016
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Oxazepins
    IR
    13C NMR
    Hammett constant
    F and R parameter
    Single and multi-regression analysis
    Opis:
    Single and multi-regression analysis was applied for the corrosion study of transmission of substituent effects on IR carbonyl stretching frequencies and 13C chemical shifts of some substituted oxazepin compounds. The substituent effects were estimated on the basis of results of the statistical analysis. The differences among the obtained regression coefficients were discussed in terms of the relative importance of the field, inductive and resonance effects of substituent.
    Źródło:
    World Scientific News; 2016, 58; 48-64
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and effects of substituent on (E)-styryl-3-methyl-2-thienyl chalcones
    Autorzy:
    Christuraj, P.
    Geetha, C.
    Vanangamudi, G.
    Arulkumaran, R.
    Manikandan, V.
    Rajakumar, P. R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1161056.pdf
    Data publikacji:
    2018
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones
    FT-IR & NMR spectra
    Fly-ash:H3PO4 nanocatalyst
    Hammett correlation analysis
    Substituent effects
    UV
    solvent-free synthesis
    Opis:
    Series of eleven substituted of (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones compounds by cross-aldol condensation reaction of 3-methylthiophene-2-carbaldehyde with various substituted acetaldehyde in the occurrence of Fly-Ash: H3PO4 catalyst. The effect of catalytic activity of this fly-ash:H3PO4 nanocatalyst was studied with the obtained yield of products under solvent-free conditions. The synthesized substituted (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The infrared group frequencies of ʋ(cm-1) of COs-cis & s-trans, CHip and CHop, CH=CHop, >C=C
    Źródło:
    World Scientific News; 2018, 112; 55-73
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and spectral correlation studies of some (E)-N′-1-(substituted benzylidene) benzohydrazides
    Autorzy:
    Manikandan, V.
    Balaji, S.
    Senbagam, R.
    Vijayakumar, R.
    Rajarajan, M.
    Vanangamudi, G.
    Arulkumaran, R.
    Sundararajan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1162032.pdf
    Data publikacji:
    2018
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-N’-1-(substituted benzylidene) benzohydrazides
    IR and NMR spectra and Correlations
    UV
    Opis:
    About ten substituted (E)-N’-1-(substituted benzylidene) benzohydrazides have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. The effects of substituent on these data have been studied using Hammett equation.
    Źródło:
    World Scientific News; 2018, 111; 26-39
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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