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Wyświetlanie 1-3 z 3
Tytuł:
Usuwanie ortofosforanów ze ścieków syntetycznych o niskim pH z wykorzystaniem metody roztwarzania metali i elektrokoagulacji
Orthophosphates removal from synthetic sewage with low pH using the electrocoagulation and the metal digestion method
Autorzy:
Wysocka, I.
Ładuch, W
Powiązania:
https://bibliotekanauki.pl/articles/1819409.pdf
Data publikacji:
2012
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
wastewater
coagulation
steel
Opis:
Unquestionably, effective methods of phosphorus compound removal include precipitation methods. These methods include: electrocoagulation and the experimental metal digestion method. Metal solution and electrocoagulation in this paper use corrosion effect of steel plates to couse iron ions to get through into the synthetic wastewater. Iron ions that are present in solution induct deposition and sorption of phosphate compounds, which subsequently are removed. The real mechanism is quite complicated and consists of transforming phosphorus compounds into insoluble forms, and then separating them from the sewage by flotation, sedimentation, filtration. Electrocoagulation requires the electrical current to be connected with electrodes. The research was conducted with usage of steel electrodes with 1414 cm2 contact surface, which were corroding and releasing iron ions responsible for orthophosphate deposition. The electrocoagulation process was using a direct electrical current with intensity of 0.1 A. Synthetic wastewater containing 10.5 mg P/dm3 ortophosphorus and 3 pH was used. The main object of this paper was to compare electrocoagulation and metal solution as methods of phosphate removal from synthetic wastewater with usage of reactors containing steel electrodes. The analysis were conducted in acidic environment. Additionally there was examined content of the iron and pH in the solution. The article presents a study into comparative tests were conducted on a laboratory scale. The research indicates, that electrocoagulation is a method of wastewater treatment that takes less time than metal solution. Complete phosphate removal in the environment at pH 3 with electrocoagulation was achieved after 240 minutes, whereas with metal solution method it took 420 minutes. The downside of both methods is the secondary contamination of wastewater with iron ions.
Źródło:
Rocznik Ochrona Środowiska; 2012, Tom 14; 790-799
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Porównanie efektów usuwania ortofosforanów ze ścieków metodą elektrokoagulacji i metodą roztwarzania metali
Comparison of the results of orthophosphates removal from sewage using electrocoagulation method and metal digestion method
Autorzy:
Wysocka, I.
Giza, M. N.
Powiązania:
https://bibliotekanauki.pl/articles/1819439.pdf
Data publikacji:
2011
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
ortofosforanty
roztwarzanie metali
elektrokoagulacja
orthophosphates
dissolution of metals
electrocoagulation
Opis:
Celem niniejszych badań było porównanie efektów usuwania związków fosforu (ortofosforanów) z wód z dodatkiem ortofosforanów, z wykorzystaniem dwóch metod: metody elektrokoagulacji (z wykorzystaniem procesów elektrochemicznych z użyciem prądu stałego) i metody roztwarzania metali (z wykorzystaniem procesów korozyjnych).
There is a search in progress for some efficient methods of removing biogenic compounds from the treated sewage. Unquestionably, effective methods of phosphorus compounds removal include precipitation methods. The most common is the chemical precipitation method based on applying iron, aluminium or calcium salt to the solution and electrocoagulation. These methods utilise low solubility of metal phosphates and their sorption on the surfaces of the forming agglomerates. The real mechanism is quite complicated and consists of transforming phosphorus compounds into insoluble forms, and then separating them from the sewage by flotation, sedimentation, filtration. The method of iron solution should also be accounted into similar physical and chemical methods. The main difference between the aforementioned methods lies in the way of applying the precipitation agent to the solution. The method of iron solution is based on similar premises as the electrocoagulation method, however, metal ions here are dissolved into the solution as a result of spontaneous corrosion processes and, due to the further transformations in the sewage environment, they are to be responsible for phosphorus removal. The article presents comparative tests on a laboratory scale. The electrocoagulation method and metal digestion method were compared with regard to the effectiveness of orthophosphates removal from synthetic sewage. The comparison of both methods suggests that they can bring similar results of removing phosphorus (ortophosphates) from sewage. The process of reduction of concentration of orthophosphates in sewage occurs faster when the electrocoagulation method is used. However, with a longer test duration, better results are achieved using the metal digestion method. It was also noted that both methods introduce different amounts of iron into the solution. The methods differ with regard to the amount of iron remaining in the sewage in a suspended form. This indicates a better use of iron ions in the metal digestion method and it slightly limits the problem of an excessive amount of sludge.
Źródło:
Rocznik Ochrona Środowiska; 2011, Tom 13; 1915-1925
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Usuwanie ortofosforanów ze ścieków syntetycznych o neutralnym i alkalicznym odczynie z wykorzystaniem metody roztwarzania metali i elektrokoagulacji
Orthophosphates Removal from Synthetic Neutral and Alkaline Wastewater Using the Electrocoagulation and the Metal Dissolution Methods
Autorzy:
Wysocka, I.
Kisielewska, M.
Rynkiewicz, M. R.
Konopka, S.
Powiązania:
https://bibliotekanauki.pl/articles/1819125.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
usuwanie ortofosforanów
ścieki syntetyczne
pH
chitin
orthophosphates removal
wastewater
Opis:
The main objective of this paper was to compare efficiency of electrocoagulation and metal dissolution methods in orthophosphate removal from synthetic wastewater at 7.0 and 8.0 pH. The research was conducted with usage of steel electrodes with 1414 cm2 contact surface, which were corroding and releasing iron ions responsible for orthophosphate precipitation. The electrocoagulation process with alkaline wastewater (8.0 pH) was additionally using a direct electrical current with intensity of 0.1 A and voltage of 1.5 V. Changes of the pH value, orthophosphate and iron ions content were also measured. Obtained results show, that wastewater treatment from orthophosphate with electrocoagulation takes place much faster than with metal dissolution method. Complete orthophosphate removal (starting concentration was 10.5 mg P/dm3) with electrocoagulation process occurred after 415 minutes of research, when metal dissolution method obtained the same effect after 1445 minutes. In the wastewater with starting 7.0 pH and with electrocoagulation, the total dephosphatation occurred after 1440 min, but the metal dissolution method after this time ensure only 37% reduction in the orthophosphate concentration. The pH value of treated wastewater increased during the every study. The most noticeable increase was while using electrocoagulation process, which attained 11.1 pH (wastewater with starting 8.0 pH) and 10.8 pH (wastewater with starting 7.0 pH) after 1440 minutes. Applying the metal dissolution method increase in pH was lower, was respectively 8.8 pH and 8.6 pH. Concentration of iron ions concentration also increased in treated wastewater. In the wastewater with starting 8.0 pH, from 0.00 mg Fe/dm3 to 0.16 mg Fe/dm3 with metal dissolution method and 0.00 mg Fe/dm3 to 0.46 mg Fe/dm3 with electrocoagulation. In the wastewater with starting 7.0 pH, the maximum observed total iron concentration was 0.04 mg Fe/dm3. Electrocoagulation method turned out to be more effective in orthophosphate removal from wastewater than metal dissolution method, which occurred in shorter time needed for dephosphatation. However it requires a more consumables funding related to the use of energy and electrodes wearing faster.
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 3; 2725-2737
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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