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    Wyświetlanie 1-8 z 8
    Tytuł:
    Thermodynamic analysis of medium pressure reciprocating natural gas expansion engines
    Autorzy:
    Farzaneh-Gord, M.
    Izadi, S.
    Pishbin, S. I.
    Sheikhani, H.
    Deymi-Dashtebayaz, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/777996.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Expansion engine
    thermodynamic
    first law
    optimization
    ideal gas model
    Opis:
    Natural gas pressure has to be reduced from medium pressure of 1.724 MPa (250 psia) to lower pressure of 0.414 MPa (60 psia) at Town Border pressure reduction Station (TBS). Currently, the pressure reduction is carried out by throttling valves while considerable amount of pressure energy is wasted. One of the equipment which could be used to recover this waste energy is the reciprocating expansion engine. The purpose of this research is to simulate one-sided reciprocating expansion engine thermodynamically for TBS pressure range. The simulation is based on first law of thermodynamics, conversation of mass and ideal gas assumptions. The model could predict in-cylinder pressure and in-cylinder temperature at various crank angles. In addition, the effects of the engine geometrical characteristics, such as intake and exhaust port area and ports timing on the Indicated work per cycle output are investigated.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 2; 119-125
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption of CO2 by surface modified coal-based activated carbons: kinetic and thermodynamic analysis
    Autorzy:
    Xinzhe, Liu
    Mingyang, Zhang
    Juan, Chen
    Zhengyu, Hu
    Shuaifei, Xian
    Mingxuan, Tang
    Chenchen, Zhang
    Powiązania:
    https://bibliotekanauki.pl/articles/2174813.pdf
    Data publikacji:
    2022
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Surface modification
    CO2 adsorption capacity
    adsorption kinetics
    thermodynamic parameters
    Opis:
    The effects of different surface modifiers on the CO2 adsorption capacity of coal-based activated carbons were studied, and the diffusion behavior, adsorption kinetics and thermodynamic parameters of CO2 in activated car-bons were analyzed. The results show that compared with ethylene glycol, 1,2-propylenediamine and zinc chloride, potassium hydroxide and sodium hydroxide can greatly improve CO2 adsorption capacity. The adsorption rate is faster, and the adsorption capacity is larger, with the maximum CO2 adsorption capacity being 33.54 mL/g. Fick’s law can well describe the diffusion behavior of CO2 in activated carbon. The addition of a surface modifier can increase the diffusion coefficient. The diffusion of CO2 in activated carbon falls into the category of crystal diffusion. The adsorption kinetics of CO2 before and after surface modification follow the Bangham equation. During the adsorption process, δ H < 0, δ G < 0, δ S < 0. Surface modification can reduce adsorption heat and promote adsorption, and the adsorption process is dominated by physisorption.
    Źródło:
    Polish Journal of Chemical Technology; 2022, 24, 3; 19--28
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Simultaneous thermodynamic simulation of CNG filling process
    Autorzy:
    Deymi-Dashtebayaz, M.
    Farzaneh-Gord, M.
    Reza Rahbari, H
    Powiązania:
    https://bibliotekanauki.pl/articles/779861.pdf
    Data publikacji:
    2014
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    compressed natural gas
    cascade storage bank
    fast filling process
    thermodynamic analysis
    entropy
    Opis:
    In CNG station, the fuel is usually stored in the cascade storage bank to utilize the station more efficiently. The cascade storage bank is generally divided into three reservoirs, commonly termed low, medium and high-pressure storage bank. The pressures within these reservoirs have huge effects on the performance of the stations. In the current study, a theoretical simulation based on mass balance and thermodynamic laws has been developed to study the dynamic fast fi lling process of vehicle’s (NGV) cylinder from the cascade storage bank. The dynamic change of the parameters within the storage bank is also considered. Natural gas is assumed to contain only its major component, methane, and so thermodynamic properties table has been employed for finding the thermodynamics properties. Also the system is assumed as a lumped adiabatic system. The results show that the initial pressure of the cascade storage bank has a big effect on the storage bank volumes for bringing up the NGV cylinder to its target pressure (200 bar). The results also showed that ambient temperature has effect on the refueling process, chiefly the final NGV cylinder and the cascade storage bank conditions.
    Źródło:
    Polish Journal of Chemical Technology; 2014, 16, 1; 7-14
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of thermal degradation behavior and kinetics of ABS/PC blend
    Autorzy:
    Bano, Saira
    Ramzan, Naveed
    Iqbal, Tanveer
    Mahmood, Hamayoun
    Saeed, Farhan
    Powiązania:
    https://bibliotekanauki.pl/articles/778844.pdf
    Data publikacji:
    2020
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    ABS/PC blend
    thermal degradation
    iso-conversional analysis
    activation energy
    thermodynamic parameters
    Opis:
    This work investigated kinetics and thermal degradation of acrylonitrile butadiene styrene and polycarbonate (ABS/PC) blend using thermogravimetric analysis in the range of 25 to 520°C. For thermal degradation of blend, activation energy (Ea) and pre-exponential factor (A) were calculated under various heating rates as 5, 10, 15 and 20°C/min using iso-conversional model-free methods (Kissinger, Flynn-Wall- Ozawa and Friedman). Mass loss of the blend as a function of temperature was plotted as thermogravimetric curve (TG) while derivative values of mass loss were drawn as derivative thermogravimetric (DTG) curve. Using Kissinger method, Ea was 51.4 kJ/mol, while values calculated from FWO and Friedman method were 86–161 and 30–251 kJ/mol respectively. Results showed increasing trend of Ea with higher conversion values indicating different degradation mechanisms at the initial and final stages of the experiment. Thermodynamic parameters such as enthalpy change (ΔH), Gibbs free energy (ΔG) and entropy change (ΔS) were also calculated.
    Źródło:
    Polish Journal of Chemical Technology; 2020, 22, 3; 64-69
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Simultaneous synthesis-immobilization of nano ZnO on perlite for photocatalytic degradation of an azo dye in semi batch packed bed photoreactor
    Autorzy:
    Khani, A.
    Sohrabi, M.R.
    Powiązania:
    https://bibliotekanauki.pl/articles/778943.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Natural gas vehicle
    driving range
    compressed natural gas (CNG)
    thermodynamic properties
    CNG fuelling station
    Opis:
    A novel, simple and simultaneous synthesis-immobilization of nano ZnO on perlite (nZnO-P) as a photocatalyst for photocatalytic degradation of Acid orange 7 (AO7) in aqueous solution was investigated. The effect of operational parameters such as initial dye concentration, initial pH, flow rate, photocatalyst granule size, temperature and the kinetic of the removal of AO7 in terms of the Langmuir-Hinshelwood model in a designed semi batch packed bed photoreactor connected to an on-line sampling UV-Vis spectrophotometer was studied. The results showed that AO7 removal efficiency increased with nZnO-P using the designed setup and the proposed photocatalyst was more efficient than TiO2 as a standard catalyst. Our results confirmed the pseudo-first-order kinetics model. The values of the adsorption equilibrium constant, KAO7, the kinetic rate constant of surface reaction, kc, and the activation energy (Ea) were found to be 0.57 (mg.l-1)-1, 0.41 mg.l-1.min-1 and 11.44 kJ/mol, respectively.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 4; 69-76
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of important parameters on the natural gas vehicles driving range
    Autorzy:
    Farzaneh-Gord, M.
    Rahbari, H.R.
    Nikofard, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/778945.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Natural gas vehicle
    driving range
    compressed natural gas (CNG)
    thermodynamic properties
    CNG fuelling station
    Opis:
    One of the most important issues regarding Natural Gas Vehicles (NGVs) is the Driving Range, chich is defi ned as capability of a NGV to travel a certain distance after each refueling. The Driving Range is a serious obstacle in the development and growth of NGVs. Thus the necessity of studying the effects of various parameters on the Driving Range could be realized. It is found that the on-board storage capacity and the natural gas heating value have the greatest effect on the Driving Range. The charge mass of NGV cylinders is varied due to the natural gas composition and the fi nal in-cylinder values (temperature and pressure). Underfi lling of NGV cylinders, during charging operations, is a result of the elevated temperature which occurs in the NGV storage cylinder, due to compression and Rother processes could be overcome by applying extensive over-pressurization of the cylinder during the fuelling operation. Here, the effects of the most important parameters on the Driving Range have been investigated. The parameters are natural gas composition, engine effi ciency and fi nal NGV on-board in-cylinder temperature and pressure. It is found that, the composition has big effects on the Driving Range. The results also show that as fi nal in-cylinder pressure decreases (or temperature increases), the Driving Range will be increased.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 4; 61-68
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimizing Natural Gas Fueling Station Reservoirs Pressure Based on Ideal Gas Model
    Autorzy:
    Farzaneh-Gord, M.
    Deymi-Dashtebayaz, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/779242.pdf
    Data publikacji:
    2013
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    compressed natural gas
    CNG cylinder
    fast filling process
    Cascade Reservoirs
    thermodynamic analysis
    entropy generation
    Opis:
    At CNG fuelling station, natural gas is usually stored in a cascade storage system to utilize the station more efficient. The cascade storage system is generally divided into three reservoirs, commonly termed low, medium and high-pressure reservoirs. The pressures within these three reservoirs have huge effects on the performance of a CNG fuelling station and a fast filling process of natural gas vehicle’s (NGV) cylinder. A theoretical analysis is developed to study the effects of the reservoirs pressures and temperatures on the performance of the CNG station. The analysis is based on the first and the second law of thermodynamics, conservation of mass and ideal gas assumptions. The results show that as the reservoir temperature decreases, the fill ratio increases and the pressure within the filling station reservoirs has no effects on the fill ratio. The non-dimensional entropy generation and filling time profiles have opposite trends and as entropy generation decreases, the filling time increases. The optimized non-dimensional low and medium pressure-reservoir pressures are found to be as 0.24 and 0.58 respectively in thermodynamic point of view.
    Źródło:
    Polish Journal of Chemical Technology; 2013, 15, 1; 88-96
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    In situ methanolic solvent synthesis, spectroscopic and thermogravimetric characterizations of three new transition metal complexes of trimethoprim drug
    Autorzy:
    Refat, Moamen S.
    Al-Humaidi, Jehan Y.
    El-Sayed, Mohamed Y.
    Hassan, Reham F.
    Powiązania:
    https://bibliotekanauki.pl/articles/1849325.pdf
    Data publikacji:
    2021
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    complexation
    trimethoprim
    transition metals
    TGA
    thermogravimetric analysis
    FTIR
    Fourier transform infrared spectroscopy
    ESR
    kinetic thermodynamic parameters
    Opis:
    Trimethoprim drug (TMP) complexes of copper (II), cobalt (II), and nickel (II) were prepared and discussed by using elemental analysis (C, H, N analysis), magnetic, molar conductance, FTIR, Raman spectroscopy, electron spin resonance (ESR) and UV-vis spectroscopy analyses. TMP drug coordinated as a tridentate ligand towards the respected three metal ions through two nitrogen atoms of amino groups and nitrogen atom of pyrimidine ring which flanked between –NH2 groups, these assignments confirmed by spectroscopic, magnetic, ESR and thermogravimetric analyses with formulas [Cu(TMP)(H2O)3]Cl2, [Co(TMP)(H2O)3]Cl2 and [Ni(TMP) (H2O)]Cl2. Copper (II) and cobalt (II) complexes have an octahedral geometrical structure included one TMP molecule, three coordinated water molecules and two uncoordinated chlorine atoms while, nickel(II)–TMP complex has a tetrahedral geometric configuration that involved one TMP molecule, one coordinated water molecule and two uncoordinated chlorine atoms. The activation energies and other kinetic thermodynamic parameters were estimated based on the employed of the Coats-Redfern and Horowitz-Metzger equations. The nano–structured form of the synthesized TMP complexes was confirmed dependent on the transmission electron microscopy (TEM).
    Źródło:
    Polish Journal of Chemical Technology; 2021, 23, 1; 60-67
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-8 z 8

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