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Wyświetlanie 1-7 z 7
Tytuł:
Transient CFD simulations of turbulent liquid - liquid flow in a Kenics static mixer. Radial and tangential velocities
Autorzy:
Murasiewicz, H.
Jaworski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779172.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
LES
ciecz-ciecz
przepływ burzliwy
mieszalnik Kenics
liquid-liquid
turbulent flow
Kenics mixer
Opis:
The results of modelling of the two-phase turbulent flow of a two-phase, liquid-liquid mixture in a Kenics static mixer were reported. Advanced transient simulations were performed using the large eddy simulation (LES) approach and a broader analysis of the velocity field was carried out. The two-phase flow was modelled employing the Eulerian approach in the pseudo-homogeneous version of the mixture model. Three cases were again considered, which differed by the density of the two phases and the simulations were performed for Reynolds number of 10,000. The LES results for the tangential and radial components were compared with those obtained in the steady-state RANS approach.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 2; 36-40
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selection of cutting and washing fluids as a method of waste minimization
Autorzy:
Rymarczyk, A.
Mędrzycka, K.
Tomczak-Wandzel, R.
Powiązania:
https://bibliotekanauki.pl/articles/778187.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
korozja
ciecz obróbkowa
corrosion
cutting fluids
Opis:
The results of the corrosion test for washing and cutting fluids used in the process of gear-shafts production are presented. The test has been performed according to the DIN 51360-2 (Ford-test) and the PN-92/M-55789 procedures. Three cutting fluids and three washing fluids were chosen and their solutions in tap water (used in practice in the company) were investigated. On the basis of the obtained results it has been stated that the lower the fluid concentration, the stronger corrosion is developed. The concentrations recommended by the producer in the case of cutting fluids are properly chosen. For washing fluids two regions of concentration have been evaluated. The concentration recommended for rinsing is too low for protection against corrosion, while higher concentrations, for the washing process, are properly chosen, and corrosion did not occur.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 143-146
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of organic impurities using 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6]
Autorzy:
Koźlecki, T.
Sawiński, W.
Sokołowski, A.
Ludwig, W.
Polowczyk, I.
Powiązania:
https://bibliotekanauki.pl/articles/778267.pdf
Data publikacji:
2008
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ekstrakcja ciecz-ciecz
ciecze jonowe
oczyszczanie ścieków przemysłowych
liquid-liquid extraction
ionic liquids
industrial wastewater purification
Opis:
Extraction of several chloro compounds from water has been examined. As the extracting liquid the 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6], which is common hydrophobic ionic liquid, was used. Additionally, extraction of selected chlorinated compounds from tert-butylmethylether (MTBE) was investigated. The obtained results show the usefulness of [BMIM][PF6] to remove the organic impurities from water, particularly at the concentration range inappropriate for biological purification plants.
Źródło:
Polish Journal of Chemical Technology; 2008, 10, 1; 79-83
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of palladium (II) ions from chloride solutions with phosphonium ionic liquid CyphosŽIL101
Autorzy:
Cieszyńska, A.
Regel-Rosocka, M.
Wiśniewski, M.
Powiązania:
https://bibliotekanauki.pl/articles/779877.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ekstrakcja palladu
kwas solny
fosfoniowa ciecz jonowa
ciecz jonowa
extraction of palladium(II)
hydrochloric acid
phosphonium ionic liquids
Opis:
The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with phosphonium ionic liquid CyphosŽIL101 in toluene was investigated. The extraction of Pd(II) is very effective. The percentage extraction of Pd(II) from 0.1 mol dm-3 HCl solution amounts to 97% with CyphosŽIL101. Both the increase in HCl concentration and the presence of NaCl have a negative influence on the extraction. The extent of extraction from 0.1 mol dm-3 HCl solution in the presence of 0.5 mol dm-3 NaCl is about 80% and from 3 mol dm-3 HCl is lower and amounts to 56%. The extraction of Pd(II) from aqueous 0.1 mol dm-3 HCl and from 0.1 mol dm-3 HCl in the presence of 0.5 mol dm-3 NaCl with this phosphonium ionic liquid is rapid and the equilibrium is achieved after 1 - 2 minutes. The extraction of Pd(II) from aqueous 3 mol dm -3 HCl is slower and the equilibrium is achieved after 5 - 6 minutes.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 2; 99-101
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
CFD modelling of two-phase liquid-liquid flow in a SMX static mixer
Autorzy:
Pianko-Oprych, P.
Jaworski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/778737.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
CFD
LES
QMOM
przepływ dwufazowy
dyspersja ciecz-ciecz
mieszalnik statyczny SMX
two-phase flow
liquid-liquid dispersion
SMX static mixer
Opis:
The paper provides an overview of the application of Computational Fluid Dynamics tools for predicting transport processes in two-phase flow in a SMX static mixer. The overview is achieved by taking a brief look at factors: mesh generation, development of sub-models, post-processing including validation and quantitative verification of CFD results with experimental data. Two types of numerical approach were used in the simulations: the Reynolds averaged Navier-Stokes in the steady-state mode with the standard k-??turbulence model and Large Eddy Simulations in the unsteady mode. Both CFD techniques were applied to calculate flow velocities, pressure drop and homogenisation level in a SMX static mixer of the liquid-liquid mixture. The steady state drop size distribution was obtained by implementation procedure containing the population balance equation, where transport equations for the moments of the drop size distribution are solved and the closure problem is overcome by using the Quadrature Method of Moments.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 3; 41-49
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of the quintic equation of the state based model for the calculations of different thermodynamic properties
Autorzy:
Kozioł, A.
Wiśniewski, R.
Powiązania:
https://bibliotekanauki.pl/articles/778661.pdf
Data publikacji:
2008
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
równanie stanu
równowaga para-ciecz
wielomiany Hermita
NBP equation of state
vapour-liquid equilibrium
cubic Hermite polynomials
Opis:
Different thermodynamic properties (the vapour density, the liquid density and the saturation pressure) were calculated by the model based on the Nakamura-Breedveld-Prausnitz equation of state (NBP EOS). Since the original form of the NBP EOS often generates inaccurate results for liquids, it was modified to describe this phase better. The calculations were realized in the subcritical region. So far, the temperature-dependent NBP EOS parameters have been obtained by special correlations. Their constants were fitted to a lot of experimental data. In this paper the equation of state temperature-dependent parameters were obtained by a new method which was based at piecewise cubic Hermite interpolating polynomials (PCHIPs). In the proposed method some experimental data (called the key ones) were used, thus reducing the experimental effort. Seven substances were chosen for the test calculations. Each of them is common in industry. The calculation results were compared with the experimental data. The new method has made an accurate description of vapour-liquid equilibrium for the considered pure substances over a wide temperature range possible.
Źródło:
Polish Journal of Chemical Technology; 2008, 10, 1; 6-10
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Vegetable oils derivatives as the modifiers of the lubricating properties of water
Autorzy:
Sułek, M.W.
Sas, W.
Przondo, J.
Powiązania:
https://bibliotekanauki.pl/articles/778150.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ekologiczne ciecze obróbkowe
ciecz obróbkowa
opór ruchu
zużycie
właściwości przeciwzatarciowe
ecological cutting fluids
motion resistance
wear
antiseizure properties
Opis:
Water has been used as a lubricating medium in a number of applications in tribology. Its insufficient lubricating properties are modified by appropriate additives. The aim of the tribological studies presented in this paper is an application of a mixture containing triglyceride ethoxylates and partial glycerides as well as esters and a block copolymer as additives. All the components are commercially available and relatively cheap. In order to examine the aqueous solutions, two kinds of tests were carried out on a four-ball apparatus: at the fixed load - measurements of the friction coefficient and wear as a function of time and seizure tests which made it possible to determine the scuffing load (Pt), the seizure load (Poz) and the limiting pressure of seizure (p(oz)). Changes in the quantities measured were analyzed as a function of concentrations ranging from 0.001% to 100%. In the fixed load tests the coefficient of friction decreased almost eight-fold, reaching the lowest value of 0.06 at above 0.1% concentration of the additive. Wear decreased over 3.5-fold. In the seizure tests a relatively high efficiency of the additive package was observed at the concentration of the order of the thousandth part of one percent. The compositions reached the maximum anti-seizure capacity at the concentrations of 4 and 10%. It is particularly interesting to note that the stability of the lubricating film being formed was characterized by the scuffing load. The maximum value of Pt was about 4kN high. Summing up, on the basis of the results obtained it may be concluded that the choice of package additives was correct and it effectively modified the lubricating properties of water.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 147-150
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-7 z 7

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