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Wyszukujesz frazę "Zn" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Adsorption of Zn(II) ions from aqueous environment by surface modified Strychnos potatorum seeds, a low cost adsorbent
Autorzy:
Senthil, Kumar P.
Powiązania:
https://bibliotekanauki.pl/articles/949520.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
isotherms
kinetics
shrinking core model
Zn(II)
Opis:
The surface modified Strychnos potatorum seeds (SMSP), an agricultural waste has been developed into an effective adsorbent for the removal of Zn(II) ions from aqueous environment. The Freundlich model provided a better fit with the experimental data than the Langmuir model as revealed by a high coefficient of determination values and low error values. The kinetics data fitted well into the pseudo-second order model with the coefficient of determination values greater than 0.99. The influence of particle diffusion and film diffusion in the adsorption process was tested by fitting the experimental data with intraparticle diffusion, Boyd kinetic and Shrinking core models. Desorption experiments were conducted to explore the feasibility of regenerating the spent adsorbent and the adsorbed Zn(II) ions from spent SMSP was desorbed using 0.3 M HCl with the efficiency of 93.58%. The results of the present study indicates that the SMSP can be successfully employed for the removal of Zn(II) ions from aqueous environment.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 3; 35-41
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of Zn2+ from solutions on manganese oxide obtained via ozone precipitation reaction
Autorzy:
Contreras-Bustos, R.
Espejel-Ayala, F.
Cercado-Quezada, B.
Jiménez-Becerril, J.
Jiménez-Reyes, M.
Powiązania:
https://bibliotekanauki.pl/articles/778323.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
manganese dioxide
aqueous Zn(II) solutions
adsorption process
Opis:
Synthesis via ozone precipitation reaction was used to obtain manganese dioxide (OMD) and it was probed as an adsorbent for zinc ions. Adsorption was followed along shaking time and increasing ratio [NO3 –] / [Zn2+], and isotherms were obtained at different pH values and in the presence of several anions (chloride, nitrate, sulphate, and acetate). It was found that adsorption equilibrium is fast and follows the pseudo-second order model (qe = 34 ±1 mg/g and K = 0.07 ±0.01 g/mg h). Isotherms were fitted to Langmuir, Freundlich, and Langmuir-Freundlich models, and the best fitting was found with the last one. The process is dependent on pH and the efficiency increases from pH 1 to 4. The ratio [NO3 –] / [Zn2+] up to 3 does not seem to change the behaviour of the process. Regarding the anions, the efficiency of Zn(II) adsorption occurs according to: acetate > nitrate and sulphate > chloride. Manganese oxide obtained via ozonization is an excellent adsorbent for zinc ions.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 1; 46-50
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Galvanic coupling effects for module-mounting elements of ground-mounted photovoltaic power station
Autorzy:
Pierozynski, B.
Bialy, H.
Powiązania:
https://bibliotekanauki.pl/articles/780083.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
PV mounting assembly
Zn-coated steel
Magnelis® coating
galvanic coupling
Opis:
This communication reports on the concerns associated with possible generation of galvanic coupling effects for construction materials that are used to manufacture mounting assemblies for ground-mounted photovoltaic (PV) power stations. For this purpose, six macro-corrosion galvanic cells were assembled, including: hot-dip Zn/Magnelis®-coated steel/Al and stainless steel (SS)/Al cells. Corrosion experiments involved continuous, ca. three-month exposure of these couplings in 3 wt.% NaCl solution, conducted at room temperature for a stable pH value of around 8. All corrosion cells were subjected to regular assessment of galvanic current-density and potential parameters, where special consideration was given to compare the corrosion behaviour of Zn-coated steel samples with that of Magnelis®-coated electrodes. Characterization of surface condition and elemental composition for examined materials was carried-out by means of SEM and EDX spectroscopy techniques.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 4; 22-27
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption kinetic, equilibrium and thermodynamic investigations of Zn(II) and Ni(II) ions removal by poly(azomethinethioamide) resin with pendent chlorobenzylidine ring
Autorzy:
Kumar, P. S.
Ethiraj, H.
Venkat, A.
Deepika, N.
Nivedha, S.
Vidhyadevi, T.
Ravikumar, L.
Sivanesan, S.
Powiązania:
https://bibliotekanauki.pl/articles/780002.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
models
Ni(II) ions
poly(azomethinethioamide)
Zn(II) ions
Opis:
This paper reports the application of poly(azomethinethioamide) (PATA) resin having the pendent chlorobenzylidine ring for the removal of heavy metal ions such as Zn(II) and Ni(II) ions from the aqueous solutions by adsorption technology. Kinetic, equilibrium and thermodynamic models for Zn(II) and Ni(II) ions adsorption were applied by considering the effect of contact time, initial metal ion concentration and temperature data, respectively. The adsorption influencing parameters for the maximum removal of metal ions were optimized. Adsorption kinetic results followed the pseudo-second order kinetic model based on the correlation coefficient (R2) values and closed approach of experimental and calculated equilibrium adsorption capacity values. The removal mechanism of metal ions by PATA was explained with the Boyd kinetic model, Weber and Morris intraparticle diffusion model and Shrinking Core Model (SCM). Adsorption equilibrium results followed the Freundlich model based on the R2 values and error functions. The maximum monolayer adsorption capacity of PATA for Zn(II) and Ni(II) ions removal were found to be 105.4 mg/g and 97.3 mg/g, respectively. Thermodynamic study showed the adsorption process was feasible, spontaneous, and exothermic in nature.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 3; 100-109
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The optimization of low-magnesium zinc concentrate production process
Autorzy:
Jarosiński, A.
Fela, K.
Powiązania:
https://bibliotekanauki.pl/articles/779226.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
koncentraty cynku
usuwanie magnezu
obróbka chemiczna
ługowanie
Zn-concentrate
magnesium removal
chemical treatment
acid leaching
Opis:
In this paper the result of the study on chemical leaching of zinc concentrate with H2SO4 solution was presented. The object of this work was to assess the effect of some parameters such as acid concentration, the leaching agent amount /stoichiometry amount or excess of acid were applied/, reaction time and temperature on the process. The investigation was performed as a active experiment according to Hartley's plan. The process optimisation procedure was based on the fuzzy logic system. Mainly, the parameters such as magnesium leaching efficiency and zinc losses were taken into account. It was stated that the highest magnesium leaching efficiency of 77.8% with low Zn-losses was reached when H2SO4 solution concentration was 2.5% for 20%-excess of acid, at temperature 25°C and process time of 1 hour.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 20-23
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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