- Tytuł:
- Reaction crystallization of struvite in a continuous DTM type crystallizer with a compressed air driven jet pump
- Autorzy:
-
Matynia, A.
Mazieńczuk, A.
Piotrowski, K.
Wierzbowska, B.
Hutnik, N.
Kozik, A. - Powiązania:
- https://bibliotekanauki.pl/articles/779281.pdf
- Data publikacji:
- 2011
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
krystalizator DTM
strumienica
sprężone powietrze
krystalizacja
usuwanie fosforanów
struwit
rozkład miarowy kryształów
model kinetyczny
continuous DTM crystallizer
jet pump
compressed air
reaction crystallization
phosphates(V) removal
struvite
crystal size distribution
SIG kinetic model - Opis:
- Experimental tests covering the production of struvite MgNH4PO4ź6H2O from water solutions containing 1.0 mass % of phosphate(V) ions using magnesium and ammonium ions in stoichiometric proportions were carried out in a crystallizer of 1.2 dm3 working volume. The process temperature was 298 K. Struvite crystals of mean size Lm from ca. 14 to ca. 38 µm were produced depending on the process environment's pH (9-11) and the mean residence time of suspension in a crystallizer, τ (900-3600 s). In such defined process conditions the linear growth rate of struvite crystals changed from 1.45ź10-8 m/s (pH 9, τ 900 s) to 2.06ź10-9 m/s (pH 11, τ 3600 s) while the nucleation rate from 5.1ź10^7 to 3.2ź10^9 1/(sm3). Crystal product of the most advantageous granular characteristics was produced at pH 9 and the mean residence time 3600 s. Within this product population the largest sizes reached above 200 µm while the number of crystals smaller than 3 mm was kept below 6%.
- Źródło:
-
Polish Journal of Chemical Technology; 2011, 13, 2; 46-53
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł