- Tytuł:
- Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion
- Autorzy:
-
Lewandowski, G.
Rytwińska, E.
Milchert, E. - Powiązania:
- https://bibliotekanauki.pl/articles/778202.pdf
- Data publikacji:
- 2007
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
epoksydowanie
wodoronadtlenek tert-butylu
(1Z,5E,9E)-1,5,9-cyklododekatrien
1,2-epoksy-(Z,E)-5,9-cyklododekadien
planowanie doświadczeń
optymalizacja
epoxidation
tert-butyl hydroperoxide
(1Z,5E,9E)-1,5,9-cyclododecatriene
1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene
design of experiments
optimization - Opis:
- The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)6 were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)6). According to the design 20 experiments were performed at the constant temperature of 70°C.
- Źródło:
-
Polish Journal of Chemical Technology; 2007, 9, 3; 105-107
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł