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    Wyświetlanie 1-7 z 7
    Tytuł:
    Polymerization shrinkage by investigation of uv curable dental restorative composites containing multifunctional methacrylates
    Autorzy:
    Świderska, J.
    Czech, Z.
    Kowalczyk, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/778955.pdf
    Data publikacji:
    2013
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    polymerization shrinkage
    UV-curable
    multifunctional methacrylates
    Opis:
    Typical commercial restorative dental compositions in the form of medical resins contain in-organic fillers, multifunctional methacrylates and photoinitiators. The currently used resins for direct composite restoratives have been mainly based on acrylic chemistry to this day. The main problem with the application and radiation curing process is the shrinkage of photoreactive dental materials during and after UV curing. Shrinkage of restorative radiation curable dental composites is a phenomenon of polymerization shrinkage, typical behavior of multifunctional methacrylates during the polymerization process. The important factors in curing of dental composites are: the kind and concentration of the used methacrylate, its functionality, double bond concentration, the kind and concentration of the added photoinitiator and UV dose emitted by the UV-lamp. They are investigated multifunctional 1,3-butanediol dimethacrylate (1,3-BDDMA), diethylene glycol dimethacrylate (DEGDMA), triethylene glycol dimethacrylate (TEGDMA), trimethylolpropane trimethacrylate (TMPTMA), 2,2-bis-[4-(2-hydroxy-3-methacryxloyloxypropyl) phenyl]propane (Bis-GMA), ethoxylated Bis-GMA (EBPDMA) and dodecandiol dimethacrylate (DDDMA). Reduction of polymerization shrinkage of restorative dental compositions is at the moment a major problem of dental technology. This problem can be solved through an application of photoreactive non-tacky multifunctional methacrylates in the investigated dental adhesive fillings.
    Źródło:
    Polish Journal of Chemical Technology; 2013, 15, 2; 81-85
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of 1-substituted imidazole derivatives for the curing process of epoxy- isocyanate composition
    Autorzy:
    Pilawka, R.
    Kowalska, J.
    Czech, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/780036.pdf
    Data publikacji:
    2013
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    curing process
    DSC investigation
    rheometric curves
    Coats-Redfern method
    autocatalytic curing process
    Sesták-Berggren model
    Opis:
    The kinetics of the curing process of isocyanate-epoxy materials hardened in the presence of 1- substituted imidazole derivatives was studied by the Coast-Redfern method. The extent of a conversion parameter of the curing process in two ways was calculated: DSC (peak area integration) and rheology (viscosity changes). The activation energy values were determined for epoxy-isocyanate cured in the presence of 0.5; 1.0 and 2.0 phr 1-substituted imidazole derivatives respectively. Increasing of accelerators amount results in decreasing the activation energy and other kinetic parameters.
    Źródło:
    Polish Journal of Chemical Technology; 2013, 15, 4; 36-41
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Acrylic Pressure-Sensitive Adhesives Containing SiO2 Nanoparticles
    Autorzy:
    Czech, Z.
    Kowalczyk, A.
    Ortyl, J.
    Świderska, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/779344.pdf
    Data publikacji:
    2013
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    pressure-sensitive adhesives
    SiO2 nanoparticles
    tack
    peel adhesion
    shrinkage
    Opis:
    The use of acrylic pressure-sensitive adhesives (PSAs) is increasing in a variety of industrial fi elds. They have been applied in the manufacture of mounting tapes, self-adhesive labels, protective fi lms, mas king tapes, splicing tapes, carrier-free tapes, sign and marking fi lms, and in diverse medical products, such as pads or self-adhesive bioelectrodes. In this study, the application of SiO2 nanoparticles in acrylic PSA was investigated. The properties of the newly synthesized and modifi ed PSA were evaluated via the tack, peel adhesion, shear-strength and shrinkage. It has been found that the nanotechnologically-reinforced systems consisting of monodisperse non-agglomerated SiO2 nanoparticles and self-crosslinked acrylic PSAs showed a great enhancement in tack, peel adhesion, shear resistance and shrinkage, without showing the disadvantages known to result from the use of other inorganic additives. In this paper we evaluate the performance of SiO2 nanoparticles with a size of about 30 nm as inorganic fi ller into the synthesized solvent-borne acrylic PSA.
    Źródło:
    Polish Journal of Chemical Technology; 2013, 15, 1; 12-14
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Reducing of on polymerization shrinkage by application of UV curable dental restorative composites
    Autorzy:
    Świderska, J.
    Czech, Z.
    Świderski, W.
    Kowalczyk, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/778914.pdf
    Data publikacji:
    2014
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    dental compositions
    polymerization shrinkage
    multifunctional methacrylates
    UV-curin
    Opis:
    This manuscript describes dental compositions contain in-organic fillers, multifunctional methacrylates and photoinitiators. The main problem by application and UV curing process is the shrinkage of photoreactive dental materials during and after UV curing process. Total shrinkage of UV curable dental composites is a phenomenon of polymerization shrinkage, typical behavior for multifunctional methacrylates during polymerization process. The important factors by curing of dental composites are: kind and concentration of used methacrylates, their functionality, double bond concentration, kind and concentration of added photoinitiator and UV dose. They are investigated UV-curable dental compositions based on 2,2-bis-[4-(2-hydroxy-3-methacryxloyloxypropyl)phenyl]propane (Bis-GMA) and containing such multifunctional monomers as 1,3-butanediol dimethacrylate (1,3-BDDMA), diethylene glycol dimethacrylate (DEGDMA), tetraethylene glycol dimethacrylate (T3EGDMA), trimethylolpropane trimethacrylate (TMPTMA), polyethylene glycol 200 dimethacrylate (PEG200DA). Reduction of polymerization shrinkage of dental compositions is at the moment a major problem by dental technology.
    Źródło:
    Polish Journal of Chemical Technology; 2014, 16, 3; 51-55
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Preparation of activated carbon from the biodegradable film for CO2 capture applications
    Autorzy:
    Serafin, J.
    Antosik, A. K.
    Wilpiszewska, K.
    Czech, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/949409.pdf
    Data publikacji:
    2018
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    biodegradable film activated carbon
    adsorption
    CO2
    capture
    Opis:
    In this work for the first time, activated carbons were prepared from carboxymethyl fi lm (low-cost carboxymethyl fi lm waste), using chemical activation with potassium hydroxide. The samples were characterized by nitrogen adsorption-desorption at 77 K, XRD, SEM methods. The high values of the specifi c surface area and total pore volume were achieved and were equal to 2064 m2/g and 1.188 cm3 /g, respectively. Waste from the fi lm can be immediately utilized without CO2 production. This is the environmentally friendly way of waste utilization. Through this process, we can protect our environment. This study showed that the activated carbon obtained from carboxymethyl fi lm waste can be used as a good adsorbent for CO2 adsorption.
    Źródło:
    Polish Journal of Chemical Technology; 2018, 20, 3; 75-80
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Electrically conductive acrylic pressure-sensitive adhesives containing carbon black
    Autorzy:
    Czech, Z.
    Pełech, R.
    Kowalczyk, A.
    Kowalski, A.
    Wróbel, R. J.
    Powiązania:
    https://bibliotekanauki.pl/articles/779803.pdf
    Data publikacji:
    2011
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    akrylowe kleje samoprzylepne
    sadza
    materiały przewodzące elektryczność
    acrylic pressure-sensitive adhesives
    carbon black
    electrical conductive materials
    Opis:
    Acrylic pressure-sensitive adhesives (PSA) are non electrical conductive materials. The electrical conductivity is incorporated into acrylic self-adhesive polymer after adding electrically conductive additives like carbon black, especially nano carbon black. After an addition of electrical conductive carbon black, the main and typical properties of pressure-sensitive adhesives such as tack, peel adhesion and shear strength, are deteriorated. The investigations reveals that the acrylic pressure-sensitive adhesives basis must be synthesised with ameliorated initial performances, like high tack, excellent adhesion and very good cohesion. Currently, the electrical conductive solvent-borne acrylic PSA containing carbon black are not commercially available on the market. They are promising materials which can be applied for the manufacturing of diverse technical high performance self-adhesive products, such as broadest line of special electrically conductive sensitive tapes.
    Źródło:
    Polish Journal of Chemical Technology; 2011, 13, 4; 77-81
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of the unsaturated photoinitiators kind on the properties of uv-crosslinkable acrylic pressure-sensitive adhesives
    Autorzy:
    Czech, Z.
    Kowalczyk, A.
    Górka, K.
    Głuch, U.
    Shao, L.
    Świderska, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/779106.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    pressure-sensitive adhesive
    photoreactive
    UV-crosslinking
    tack
    peel adhesion
    shear strength
    shrinkage
    Opis:
    UV-crossinkable pressure-sensitive adhesives (PSA) materials are called, in the adhesives trade photoreactive self-adhesive. UV-crosslinkable PSAs are designed after the UV-initiated crosslinking reaction to stick to almost any surface by a simple contact under light pressure. This special class of adhesives does not undergo any physical transformation or chemical reaction during the bonding process. Because of the rheological properties the adhesive must be fi nely tuned for the application, combining a carefully chosen polymer architecture and monomer composition with the proper addition of small additives called photoinitiators. The best way is using the unsaturated copolymerizable photoinitiators and their direct incorporation into polymer chain during the polymerization process. Progress in the coating technology and the development of novel photoreactive acrylic adhesives will open the door to new applications and an extended market penetration of UV-crosslinkable acrylic adhesive raw materials containing unsaturated copolymerizable photoinitiators incorporated into the polymer backbone. Photoreactive UV-crosslinkable acrylic PSA are characterized by good tack, good adhesion, excellent cohesion and very low shrinkage.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 3; 83-87
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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