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Wyszukujesz frazę "schiff base" wg kryterium: Wszystkie pola


Wyświetlanie 1-3 z 3
Tytuł:
Corrosion Inhibition of Mild Steel in Nitric Acid Media by some Schiff Bases Derived from Anisalidine
Autorzy:
Saxena, N.
Kumar, S.
Sharma, M. K.
Mathur, S. P.
Powiązania:
https://bibliotekanauki.pl/articles/779278.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Schiff base
degradation
inhibitor and mild steel
Opis:
Corrosion inhibition performance of mild steel in nitric acid solution containing different concentration of anisalidine derivative Schiff bases viz. N- (4-nitro phenyl) p-anisalidine (SB1), N- (4-chloro phenyl) p-anisalidine (SB2), N- (4-phenyl) p-anisalidine (SB3), N- (4-methoxy phenyl) p-anisalidine (SB4), N- (4-hydroxy phenyl) p-anisalidine (SB5) has been investigated using mass loss, thermometric and potentiostate polarization technique. Inhibition efficiencies of Schiff bases have been evaluated at different acid strength. The inhibition efficiency was found larger than their parent amines. Inhibition efficiencies of synthesized Schiff bases increase with inhibitor concentration. Inhibition efficiency increases up to 98.32% with ansalidine derivative Schiff base.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 61-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, computational, anticancerous and antiproliferative effects of some copper, manganese and zinc complexes with ligands derived from symmetrical 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl-salicylaldehyde
Autorzy:
Ababneh, Taher S.
El-Khateeb, Mohammad
Tanash, Aissar K.
AL-Shboul, Tareq M.A.
Shammout, Mohammad Jamal A.
Jazzazi, Taghreed M.A.
Alomari, Mohammad
Daoud, Safa
Talib, Wamidh H.
Powiązania:
https://bibliotekanauki.pl/articles/1849324.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
tetradentate schiff base
symmetrical metal complexes
DFT calculation
spectroscopy
anticancerous
antiproliferative
Opis:
Four new symmetrical Schiff bases derived from 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl-salicylaldehyde have been synthesized and characterized by elemental analysis and different spectroscopic techniques. The reaction of 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl with two equivalents of 5-tert-butyl-, 3,5-dinitro-, 3,5-dibromo- and 3-tert-butyl-salicylaldehyde yielded 2,2’-bis(5-tert-butyl-salicylideneamino)-4,4’-dimethyl-1,1’-biphenyl (A1) as well as the 3,5-dinitro- (A2), 3,5-dibromo- (A3) and 3-tert-butyl- (A4) substituted derivatives. The tetradentate ligands were then reacted with copper-, manganese- and zinc-acetate producing the tetra-coordinate metal complexes which were characterized by FTIR, UV-Visible spectroscopy, magnetic susceptibility and elemental analysis. Zinc complexes were characterized by 1H-NMR spectroscopy. Density functional theory (DFT) calculations at the B3LYP/6-31G(d) level of theory were carried out to fully optimize and examine the molecular geometries of complexes. Subsequently, IR vibrational and UV-Vis absorption spectra were computed and correlated with the observed values and the results are in good agreement with the experimental data. The anticancerous and antiproliferative activity of the A3 ligand and its metal complexes were determined.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 1; 7-15
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) Schiff base complexes of 3-hydroxy-4-[N-(2-hydroxynaphthylidene)-amino]-naphthalene-1-sulfonic acid: Synthesis, Spectroscopic, thermal, and antimicrobial studies
Autorzy:
Bakare, Safyah B.
Powiązania:
https://bibliotekanauki.pl/articles/778830.pdf
Data publikacji:
2019
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Schiff base
hydroxynaphthalene-1-sulfonic acid
hydroxy-1-naphthaldehyde
transition metal ions
morphology
antimicrobial activity
Opis:
Five divalent transition metals Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) complexes have been synthesized using 3-hydroxy-4-[N-(2-hydroxynaphthylidene)-amino]-naphthalene-1-sulfonic acid (H3L) Schiff base as a ligand derived from the condensation reaction between 4-amino-3-hydroxynaphthalene-1-sulfonic acid and 2-hydroxy-1-naphthalde-hyde. The synthesized complexes were characterized using microanalytical, conductivity, FTIR, electronic, magnetic, ESR, thermal, and SEM studies. The microanalytical values revealed that the metal-to-ligand stoichiometry is 1:1 with molecular formula [M2+(NaL)(H2O)x].nH2O (where x = 3 for all metal ions except of Zn(II) equal x = 1; n = 4, 10, 7, 4, and 6 for Cu(II), Co(II), Ni(II), Mn(II) and Zn(II), respectively). The molar conductivity result indicates that all these complexes are neutral in nature with non-electrolytic behavior. Dependently on the magnetic, electronic, and ESR spectral data, octahedral geometry is proposed for all the complexes except to zinc(II) complex is tetrahedral. Thermal assignments of the synthesized complexes indicates the coordinated and lattice water molecules are present in the complexes. SEM micrographs of the synthesized complexes have a different surface morphologies. The antimicrobial activity data show that metal complexes are more potent than the parent ligand.
Źródło:
Polish Journal of Chemical Technology; 2019, 21, 3; 26-34
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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