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Tytuł:
The influence of holmium on catalytic properties of Fe or Cu-modified vermiculites
Autorzy:
Samojeden, Bogdan
Grzybek, Teresa
Kowal, Joanna
Szymaszek, Agnieszka
Jabłońska, Magdalena
Gläser, Roger
Motak, Monika
Powiązania:
https://bibliotekanauki.pl/articles/109844.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
selective catalytic reduction
deNOx
holmium
vermiculite
Opis:
Natural layered clay, vermiculite, was modified and tested as catalyst for the selective catalytic reduction of NOx with ammonia (NH3-SCR). Its modification included the application of the blowing agent (azodicarbonamide), acid treatment and pillaring with Al2O3. Active phase (transition metals: Cu or Fe) was introduced via impregnation. The obtained materials were characterized by N2 sorption (texture), XRD (structure), DR-UV-Vis (oxidation state and aggregation of the active phase), H2-TPR (reducibility of the active phase), in situ DRIFTS (types of adsorbed species due to contact of the sample NH3) and NH3-TPD (type/strength of the acidic sites). The initial modification procedures (treatment with azodicarboamide) resulted in the increase of specific surface area of vermiculite. The introduction of transition metal ions provided a significant amount of acidic sites. The promoting impact of holmium was confirmed by the increased strength of the sites. The highest catalytic activity was exhibited by the sample Fe-containing vermiculite and doped with Ho.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1484-1495
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Feasibility study on preparation of magnesium titanate in carbonthermic reduction of vanadium titanomagnetite concentrates
Autorzy:
Chen, Chao
Sun, Ti-Chang
Kou, Jue
Wang, Xiao-Ping
Zhao, Yong-Qiang
Powiązania:
https://bibliotekanauki.pl/articles/110181.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium titanomagnetite
carbonthermic reduction
magnesium titanate
formation mechanism
Opis:
Effect of temperature and Mg:Ti ratio on phase composition and microstructure of reduced pellets was investigated to verify the feasibility of preparation of magnesium titanate by adding MgO in carbonthermic reduction of the vanadium titanomagnetite concentrates (VTC). Thermodynamic analysis results showed that magnesium titanate is more easily generated than FeTi2O5 or TiO2 by the reaction of FeTiO3 and MgO under the reductive atmosphere, which was confirmed by the discovery of magnesium titanate at roast experiment. It was found that the optimum conditions for reduction of VTC pellets were temperature of 1250 ºC and Mg:Ti ratio of 2, and the main phases of reduction product were metallic Fe and magnesium titanate (Mg2TiO4). However, trace iron impurities in Mg2TiO4 particles were found by energy-dispersive spectroscopy (EDS), so further purification is required.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 417-425
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of mechanical activation on carbothermic reduction and nitridation of titanomagnetite concentrates
Autorzy:
Wen, Xiaojin
Yu, Wen
Zeng, Danliang
Zhu, Liang Liang
Chen, Jiangan
Powiązania:
https://bibliotekanauki.pl/articles/1446680.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
titanomagnetite concentrates
carbothermic reduction
mechanical activation
titanium nitride
Opis:
The carbothermic reduction and nitridation process of titanomagnetite concentrates with the help of mechanical activation were investigated by particle size analysis, thermodynamic calculation, thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy, and energy-dispersive spectroscopy analysis. The thermogravimetric and X-ray diffraction results indicated that either the reduction of iron oxide or the reduction and nitridation of M3O5 to TiN could be promoted significantly with the increase in activation time. The results obtained from scanning electron microscopy and energy-dispersive spectroscopy showed that, when samples were not activated, chunks of and thin M3O5 were derived from the reduction of ilmenite and titanomagnetite. They were severely sintered with impurities to form a dense structure. As a result, M3O5 was difficult to be converted to TiN, especially chunks of M3O5. However, when samples were activated, the sintering degrees of the impurity and M3O5 were mitigated, and the particle size of the iron as a medium for delivering C to M3O5 was decreased in the roasted product. This condition enhanced the diffusion of C to the surface of M3O5. Meanwhile, the bulk of ilmenite was broken in the activation process, which prevented the formation of chunks of M3O5. Thus, the conversion of M3O5 to TiN was promoted.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 33-45
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Temperature on Fe and Ti in Carbothermic Reduction of Vanadium Titanomagnetite with adding MgO
Autorzy:
Li, Xiaohui
Kou, Jue
Sun, Tichang
Wu, Shichao
Zhao, Yongqiang
Powiązania:
https://bibliotekanauki.pl/articles/110204.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
VTM concentrate
temperature
carbothermic reduction
Fe
magnesium titanate
Opis:
Effects of temperature on Fe and Ti in carbothermic reduction of vanadium titanomagnetite (VTM) concentrate with adding MgO at 1100~1500℃ were investigated. It was found that most of Fe in the VTM concentrate existed in the form of magnetite and a small amount existed as ilmenite; Ti in the VTM concentrate was mainly present in the form of ilmenite. The temperature had significant effects on Fe and Ti: increasing temperature was beneficial to decrease the Fe content in the magnesium titanate mixture, and the Fe content could decrease to 5.47% at 1500℃. Thermodynamic analysis showed that FeTiO3 and MgO preferentially reacted to form Mg2TiO4, followed by MgTiO3 and MgTi2O5 when the temperature increased from 1100℃ to 1500℃. Results of X-ray diffraction and scanning electron microscopy-energy dispersive spectroscopy analyzes showed that an intermediate product of MgFe2O4 would formed at 1300~1400℃ in the actual experiment. This caused the Fe content in the magnesium titanate mixture to increase from 21.32% to 22.85% when the temperature increased from 1200℃ to 1400℃. In addition, the size of magnesium titanate particles could increase from a few microns to approximately 100 µm when the temperature increased from 1100℃ to 1500℃, which was conducive to realize the separation of metallic iron and magnesium titanate.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 4; 917-927
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective reduction of PbSO4 to PbS with carbon and flotation treatment of synthetic galena
Autorzy:
Zheng, Y.-X.
Liu, W.
Qin, W.-Q.
Han, J.-W.
Yang, K.
Luo, H.-L.
Powiązania:
https://bibliotekanauki.pl/articles/110717.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
wastes
lead sulfate
reduction
carbon
lead sulfide
flotation
Opis:
In order to recover lead from the zinc leaching residues, a new technology involving selective reduction of lead sulfate to lead sulfide with carbon followed by flotation was investigated. The reduction thermodynamics of PbSO4 was discussed and the effects of molar ratio of C to PbSO4, reaction temperature and time were examined by thermogravimetry (TG) and XRD. Verification tests were further carried out to prove the conclusions of thermodynamic and TG analyses, and the transformation extent could reach 86.45% under the optimal roasting conditions. The prepared galena was then subjected to micro-flotation tests, and the highest lead recovery could reach up to 75.32%.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 535-546
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on recovery of lead, zinc, iron from jarosite residues and simultaneous sulfur fixation by direct reduction
Autorzy:
Wang, Y.
Yang, H.
Zhang, W.
Song, R.
Jiang, B.
Powiązania:
https://bibliotekanauki.pl/articles/110933.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
jarosite
direct reduction
recovery
valuable metal
sulfur fixation
Opis:
Jarosite residues, which are generated in a zinc production plant by a hydrometallurgical process, contain a large amount of valuable metal components. In this study, a method was proposed for the recovery of lead, zinc and iron from the residues and simultaneous sulfur fixation through direct reduction followed by magnetic separation. The influences of the roasting temperature, roasting time and the concentration of SO2 gas in the direct reduction process were researched in detail. Results showed that the volatilization rates of lead, zinc and sulfur were 96.97%, 99.89% and 1.09%, respectively, and the iron metallization rate was 91.97% under optimal reduction conditions; roasting temperature 1523 K for 60 min. The magnetic concentrate with the iron content of 90.59% and recovery rate of 50.87% was obtained from the optimal reduction product by grinding and magnetic separation. The optimum fineness for separation 96.56% less than 37 μm accounted with magnetic field strength 24 kA/m. The theoretical analysis was carried out by thermodynamics, X-ray powder diffraction, gas analysis and scanning electron microscopy.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 517-526
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects and mechanism of Bayer red mud on co-reduction with a saprolitic laterite ore to prepare ferronickel
Autorzy:
Wang, Xiaoping
Sun, Tichang
Wu, Shichao
Hu, Tianyang
Rong, Lingkun
Powiązania:
https://bibliotekanauki.pl/articles/1449072.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
red mud
laterite ore
co-reduction
ferronickel powder
Opis:
Co-reduction of a saprolitic laterite and waste Bayer red mud was investigated to prepare ferronickel powder. The synchronous reduction and comprehensive recovery of nickel and iron in the low-grade laterite ores and iron in the red mud were realized. At the red mud dosage of 50 wt%, ferronickel powder with nickel and iron grades of 5.58 wt% and 89.91 wt% was obtained. The corresponding nickel and total iron recoveries were 93.11 wt% and 90.23 wt%, respectively. The red mud enhanced the nickel recovery of the saprolitic laterite ore evidently, attributing to the formation of low-melting anorthite, omphacite, and diopside during co-reduction. This led that NiO in the saprolitic ore was released. Meanwhile, obvious melting phenomenon of the roasting system was appeared, enhancing the growth of the ferronickel particles.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 4; 641-652
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sorption and reduction of chromiumion ions by the chelating ion exchanger Diaion CR20
Autorzy:
Wójcik, Grzegorz
Powiązania:
https://bibliotekanauki.pl/articles/109632.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chromium(III)
chromium(VI)
reduction
ion exchange
speciation
chelating resin
Opis:
The chelating ion exchanger Diaion CR20 was applied for removal of chromium(VI) ions in the pH range from 1.5 to 10 and in the presence of 1 M H2SO4. The speciation analysis was used to predict the reduction process. Reduction of chromium(VI) to chromium (III) was observed during the chromium(VI) ions sorption. The kinetic parameters for the pseudo-first-order and pseudo-second-order, Elovich and intraparticle diffusion models were calculated. The most common three isotherm models: Freundlich, Langmuir and Dubinin-Radushkevich were used to describe chromium(VI) uptake. It was proved that the polyamine groups present in selected ion exchanger are able to sorb both chromium(VI) and (III) ions. The maximal sorption capacity towards chromium(VI) ions was estimated at pH 1.5 – 169.49 mg Cr(VI)/g and 159.31 mg Cr(VI)/g in 1 M H2SO4. Both static and column methods were used in the investigations.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1382-1393
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An innovative technology for recovery of zinc, lead and silver from zinc leaching residue
Autorzy:
Zheng, Y.-X.
Lv, J.-F.
Liu, W.
Qin, W.-Q.
Wen, S.-M.
Powiązania:
https://bibliotekanauki.pl/articles/110688.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
zinc leaching residue
lead sulfate
zinc sulfate
reduction roasting
flotation
Opis:
Zinc leaching residue is a good source of zinc and has a great potential to be utilized. However, it is very difficult to recover lead, zinc and silver from the residue by traditional technologies. In this study, a new technology based on conversions of PbSO4 and ZnSO4 in the residue to their respective sulfides by reduction roasting with coal powder followed by a flotation treatment was developed. The effects of roasting temperature, coal dosage, reaction time and pyrite dosage were investigated at a laboratory scale. The results showed that the conversion extent of PbSO4 and ZnSO4 under the optimal experimental conditions was 71.89 and 69.76%, respectively. A flotation concentrate containing 39.13% Zn, 6.93% Pb and 973.54 g/Mg Ag was obtained from the treated material, and the recovery of Zn, Pb and Ag was 48.38, 68.23 and 77.41%, respectively. The tailing containing ZnFe2O4 or Fe3O4 could be either stockpiled or further disposed.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 943-954
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High-temperature carbothermal dephosphorization of Malaysian monazite
Autorzy:
Udayakumar, Sanjith
Sheikh Abdul Hamid, Sheikh Abdul Rezan
Baharun, Norlia
Pownceby, Mark
Powiązania:
https://bibliotekanauki.pl/articles/2146886.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
malaysian monazite concentrate
dephosphorization
carbothermal reduction
rare earth elements
graphite
Opis:
High-temperature carbothermal reduction experiments with graphite powder were conducted to assess the dephosphorization behavior of Malaysian monazite concentrate. Thermodynamic analysis of the possible dephosphorization reactions was conducted to evaluate the feasibility of the carbothermal reduction of the monazite phases. The effects of temperature, particle size, and monazite to carbon ratio were then investigated under different conditions. The carbothermal reduction experiments were conducted based on the Taguchi design method, and up to 97% of phosphorous removal was achieved under optimized conditions. The optimal conditions for dephosphorization were determined as; a reduction temperature of 1350 °C, a particle size of -75 μm, and monazite to carbon molar ratio of 0.3. Microstructural and phase characterization of the dephosphorized products revealed that CeO2, Nd2O3, La2O3, and Pr2O3 oxide phases were prominent, and no residual peaks of monazite remained in the reduced products. The information gained from the study can aid in the design of a suitable post-dephosphorization hydrometallurgical treatment for exploiting Malaysian monazite as a local source of REEs.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 6; 140--155
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of the fixed carbon and ash in blast furnace dust on its co-reduction with seaside titanomagnetite
Autorzy:
Wang, Xiaoping
Hu, Tianyang
Chen, Chuanzhong
Sun, Tichang
Powiązania:
https://bibliotekanauki.pl/articles/109936.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
seaside titanomagnetite
blast furnace dust
co-reduction roasting
fixed carbon
ash
Opis:
Previous research has found that the fixed carbon in blast furnace dust (BFD) could be used as the reductant of co-reduction roasting of the iron oxides in seaside titanomagnetite and BFD to replace coals. This research studied the influence mechanism of the fixed carbon and ash in BFD on coreduction.Results showed that both fixed carbon and ash in BFD promoted the reduction of iron, while ash had adverse effect on separation of titanium and iron. The main mechanism was as follows: The ash in BFD accelerated melting. In addition, the iron oxide in the ash of BFD could be reduced to metallic iron cores more easily in the initial stage, providing the site of inhomogeneous core and promoting the aggregation and growth of metallic iron. Furthermore, the fixed carbon mainly reacted with iron ore by solid-solid reaction, leading to a rapid reduction rate and a high utilization rate of fixed carbon.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1323-1337
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bioleaching of uranium minerals and biosynthesis of UO2 nanoparticles
Autorzy:
Baranska, J. A.
Sadowski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/109668.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bioleaching
U(VI) reduction
Acidithiobacillus ferroxidans
Shewanella
nanoparticles
UO2 precipitation
Opis:
Uranium mining has resulted in generation of significant amounts of solid wastes. The mecha-nism and chemical conditions of uranium waste bioleaching were considered. The initial results of bi-oleaching of solid waste from closed Kowary mine were presented. The process of U(VI) bioreduction by anaerobic reduction microorganisms was described. The factors that contributed to UO2 nanoparticles fabrication were discussed. The obtained UO2 particles are promising for development of novel catalysts.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 1; 71-79
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of pellet technology on direct reduction of jarosite residues from zinc hydrometallurgy
Autorzy:
Wang, Yayun
Yang, Huifen
Hou, Xiaoqiang
Gao, Wenjie
Gui, Haiping
Liu, Qian
Powiązania:
https://bibliotekanauki.pl/articles/110389.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
jarosite residues
direct reduction
powdery jarosite
pellet jarosite
gas concentration analysis
Opis:
In this study, the coal-based direct reduction technique has been applied to recover the valuable metals lead, zinc and ions from powdery and pellet jarosites. The influence of coal dosage of powdery and pellet jarosite separately on the volatilization rates of lead and zinc and on the metallization rate of iron was investigated. Results showed that the lead and zinc in both powdery and pellet jarosite could be effectively reduced with the volatilization rates higher than 95% and 99%, respectively. However, the iron reduction efficiency of pellet jarosite is better than that of powdery jarosite. The concentration of CO and CO2 gas produced in the reduction process of two types of jarosite were detected and compared to investigate the difference of reduction mechanism between powdery and pellet jarosite. The result showed that the utilization of both CO and C during the reduction of pellet jarosite was higher than that of powdery jarosite. The theoretical analysis was carried out by gas analysis and scanning electron microscopy and energy dispersive spectrometer (SEM-EDS).
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 802-811
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improvement of leaching efficiency of cathode material of spent $LiNi_xCo_yMn_zO_2$ lithium-ion battery by the in-situ thermal reduction
Autorzy:
Lu, Qichang
Jiang, Haidi
Xie, Weining
Zhang, Guangwen
He, Yaqun
Duan, Chenlong
Zhang, Jing
Yu, Zhaoyi
Powiązania:
https://bibliotekanauki.pl/articles/1447956.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
spent lithium-ion batteries
in-situ thermal reduction
leaching efficiency
LiNixCoyMnzO
Opis:
Green cars and electronic products consume lots of lithium-ion batteries (LIBs), and massive spent LIBs are yielded due to performance degradation. This paper provides an economical and environmentally friendly approach to recover valuable metals from cathode materials of the spent LIBs. It combines the in-situ thermal reduction (self-reduction by polyvinylidene fluoride (PVDF) and residual electrolyte in cathode material) and sulfuric acid leaching. Elements of high valent are reduced by the binder (PVDF) and the residual electrolyte on the surface of $NCM(LiNi_xCo_yMn_{1-x-y}O_2)$ material at high temperatures. Moreover, the changes in substance type, element valency, and contents of cathode materials reduced with various terminal temperatures and retention time are analyzed by Xray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Results show that the optimal terminal temperature for in-situ thermal reduction is 600 °C, and the optimum retention time is 120 min. Under the best in-situ thermal reduction conditions, the results from XRD confirm that part of $Ni^{2+}$ is converted to simple substance $Ni$, $Co^{3+}$ is reduced to $Co$, and $Mn^{4+}$ is reduced to $Mn^{2+}$ and elemental $Mn$, which are confirmed by XRD. Analyzed results by XPS indicate that the content of $Ni^{2+}$ decreases to 67.05%, and $Co^{3+}$ is completely reduced to $Co$. $Mn^{4+}$ is reduced to 91.41% of $Mn^{2+}$ and 8.59% of simple substance $Mn$. In-situ thermal reduction benefits the leaching processes of cathode materials. The leaching efficiencies of $Ni$, $Co$, and $Mn$ increase from 53.39%, 51.95%, and 0.71% to 99.04%, 96.98%, and 97.52%, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 70-82
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of direct reduction time of vanadium titanomagnetite concentrate on the preparation and photocatalytic performance of calcium titanate
Autorzy:
Li, Xiaohui
Kou, Jue
Sun, Tichang
Wu, Shichao
Tian, Yuechao
Powiązania:
https://bibliotekanauki.pl/articles/1449028.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium titanomagnetite concentrate
calcium titanate
direction reduction
metallic iron
photocatalytic performance
Opis:
Effects of direct reduction time of vanadium titanomagnetite concentrate (VTCE) on the preparation and photocatalytic performance of calcium titanate were investigated in this study. It was found that extending the reduction time could not only promote the formation of calcium titanate, but also facilitate the reduction of iron minerals in the reduction products. The optimum reduction time was 180min under the conditions of $CaCO_3$ dosage of 18wt%, reduction temperature of 1400℃ and lignite dosage of 70wt%. The reduced iron (Fe grade of 90.95wt%, Fe recovery of 92.21wt%) and calcium titanate were obtained via grinding-magnetic separation. Moreover, calcium titanate prepared via the direct reduction method could be used as a photocatalyst, where the degradation degree of methylene blue increased from 25.13% to 60.14% with the addition of calcium titanate. Furthermore, Langmuir Hinshelwood fitting results indicated that the degradation of methylene blue by the calcium titanate prepared under different reduction times conformed to first-order reaction kinetics, where the photocatalytic degradation rate of methylene blue was noted to be the highest for a reduction time of 180 min.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 75-86
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
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