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Wyszukujesz frazę "poly-acrylic acid" wg kryterium: Temat

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    Wyświetlanie 1-3 z 3
    Tytuł:
    Effect of polyacrylic acid molar mass as a surface modifier on rheological properties of calcium carbonate suspensions
    Autorzy:
    Selim, Khaled Abdelaal
    Farghaly, Mohamed Galal
    Abdallah, Samah Saleh
    Abdel-Khalek, Mohamed Abdel-Dayem
    Powiązania:
    https://bibliotekanauki.pl/articles/1446411.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    calcium carbonate
    surface modification
    poly-acrylic acid
    rheology
    adsorption
    Opis:
    Suspensions of calcium carbonate are of a major concern in various fields, such as coating, painting and ceramics and their rheological properties are very important. The effect of polyacrylic acid (PAA) of different molecular mass as a surface modifier on the surface and rheological properties of the aqueous suspension of calcium carbonate was investigated. The effect of the volume fraction of particles and polymer concentration on the viscosity at lower shear rate was discussed. The flow behavior of the concentrated suspension in the presence of PAA can be explained by the difference of the repulsive force among particles, induced by the adsorbed polymer. The results showed that the dispersibility is more pronounced by the steric hindrance behavior rather than the electrostatic behavior.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 18-26
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption of sodium/calcium poly(acrylic acid) salts on anatase: effect of the polyelectrolyte molecular weight and neutralization
    Autorzy:
    Jacquemet, Christian
    Powiązania:
    https://bibliotekanauki.pl/articles/1449765.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    free energy
    Langmuir isotherm
    sodium-calcium poly(acrylic acid) salts
    anatase
    Opis:
    Abstract: Interactions of poly(acrylic acid)s (PAAs) of two different molecular weights (Mw = 9,560 g×$mol^{-1}$ and 4,220 g×$mol^{-1}$) with surfaces of an untreated anatase $TiO_2$ were assessed through adsorption isotherm measurements. Those dispersants were tested under different sodium-calcium neutralization states (molar ratio $r = Ca^{2+}$ / $CO_{2-}$ varying from 0 to 0.35). Their behavior towards the $TiO_2$ surfaces can be described by the Langmuir adsorption model. For both polymers, surface coverage ($Γ_max$) evolves linearly with the molar ratio $r$. For a given r value, a lower surface coverage was observed with the polymer having the highest molecular weight. The free energy of adsorption ($/DeltaG_{ads}$) of PAAs was estimated from adsorption experiment data. This calculation indicates that sorption occurs spontaneously and is unlikely to be of chemical nature. The absolute values of $/DeltaG_{ads}$ are higher for the highest molecular weight polymers suggesting that they are more strongly adsorbed to anatase surfaces. The absolute values of $/DeltaG_{ads}$ per mole of sodium-calcium macromolecules are found to be lower than those calculated for their homologues 100% sodium neutralized suggesting that they are bound with the solid by a fewer number of segments.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 1; 113-123
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption and electrokinetic studies of sodalite/lithium/poly(acrylic acid) aqueous system
    Autorzy:
    Wiśniewska, Małgorzata
    Franus, Wojciech
    Fijałkowska, Gracja
    Ostolska, Iwona
    Wójcik, Grzegorz
    Nosal-Wiercińska, Agnieszka
    Gościańska, Joanna
    Powiązania:
    https://bibliotekanauki.pl/articles/1450512.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sodalite
    zeolite from fly ash
    lithium acquisition
    zeta potential
    solid surface charge density
    poly(acrylic acid) adsorption
    mixed adsorbates
    Opis:
    The synthetic zeolite-sodalite obtained by the hydrothermal conversion of fly ash with aqueous sodium hydroxide was used in the experiments. Its adsorption properties in relation to lithium ions were examined. The effects of: solution pH, presence of polymeric substance – poly(acrylic acid) and order of individual adsorbates addition were determined. To specify the binding mechanism of lithium ions on the sodalite surface, besides adsorption experiments, the measurements leading to the solid surface charge density and zeta potential determination, were performed. As a result, the structure of mixed adsorption layer composed of polymer+metal complexes was characterized. The presented study concerns two important issues: management of environmentally harmful wastes such as coal combustion products as well as searching for new sources of lithium and effective methods of its acquisition.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 6; 158-166
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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