Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "malachite" wg kryterium: Temat

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-7 z 7
    Tytuł:
    New insights into the promotion mechanism of $(NH_4)_2SO_4$ in sulfidization flotation: a combined experimental and computational study
    Autorzy:
    Chen, Daixiong
    Liu, Mengfei
    Hu, Bo
    Dong, Yanhong
    Xue, Wei
    He, Peng
    Chen, Fang
    Zhu, Jianyu
    Zhang, Chenyang
    Powiązania:
    https://bibliotekanauki.pl/articles/1446762.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite
    promotion
    sulfidization
    flotation
    mechanism
    Opis:
    Ammonium sulfate ((NH4)2SO4) exhibits promoting effects in malachite sulfidization flotation. However, the promotion mechanism remains poorly understood. In this study, micro-flotation tests, zeta-potential measurements, scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and materials studio simulation (DFT) were used to investigated the promotion mechanism of $(NH_4)_2SO_4$. Micro-flotation test demonstrates that the recovery of malachite from 73% increased to 83%, when the (NH4)2SO4 was added. Contact angle and zeta potential test results indicate that addition of $Na_2S•9H_2O$ changes the surface properties of malachite and provide the conditions for adsorption of butyl xanthate (BX). After promoting the sulfidization by $(NH_4)_2SO_4$, BX is more effective in improving the hydrophobicity. SEM-EDS and AFM results show that $(NH_4)_2SO_4$ can improve performance and stability of sulfidization. X-ray photoelectron spectroscopy indicates that after sulfidization, polysulfides and cuprous were appeared in malachite surface, infers that a redox reaction occurs between sulfur and copper on the surface of malachite. After addition of $(NH_4)_2SO_4$, the percentage of polysulfides and cuprous were increased, it implies $(NH_4)_2SO_4$ can accelerate the redox reaction. Computational results show that after adding $(NH_4)_2SO_4$, the adsorption energy of HS- on the malachite surface is reduced, implies that $(NH_4)_2SO_4$ can improve the stability of HS-adsorption on the surface of malachite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 5; 57-70
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effects of copper ions on malachite sulfidization flotation
    Autorzy:
    Yin, Wanzhong
    Sheng, Qiuyue
    Ma, Yingqiang
    Sun, Haoran
    Yang, Bin
    Tang, Yuan
    Powiązania:
    https://bibliotekanauki.pl/articles/110331.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite
    sulfidization flotation
    Cu2+ ion
    depression
    Opis:
    In this study, the effects of copper ions (Cu2+) on the sulfidization (Na2S) flotation of malachite was investigated using micro-flotation experiments, zeta-potential measurements, X-ray photoelectron spectroscopy (XPS) analysis, adsorption experiments, and Materials Studio simulation. The results indicated that the flotation recovery of malachite decreased after the pretreatment of the mineral particles with Cu2+ ions prior to the addition of Na2S. The results for zeta-potential measurements and XPS analysis revealed that less sulfide ion species in the pulp solution transferred onto the mineral surface, the sulfidization of malachite surface weakened. The adsorption amount of collector on the mineral surface decreased, and this finding was confirmed by the results of the zeta-potential and adsorption experiments. Materials Studio simulation revealed that the adsorption energy of HS- ions and C4H9OCSS- ions on malachite surface increased after the adding of Cu2+ ion. The competitive adsorption made Cu2+ ions depress sulfidization flotation of malachite, the dissolution of mineral surface affected the adsorption of reagents on it, and decreased the floatability of malachite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 2; 300-312
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dissolution kinetics of malachite in ethylene diamine phosphate solutions
    Autorzy:
    Shen, Peilun
    Liu, Ruizeng
    Liu, Dianwen
    Zhan, Xiaolin
    Jia, Xiaodong
    Song, Kaiwei
    Powiązania:
    https://bibliotekanauki.pl/articles/110214.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite
    organic amine
    ethylene diamine phosphate
    dissolution
    kinetic
    Opis:
    Ethylene diamine phosphate (EDP), as a synthetic organic reagent, was used for the first time to leach malachite, and a new method of using organic amine to leach copper oxide ore was developed. The effects of stirring speed, particle size, reagent concentration, and reaction temperature on EDP-dissolution malachite were investigated. Results showed that malachite rapidly dissolved in EDP solution. The malachite-dissolving rate also increased with increased reagent concentration, increased reaction temperature, and decreased particle size. Stirring speed exhibited nearly no effect on EDP-induced malachite dissolution. The leaching kinetics was found to follow the shrinking-core model, and dissolution was controlled by surface chemical reaction with an activation energy of 52.63kJ×mol−1. A semiempirical rate equation was obtained to describe the dissolution process expressed as 1-(1-XCu)1/3=0.0149(CEDP)0.7814 × (Pmalachite)−0.7982×exp(−6.3308/T) ×t.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 4; 1039-1048
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    DFT and TOF-SIMS study of the interaction between hydrogen sulfide ion and malachite (–201) surface
    Autorzy:
    Mao, Yingbo
    Wu, Dandan
    Huang, Lingyun
    Powiązania:
    https://bibliotekanauki.pl/articles/1447053.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite
    hydrogen sulfide ions
    sulfidation
    DFT
    TOF-SIMS
    Opis:
    In this paper, the mechanism of interaction between hydrogen sulfide ions and malachite was investigated using density functional theory (DFT) calculations and time of flight secondary ion mass spectrometry (TOF-SIMS). The DFT calculations showed that HS− adsorption on the malachite (−201) surface was stronger than that of S adsorption resulting from the higher number of electron transfers in the solution which accelerated the sulfidation reaction rate. Density of states (DOS) analysis showed that the near Fermi level was jointly contributed to by the Cu 3d, O 2p, O 2S, and S 3P orbits after adsorption of HS− on the malachite (–201)surface. It was found that the 2p orbital of O and the 3p orbital of S overlapped, indicating that S not only reacted with Cu, but also with O. The TOF-SIMS detected S− and CuS2− fragment ion peaks in the 0−150 m/z negative segment of mass spectra. TOF-SIMS also showed that copper sulfide films of certain thicknesses were formed, demonstrating the effectiveness of hydrogen sulfide sulfidation in flotation processes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 5; 71-79
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis of a novel hydroxamic acid flotation collector and its flotation separation of malachite against quartz
    Autorzy:
    Sun, Xin
    Huang, Lingyun
    Wu, Dandan
    Hu, Bo
    Zhang, Mei
    Li, Yaming
    Tong, Xiong
    Powiązania:
    https://bibliotekanauki.pl/articles/2146909.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    collector
    malachite
    hydroxamic acid
    direct flotation
    adsorption
    Opis:
    This paper proposes a promising chelating collector, phenyl propyl hydroxamic acid (BPHA), to directly float malachite for the separation of malachite against quartz. The flotation performance and mechanism was investigated via microflotation tests, as well as through contact angle, Scanning Electron Microscopeand Energy Dispersive Spectrometer (SEM–EDS), zeta potential, adsorption capacity, Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS) analyses. The results of microflotation tests showed that BPHA has a strong ability to collect malachite and a significant selectivity against quartz. The contact angle tests showed that BPHA effectively adsorbed onto the mineral surface and could improve the hydrophobicity of the malachite surface. SEM–EDS and adsorption capacity analyses further indicated that BPHA adsorbed onto the surface of malachite. The FR-IR results suggested that BPHA could react with Cu2+ ions and facilitate strong chemical adsorption onto the surface of malachite. Furthermore, zeta potential and XPS analyses provided clear evidence that BPHA exhibited a stronger affinity for malachite and a weaker interaction with quartz.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149427
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Structural modification of cellulose to enhance the flotation efficiency of fine copper oxide ore
    Autorzy:
    Gu, Guohua
    Zhu, Renfeng
    Chen, Zhixiang
    Powiązania:
    https://bibliotekanauki.pl/articles/109394.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fine malachite
    collector
    sulfuration flotation
    contact angle
    mean size
    flocculation
    Opis:
    Using more efficient collector to improve the recovery efficiency of fine copper oxide has become imperative as the shortage of copper mineral resources. In this study, the new collector 3-hydroxy butyrate-carboxy methyl cellulose xanthate (HCMCX) was synthesized by carboxy methyl cellulose, 3-hydroxy butyrate and carbon disulfide, all of which as raw materials . The structural characteristics of HCMCX was detected by both infrared spectrum and ultraviolet spectrum. Besides, the interacting behavior between HCMCX and fine malachite was investigated through particle size analysis, contact angle measurements, and flotation tests. Particle size analysis indicated that the mean size of malachite was increased by 8 μm while the HCMCX concentration at 200 mg/dm3. The contact angle measurements demonstrated that, comparing with the collector AX at a same dosage, the mineral surface of malachite showed a stronger hydrophobicity after interacting with HCMCX. Microflotation tests results exhibited that the recovery of malachite was about 94% when the pulp pH 8 and collector concentration at 200 mg/dm3. The results of practical ore flotation tests showed that HCMCX could as an excellent collector for flotation of fine malachite, finally to achieve the concentrates containing 20% Cu and 88% Cu recovery.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 58-69
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Role of ammonium phosphate in improving the physical characteristics of malachite sulfidation flotation
    Autorzy:
    Ibrahim, Ayman M.
    Jia, Xiaodong
    Cai, Jinpeng
    Su, Chao
    Yu, Xingcai
    Zheng, Qifang
    Peng, Rong
    Shen, Peilun
    Liu, Dianwen
    Powiązania:
    https://bibliotekanauki.pl/articles/2200339.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite sulfidation
    sample preparation
    ammonium phosphate
    sodium sulfide
    floatability
    physical characteristics
    Opis:
    In this study, ammonium phosphate ((NH4)3PO4) was employed to realize improvement by modifying the physical characteristics of the malachite surface, ensuring sustainable flotation throughout the flotation operations, and enhancing the flotation process to be more stable. Furthermore, various techniques, including X-ray photoelectron spectroscopy, were intensely used to investigate the configuration and physico-chemical surface characteristics through micro-flotation experiments, contact angle and zeta potential measurements, and XRD, ToF-SIMS, EPMA, and FTIR spectrum analyses. The FTIR findings showed that new characteristic peaks of -C(=S)-N.H. groups formed and adsorbed on the surfaces of malachite at 1636 cm-1. The -CH2 groups throughout the flotation process, further promoted the attachment of the CH3 ligand to the Cu2+ ion, and the XPS analysis confirmed this. Consequently, it can be concluded that (NH4)3PO4 played a substantial part in the improved recovery rate, as demonstrated and confirmed by the methods carried out in this study. Thus, it was used to modify the physical properties surface before adding Na2S to efficiently enhance malachite floatability and reduce the loss rate of malachite. Regarding the alterations in the physical characteristics which occurred to the malachite surface, and as a consequence of increasing the recovery results of flotation, the malachite sample treated initially with (NH4)3PO4 exhibited micro flotation results with a considerably greater flotation recovery than malachite treated initially with only Na2S ions.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 161510
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies