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Wyszukujesz frazę "iron oxides" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Influences of process water chemistry on reverse flotation selectivity of iron oxides
Autorzy:
Tang, Min
Wang, Dong
Wu, Yan
Liu, Dianwen
Powiązania:
https://bibliotekanauki.pl/articles/2175429.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
water chemistry
ion distribution
iron oxides
reverse flotation
Opis:
It is critical for water quality in flotation as it dramatically influences the chemical/electrochemical properties of mineral surfaces and their interactions with reagents. Many potential variations could alter the water chemistry: water recirculation, mineral dissolutions, reagent additions, etc. This study aimed to identify the key elements from the recycled water sources affecting the separation efficiency in a typical industrial flotation circuit of iron oxides through a series of bench/micro flotation tests, zeta potential measurement, etc. The built-up and distribution of the dominant cations/anions in the process water from the roughers in the flotation system was also analyzed and recorded by Inductively Coupled Plasma-Optical Emission (ICP-OES) for a period of about three months when the operations were stable. The flotation results pointed out that a concentrate with a sharp increase of 6.0% Fe recovery and 2.5% SiO2 content was obtained by using the recycled tailing water only in comparison by using fresh water. In contrast, a slight uptrend in the grade of Fe but a substantial loss of near 6.5% Fe recovery occurs by using the treated sewage water alone instead. This could attribute to the ion distributions in these water sources, in which Ca2+, Fen+, Mg2+ or SO42ions were determined as the key ions influencing the flotation behaviors of the iron ore. But the competitive effects of Fe3+ ions were more significant than the ones of Ca2+ or Mg2+ ions. And the occurrence of starch could deteriorate the dilution of silicates in concentration induced by Fe3+/Fe2+ ions. It can be explained by zeta potential measurement or solution chemistry of those ions, indicating that at 8.5-9.0, the coating of the precipitates of Fe(OH)3(s) induced by iron ions alters a reverse on the zeta potentials of quartz. The presence of SO42-ions, however, has a positive role in reducing the possibility of slime coating on silicates due to acting as a chelating agent of iron ions.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151839
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arsenate removal on the ion exchanger modified with cerium(III) ions
Autorzy:
Dudek, Sebastian
Kołodyńska, Dorota
Powiązania:
https://bibliotekanauki.pl/articles/2146888.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
arsenic
adsorption
cerium
iron oxides
Ferrix A33E
Opis:
The iron oxide ion exchanger Ferrix A33E was successfully modified with cerium(III) ions to obtain Ferrix A33E-Ce(III) providing much better sorption properties in relation to the As(V) species. The new material has been characterized using a number of techniques including scanning electron microscopy SEM, nitrogen adsorption/desorption isotherms, Fourier transform infrared spectroscopy FTIR and X-ray photoelectron spectroscopy XPS. At optimal pH 6 the main mechanism of arsenate adsorption on A33E-Ce(III) was electrostatic attraction and formation of monodentate and bidentate surface complexes. The process was exothermic and spontaneous. Unlike the unmodified ion exchanger, A33E-Ce(III) could completely remove arsenic from the arsenate solution at a concentration of 50 mg/dm3 in 60 minutes. Furthermore, the maximum sorption capacity for As(V) was determined to be 60.41 mg/g which almost doubled after modification with cerium(III) ions. It is also worth noting that even after three cycles of sorption/desorption A33E-Ce(III) exhibited a higher sorption capacity than unmodified A33E before the arsenate adsorption. It can be concluded that modifying the sorbent with a small amount of cerium(III) ions boosts its sorption properties significantly, improves effectiveness of water purification and reduces the overall operation cost
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2 (Special issue - selected papers conference: Physicochemistry of interfaces - instrumental methods); art. no. 147412
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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