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Wyszukujesz frazę "flotation kinetics" wg kryterium: Temat


Wyświetlanie 1-12 z 12
Tytuł:
On the selection of the coarsest size class in flotation rate characterizations
Autorzy:
Orellana, Francisca
Rivera, Marcelo
Benítez, Matías
Belmonte, Karyn
Vinnett, Luis
Powiązania:
https://bibliotekanauki.pl/articles/24603662.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetics
froth flotation
coarse particles
flotation rate distribution
Opis:
This paper studies size-by-size batch flotation kinetics for the separation of Cu at particle sizes +75 μm, investigating the responses in the -150/+75 μm, -212/+150 μm, -300/+212 μm, -355/+300 μm and +355 μm size fractions. The kinetic results were analyzed to identify classes limited by the maximum achievable recovery or low flotation rates. Combinations of these classes were investigated, emulating the selection of the coarsest size in a kinetic study. The impact of compositing size classes was discussed, emphasizing implications in the identification of difficult-to-float components. The -212/+75 μm classes reached steady recoveries at long flotation times, whereas the -355/+212 μm classes presented sustained increasing recoveries at extended flotation times. Flotation rate distributions in the -212/+75 μm classes exhibited mound-shaped distributions, indicating low fractions of rate constants close to zero (R∞-limited case). Conversely, the -355/+212 μm classes presented reverse J-shaped distributions, with a high fraction of valuable minerals with flotation rates close to zero (rate-limited case). Combining several size classes in the definition of the coarsest size fraction in kinetic characterizations proved to hide the flotation patterns of the less massive constituents (+212 μm classes). The +75 μm and +150 μm cumulative retained classes trended towards steady recoveries, consistently leading to mounded flotation rate distributions. This study highlighted the need for reliable methodologies to select size fractions in kinetic characterizations, as their arbitrary definitions may lead to a misinterpretation of the mineral losses when compositing classes with different flotation responses.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 5; art. no. 176950
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of frothers and particle size on the flotation kinetics of the Jameson Cell
Autorzy:
Şahbaz, Oktay
Demir, Muhammet Kubilay
Powiązania:
https://bibliotekanauki.pl/articles/1845223.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetics
Jameson cell
frothers
particle size
Opis:
Determination of the flotation kinetic is crucial for optimization, simulation, and plant design for flotation processes. Even though there are many studies carried out to clarify the kinetic properties of the conventional flotation cells, there is not enough detailed study about the Jameson cell which is used more than 300 plants but no application in Turkey yet. One of the most important parameters affects the kinetic of flotation is a frother. The effects of common frothers on the kinetic of Jameson cell can be crucial due to the possible further application of the cell in European and Turkish flotation industries. The present study was performed out to reveal the kinetic properties of the Jameson cell by using both pure quartz and coal particles. Besides, the effects of three different types of frothers on the kinetic of the Jameson cell were investigated for various particles sizes. According to the results, aliphatic alcohol type frother (MIBC) provided higher recovery for fine particles, while polypropylene glycol type frother (AF65) gave a better ability to float medium and coarse size particles. Additionally, the results show that the Jameson cell was four times faster than the mechanical cell for medium size while the ratio was three times for coarse particles. Lastly AF65 can be used for flotation of coarse particles in the Jameson cell while MIBC can be preferred for fines.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 5; 829-838
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems
Autorzy:
Yan, H.
Yuan, Q.
Zhou, L.
Qiu, T.
Ai, G.
Powiązania:
https://bibliotekanauki.pl/articles/110078.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetics
pyrite
chalcopyrite
flotation separation
high alkaline
microcalorimetry
Opis:
The monomineral flotation test and microcalorimetry were used to study the flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems of lime and NaOH. The results showed that in these systems there were less hydrophilic substances on the chalcopyrite surface, so that the apparent activation energy of sodium butyl xanthate (SBX) adsorption on chalcopyrite surface was low. This promoted the adsorption of SBX and increased the flotation rate and recovery of chalcopyrite. In contrast, the hydrophilic Fe(OH)3 and SO42- formed by oxidation on the pyrite surface increased the adsorption activation energy of SBX. Thus, the flotation rate and recovery of pyrite were lower. Moreover, in the lime high alkaline system, the hydrophilic calcium film generated on the pyrite surface further hindered the adsorption of SBX, thereby further inhibiting pyrite in this environment. In other words, the lime high alkaline environment increased the apparent activation energy difference of SBX adsorption between chalcopyrite and pyrite compared to the NaOH system, facilitating the flotation separation of chalcopyrite and pyrite. The results can help with the theoretical research of flotation separation of other minerals, and provide guidance for developing low alkaline and lime-free pyrite depressants.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 901-910
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of sodium petroleum sulfonates with different molecular weights for flotation of kyanite ore
Autorzy:
Chen, B. Z.
Gao, H.
Li, Y.
Jin, J.
Ren, Z.
Wang, W.
Powiązania:
https://bibliotekanauki.pl/articles/109492.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
evaluation
sodium petroleum sulfonate
kyanite
flotation kinetics
entrainment
Opis:
The flotation performance of sodium petroleum sulfonates with different molecular weights was evaluated for flotation of a kyanite ore, by investigating valuable mineral recovery-grade, flotation kinetics and gangue entrainment. The results indicated that the higher molecular weight of agent, the higher final cumulative kyanite recovery was, with the maximum value of 72% being obtained with KY-3 with the molecular weight of 438. The final cumulative kyanite grade initially increased, and then decreased with the molecular weight increasing. In other words, the maximum final cumulative kyanite grade (i.e. 89.05%) was obtained with KY-2 with the molecular weight of 392. The kyanite flotation kinetics followed the first order kinetics well, while the modified flotation rate constant showed a decreasing trend after the initial increase as the molecular weight increased. In addition, the overall entrainment degree decreased with decreasing molecular weight of sodium petroleum sulfonates. The use of KY-2 in kyanite flotation was an attractive option in comparison with KY-1 and KY-3.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 956-968
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A sensitivity analysis of kinetic characterizations in continuous flotation circuits under moderate deviations with respect to perfect mixing
Autorzy:
Vinnett, Luis
Pino-Muñoz, Catalina A.
Yianatos, Juan
Díaz, Francisco
Henríquez, Felipe
Powiązania:
https://bibliotekanauki.pl/articles/2146941.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetics
residence time distribution
perfect mixing
flotation rate distribution
industrial flotation circuit
Opis:
This paper studies the effect of moderate deviations with respect to perfect mixing on the estimated kinetic parameters in industrial flotation banks. Radioactive tracer tests and mass balance surveys were performed to characterize the mixing regimes and Cu kinetic responses. For three models (Single Rate Constant, Rectangular and Gamma), two approaches to incorporate the residence time distributions (RTD) in the kinetic characterizations of rougher banks were compared: (i) RTDs measured from the radioactive tracer tests; and (ii) pure perfect mixing in each flotation machine. The measured RTDs did not present significant bypass in the evaluated banks. In all cases, comparable model fitting was obtained with both RTD approaches, which indicates that the kinetic models add sufficient flexibility to compensate for moderate biases in the mixing regime. The studied kinetic models showed non-significant differences in the estimated maximum recoveries (R∞), mean (kmean) and median (k50) rate constants when comparing the process modelling from measured RTDs and pure perfect mixing. However, the Gamma model was more sensitive to the RTD assumption in terms of the shapes of the flotation rate distributions. From the results, kinetic characterizations focused only on model fitting, or on R∞ and kmean (or k50) estimations have low sensitivity to the assumption of perfect mixing when the RTDs present moderate deviations with respect to this regime. Special attention must be paid when characterizing floating components as the perfect mixing assumption may bias the shapes of the flotation rate distributions.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152420
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of monovalent and divalent ions in coal gasification brine on the froth entrainment and flotation kinetics of anthracite coal
Autorzy:
Zheng, Kaidi
Bu, Xiangning
Zhou, Shaoqi
Zhang, Jing
Shao, Huaizhi
Sha, Jie
Xie, Guangyuan
Powiązania:
https://bibliotekanauki.pl/articles/1845216.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal gasification brine
salts ions
coal flotation
entrainment
flotation kinetics
DLVO theory
Opis:
Water plays a critical role in various stages of flotation, which brings a lot of pressure to the flotation processing plants resided in dry areas. In this regard, it will be of significance to explore the feasibility of using wastewater resources in mineral flotation. Coal gasification brine (CGB) that contains a high concentration of salts becomes the subject of interest of this study. In this study, a synthetic CGB solution, which was prepared by adding NaCl, MgCl2, and CaCl2 to ultrapure water based on the composition of salts in a real CGB, was used in the flotation of anthracite coal. The comparison results based on the first-order model showed that flotation in the presence of the synthetic CGB solution gave a higher flotation selectivity (SI =7.086) than that of flotation in ultrapure water (SI=3.545). Water recoveries and average bubble sizes in the froth showed that the addition of the three salt ions (Na+, Mg2+, and Ca2+) was conducive to diminishing the entrainment of gangue materials as a result of the reduction of water reporting to the froth. Additionally, the zeta potentials and induction time measurements indicated that only divalent ions of Ca2+ and Mg2+ significantly compressed the double electrical layer and enhanced the attachment between bubbles and coal particles according to DLVO theory, which was further confirmed by the calculation of interaction energy between coal and bubbles. The findings of the present work may promote the use of CGB as a potential water resource in coal flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 5; 960-974
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface roughness in bubble attachment and flotation of highly hydrophobic solids in presence of frother – experiment and simulations
Autorzy:
Kosior, D.
Kowalczuk, P. B.
Zawala, J.
Powiązania:
https://bibliotekanauki.pl/articles/109319.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
surface roughness
attachment
flotation
kinetics
frother
Opis:
In this paper, the kinetic of the three-phase contact (TPC) formation and the flotation recovery of highly hydrophobic solids with different surface roughness were studied in pure water and aqueous solutions of n-octanol. The surface roughness varied between 1 to 100 μm. It was found that there was a strong influence of surface roughness on both kinetics of TPC formation and flotation. The time of three phase contact formation and flotation rate were much faster for rough surfaces in both water and aqueous solutions of frother. Irrespective of the surface roughness, at above a certain frother dose, the attachment time increased and the flotation rate decreased. It was related to the presence of air at the hydrophobic solid surfaces. The mechanism of this prolongation of the time of TPC formation at the solid surfaces with different roughness due to the frother overdosage was discussed, and the experimental data were confirmed by numerical simulations.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 1; 63-72
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physicochemical study of dye removal using electro-coagulation-flotation process
Autorzy:
El-Hosiny, F. I.
Abdel-Khalek, M. A.
Selim, K. A.
Osama, I.
Powiązania:
https://bibliotekanauki.pl/articles/109865.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
electro-flotation
electrocoagulation
dyes
wastewater
kinetics
thermodynamics
Opis:
The performance of electro-flotation with aluminum electrodes for the removal of different dyes from synthetic aqueous solutions and real wastewater was studied. Parameters affecting the electro-coagulation-flotation process, such as pH, initial dye concentration, treatment time and temperature were investigated. The maximum dye removal from synthetic solutions was achieved at pH 7. The order of the dye removals is nonionic>cationic>anionic. The removal process follows pseudo first-order kinetics and the adsorption follows both physical and chemical adsorptions which is exothermic. Negative values of entropy change, ΔS°, and Gibbs free energy change, ΔG°, indicate that this adsorption process is spontaneous and less favorable at high temperatures. Treatment of a real wastewater from textile dyeing factory showed that the removal efficiency was ranging between 92-99% for all constituents. The energy consumption is 0.0167 kWh/dm3.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 321-333
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Lignite cleaning in NaCl solutions by the reverse flotation technique
Autorzy:
Zhang, H.
Liu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/110516.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lignite
reverse flotation
NaCl
kinetics
coal preparation
Opis:
A cleaning possibility of low (BD) and high ash content (IM) lignites in NaCl solutions using a reverse flotation technique was studied. Preliminary test results indicated that BD lignite cannot be cleaned effectively in the traditional manner because gangue was floated first rather than a combustible material. Further studies indicated that the lignite cleaning in NaCl solutions using the reverse flotation technique is possible. However, a large quantity of dodecyl amine hydrochloride (DAH) was required. A lower ash content in a concentrate can be obtained by addition of NaCl. A concentrate yield can be im-proved by addition of starch. Under the test conditions, for BD lignite with the ash content in the feed 15.19%, the ash content in the concentrate 11.44% and the concentrate yield 67.38% were obtained. Similarly, for IM lignite with the ash content in the feed 57.40%, the ash content in the concentrate 32.90% and the concentrate yield 25.08% were obtained. The flotation rate constant k and maximum ash recovery ε∞ significantly increased with the NaCl concentration.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 695-706
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic separation curves based on process rate considerations
Autorzy:
Drzymala, J.
Ratajczak, T.
Kowalczuk, P. B.
Powiązania:
https://bibliotekanauki.pl/articles/110027.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
separation
flotation
kinetics
separation curves
process rate
Opis:
There are many graphical representations of separation results involving time as a crucial parameter determining the kinetics of a process. The graphical representations of results of separation are usually in the form of 2D plots relating two parameters which one of them is time. Time can also be utilized as a complex parameter such as a process rate. The plots involving time are called kinetic curves. Theoretically, the number of kinetic curves is infinite. The basic process kinetic curves, relating either yield (or recovery) and time can be modified to obtain numerous local and global efficiency curves. The global efficiency kinetic curves provide characteristic constants which do not change with the time and yield of a process. In this paper the local and global efficiency plots were created using experimental data which followed the so-called first order kinetics. It was shown that the integral 1st order kinetic equation provided the kinetic constant k which was numerically identical with the 1st order specific rate v, while their units were different (k, 1/min; v, %/(%·min). The global efficiency parameters plotted versus the maximum yield provided another type of plot, which can be called the limits kinetic curve. The limits kinetic curves are very useful for characterizing, quantification and classification of separation systems. The limits kinetic curves can be normalized providing one universal curve with a characteristic point, for instance, v50 indicating the specific rate (or kinetic) constant at the maximum recovery equal to 50%. The mathematical equation of the normalized limits kinetic curve was given in the paper.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 983-995
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficient chromium removal from aqueous solutions by precipitate flotation using rhamnolipid biosurfactants
Autorzy:
Shojaei, V.
Khoshdast, H.
Powiązania:
https://bibliotekanauki.pl/articles/110347.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
kinetics
wastewater
chromium
rhamnolipid biosurfactant
precipitate flotation
Opis:
In the present research study, the efficient removal of hexavalent chromium from aqueous solutions by precipitate flotation method was investigated. The experiments were carried out with the use of ferrous sulfate as a precipitating agent for chromium and rhamnolipid bio surfactant (RL) as a precipitate collector. The effects of rhamnolipid and co-precipitate concentrations, aeration rate, solution pH, and salt addition on the chromium removal were studied using a full factorial design. The chromium removal and water recovery to foam products were analyzed as process responses. Statistical analyses showed that the effects of all factors on the chromium removal followed a non-linear trend with a peak at the middle level. After the process optimization, the maximum chromium removal of 96.75±0.3% was obtained at pH value of 8, RL/Cr ratio of 0.01, Fe/Cr ratio of 3, and aeration rate of 50 cm3/min. Addition of salt with different cationic and anionic groups negatively influenced the removal efficiency. Kinetic studies suggested that the process of chromium removal by the precipitate flotation followed the first-order process with a rate constant of about 0.018 sec-1. Given the good removal capacity and kinetics, rhamnolipid biosurfactants can be a promising environmental-friendly bio collector for the removal of chromium ions from aqueous solutions.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 1014-1025
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic modelling of flotation column and Jameson cell in coal
Autorzy:
Karaca, Sevgi
Ucar, Ali
Sahbaz, Oktay
Powiązania:
https://bibliotekanauki.pl/articles/2146872.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coarse particle
flotation column
Jameson cell
kinetics
particle size
Opis:
Physical enrichment technologies can be used worldwide in various coal washing plants to enrich up to 500 μm particle size. Conversely, coals smaller than this are discarded as waste, causing storage and environmental issues. In this regard, studies on coal below 500 μm in Turkey have recently acquired attraction. The Jameson flotation cell and flotation column, which have many uses worldwide but are not used throughout the plant in Turkey, were used to investigate the separation possibilities of coals below 500 μm. In the study, the flotation column and Jameson cell performances for three different particle sizes (-500+300, -300+212 and -212+106 μm) were compared. For the first time, both machines operated in a negative bias condition. In addition, the flotation kinetics of the machines were modelled with some critical operating parameters. Models illustrating the main and multiple effects of the parameters were developed using the data derived from the experimental results, and the models were statistically significant at the 95% confidence level. In the experiments performed with both flotation machines, the flotation rate increases with the decrease in particle size in general. According to the results, the velocity increase in the Jameson cell was 0.0050-0.0075 min-1 compared to the flotation column in the experiments performed in the size range of -500+300 μm, and the flotation rate constant increased approximately twice. In the size range of -212+106 μm, the difference became larger, and the flotation rate of the Jameson cell increased up to six times with a difference of 0.0450-0.0500 min-1.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152848
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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