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Wyszukujesz frazę "Potential" wg kryterium: Temat


Tytuł:
The effect of zeta potential on the sedimentation behavior of natural stone processing effluent
Autorzy:
Kurama, H.
Karaguzel, C.
Powiązania:
https://bibliotekanauki.pl/articles/109985.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
travertine
environment
stone industry
zeta potential
Opis:
One of the main problems for the natural stone industry is treatment of huge amount of waste sludge resulting from the cutting and polishing of them to produce slabs or tiles. The effective treatment of this sludge is very important for reducing of the sludge volume and overall operating costs. Previous studies showed that settling rate and water clarity of the supernatant solution can be increased by flocculation process. In this study, detailed electrokinetic studies were performed on the travertine samples received as natural and slurry form. The natural form of the sample was supplied from a travertine quarry while the slurry was taken from the cutting and polishing process wastewater collector pool of the processing plant. The electrokinetic measurements were conducted to find out the effect of suspension pH and the solid content on the surface potential of solid particles show that zeta potential (ζ) of travertine is positive at pH 9.76 over the all solid contents studied in this work. However, ζ of the particles become negative at lower pH values for 1% solid weight content. In contrast, for travertine slurry (6.73% solid weight), different potential variations were determined. The particles were negatively charged between pH 6 and 8. The results highlighted the effect of dissolved specific ions in the waste slurry and sensitivity of ζ to the ionic strength of the solution. The ζ measurements for a raw travertine sample, performed with different amounts of NaCl additions into the solutions, confirmed the above findings. An addition of low amounts of NaCl decreases ζ of the solid surface. Finally, the ζ measurements in the presence of polymer concentration of 0.001% to 0.1 % (wt/vol) clearly indicated that the flocculant molecules are adsorbed extensively on the travertine particles, and increase the surface potential of the particles with increasing reagent concentration.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 575-586
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective dispersion-flocculation and flotation studies on a siliceous copper ore
Autorzy:
Mweene, L.
Subramanian, S.
Powiązania:
https://bibliotekanauki.pl/articles/109546.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flocculation
adsorption
zeta potential
dispersion
chalcopyrite flotation
Opis:
A low-grade copper ore from Mpanda Mineral Field (MMF), Tanzania containing 0.90% Cu, 10.40% Fe and 58.3% SiO2 was subjected to beneficiation adopting selective dispersion, flocculation and flotation techniques. Based on the mineralogical characterization of the sample chalcopyrite, pyrite and quartz were identified as the major minerals. The isoelectric point of MMF ore was observed to be at pH 2.7, signifying that the ore was highly siliceous. The addition of sodium trisilicate and xanthan gum shifted the zeta potential of ore to more electronegative values. Adsorption of xanthan gum on chalcopyrite and silica indicated that the maximum adsorption was at pH 2.3 for chalcopyrite and the adsorption isotherm exhibited L2 type of the Giles classification. On the contrary, no adsorption of xanthan gum on silica was observed. The ground ore was selectively dispersed and flocculated at pH 9.7 using 30 ppm of sodium trisilicate and 30 ppm of xanthan gum. The grade of CuFeS2 was improved to 19.8% after 3 desliming stages. Flotation of the flocculated portion was carried out at pH 10.30 using 30 g/t of potassium amyl xanthate and potassium ethyl xanthate (1:1) , 40 g/t of Na2S as a sulphidising agent and methyl iso-butyl carbinol (MIBC) as a frother yielding a rougher concentrate with silica and chalcopyrite grades of 8.4% and 23.5% respectively with corresponding recoveries of 4.8% and 92.8% respectively. Additionally, rougher concentrate was subjected to cleaner flotation yielding silica and chalcopyrite grades of 1.8% and 29.2 % respectively and with recoveries of 1.2% and 89.1% respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1282-1291
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dispersive effect of low molecular weight sodium polyacrylate on pyrite-serpentine flotation system
Autorzy:
Zhao, K.
Yan, W.
Wang, X.
Gu, G.
Deng, J.
Zhou, X.
Hui, B.
Powiązania:
https://bibliotekanauki.pl/articles/110158.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
dispersant
serpentine
flotation
surface potential
dispersion mechanism
Opis:
In this work, the dispersive effect of low molecular weight sodium polyacrylate (PAAS) on serpentine, and its dispersion mechanism were systematically investigated through zeta potential measurements, micro and batch flotation as well as adsorption tests. At pH 5, where flotation of iron sulphide was routinely performed, pyrite and serpentine minerals were oppositely charged, and therefore they were attracted to each other. Slime coatings of serpentine adhered to the surface of pyrite, decreasing the adsorption density of a collector on the pyrite surface, but also reducing the flotation recovery. PAAS increased the flotation recovery of pyrite by promoting dispersion between pyrite and serpentine. The effective flotation separation of pyrite from the refractory iron sulphide ore was possible by using PAAS as a dispersant. Anionic PAAS adjusted the surface potential of serpentine through adsorption on the serpentine surface and changed the interaction between pyrite and serpentine particles from attractive to repulsive, and then dispersed pyrite and serpentine.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1200-1213
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of ovalbumin on pyrite flotation in the absence and presence of metal ions
Autorzy:
Guler, T.
Sahbudak, K.
Akdemir, U.
Cetinkaya, S.
Powiązania:
https://bibliotekanauki.pl/articles/110499.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
ovalbumin
metal ion
flotation
redox potential
Opis:
Recovery of gangue pyrite and its accidental activation are vital issues in flotation of complex sulfide ores. This work was performed by cyclic voltammetry (CV) and flotation tests to elucidate applicability of ovalbumin (OVA) as depressant for pyrite. The synergetic effect of metal ions in addition to its possible use in case of accidental activation by metal ions. CV tests stated that OVA adsorbed irreversibly on pyrite, and restricted electron transfer up to moderately oxidizing potentials due to electrostatic interaction together with weak hydrophobic interactions. At highly oxidizing potentials, adsorption occurred through electrochemical mechanisms through formation of metal-OVA chelates. Rate of pyrite depression with OVA was found to be potential dependent reaching its peak point around moderately oxidizing potentials both in absence and presence of metal ions. Electrochemically active metals display synergetic effect with OVA on pyrite depression, whereas noble metals activate pyrite and reduced depressing potency of OVA.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 31-40
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental study on electrokinetic of kaolinite particles in aqueous suspensions
Autorzy:
Min, F.
Zhao, Q.
Liu, L.
Powiązania:
https://bibliotekanauki.pl/articles/110918.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
kaolinite
zeta potential
pH
immersion time
electrophoresis
Opis:
Influence of aqueous phase properties and process parameters on kaolinite particle zeta potential was quantified by electrophoresis experiments. The results indicated that pH strongly altered the zeta potential of kaolinite and it decreases at the beginning and then increases in the range of pH = 2–13. The activity of different cations changes the zeta potential and has the following tendency of Al3+ > Ca2+ > Mg2+ > Na+ and the zeta potential increases due to heterocoagulation of different mineral particles in suspension. It was found that the zeta potential of kaolinite particles increases after the suspension was stirred and decreases at the beginning, and then increases with soaking time. The FTIR results showed that the zeta potential takes into account ion adsorption and the change of Si–O, Al–O and Al–OH groups on the surface of the kaolinite particles.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 659-672
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A study of selected properties of rhenium sulphide dispersion
Autorzy:
Pawlak, D. W.
Parus, J. L.
Skwarek, E.
Janusz, W.
Powiązania:
https://bibliotekanauki.pl/articles/951830.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
rhenium sulphide
particle size distribution
zeta potential
Opis:
Due to potential application of rhenium sulphide in medicine and industry, this study is focused on the properties of synthetic and commercial rhenium sulphide. The main reaction of rhenium sulphide preparation involves potassium perrhenate and sodium thiosulphate in the acidic environment giving a mixture of rhenium sulphide and sulphur. The next step is removing sulphur by its dissolution in ether. Stabilization by Povidone K-25 is needed to obtain rhenium sulphide dispersed with the grain size of 0.5–4 m. The extrapolated value of pHiep for synthesised rhenium sulphide is 2.3 whereas for commercial samples this value is lower than 2. For synthetic sample a dependence of zeta potential on the carrier electrolyte concentration is found. It is larger than that for the commercial sample, probably due to surface oxidation during synthesis or purification.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 387-397
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of oxidation roasting on ilmenite flotation
Autorzy:
Mehdilo, A.
Irannajad, M.
Rezai, B.
Powiązania:
https://bibliotekanauki.pl/articles/109387.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
ilmenite
oxidation roasting
surface chemistry
zeta potential
Opis:
In this study, the oxidation roasting was used to modify the ilmenite chemistry to improve the collector adsorption and ilmenite flotation behavior. The results indicated that the increase of the roasting temperature up to 600 ºC increased the ilmenite flotation recovery. The maximum collector adsorption density occurred on ilmenite roasted at 600 °C which resulted in the increase of ilmenite flotation recovery from 73.5% to 91% at pH 6.3. This improvement was attributed to a greater conversion of Fe2+ to Fe3+ ions and significant decrease in the zeta potential of ilmenite. At the roasting temperatures of 750 °C and 950 °C, ilmenite was converted to rutile and some trivalent iron containing phases such as hematite and pseudobrookite. Under these conditions, the collector adsorption and hence ilmenite flotation improved, however the flotation recovery decreased after the roasting at 950 °C.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 493-505
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arrheniusan activation energy of separation for different parameters regulating the process
Autorzy:
Drzymała, J.
Powiązania:
https://bibliotekanauki.pl/articles/109713.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
activation energy
separation
Gibbs potential
Arrhenius plot
Opis:
The Arrhenius model, that relates the activation energy with the kinetic constant and process temperature, was applied for flotation as a separation process, and next was extended to other incentive parameters such as the frother concentration, NaCl content and hydrophobicity. It was shown that determination of the activation energy caused by other incentive parameters (i.e. particle size, surface potential) was also possible. The units of the activation energy depend on the type of the separation process and incentive parameter. For contact angle regulating flotation the activation energy unit is mJ/m2, while for the frother concentration is J. It is known that instead in joules, the activation energy can also be expressed in J/mol and in kT or RT units, where k is the Boltzmann constant, R gas constant and T is absolute temperature in kelvins. Even though different formulas of the specific Gibbs potential were used for calculation of activation energy caused by various incentive parameters, there was generally a good agreement between the extend of changes of the first order kinetic constants of the process and activation energy value. It was found that for flotation of copper-bearing carbonaceous shale the activation energy was equal to 1.1 kT for NaCl as the incentive parameter, 3.0 kT for temperature and 32.7 kT for butyl diethylglycol ether used as a flotation frother. For methylated quartz the hydrophobicity-induced activation energy was 42 mJ/m2 for contact angle as the incentive parameter.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1152-1158
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A comparative study on interactions of ionic collectors with orthoclase
Autorzy:
Ozun, S.
Atalay, M. U.
Powiązania:
https://bibliotekanauki.pl/articles/110609.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
collector interactions
zeta potential
microflotation
FTIR
AFM
orthoclase
Opis:
Flotation and adsorption characteristics of the most commonly used cationic and anionic collectors with high grade orthoclase were investigated through the electrokinetic potential measurement, microflotation, Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM) studies. According to the obtained results, orthoclase had high flotation recovery with amine and oleic acid based (OAB) collector at certain pH ranges no flotation response was observed with petroleum sulfonate at different pHs. In contrast to the flotation recovery differences, the electrokinetic potential measurements, FTIR and AFM analyses presented similar adsorption characteristics for all collectors. The results of electrokinetic potential tests showed that amine had a strong influence on the zeta potential of orthoclase. While amine turned the zeta potentials of orthoclase from negative to positive, sulfonate and OAB collector provided slightly more negative zeta potentials at certain pHs. In the case of FTIR and AFM analyses, each collector-treated orthoclase (CTO) sample displayed similar characteristic FTIR bands of CH2 group and micro topographical collector coated patches with different intensities. However, the interactions of each collector with orthoclase surfaces were altered by rinsing with acetone indicating that the interactions were mostly through the electrostatic forces and/or hydrogen bonding.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 955-972
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oil agglomeration of metal-bearing shale in the presence of mixed cationic-anionic surfactants
Autorzy:
Polowczyk, I.
Kruszelnicki, M.
Kowalczuk, P. B.
Powiązania:
https://bibliotekanauki.pl/articles/110617.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
zeta potential
synergism
surfactants
kerosene
hydrophobic coagulation
Opis:
This paper reports oil agglomeration of fine metal-bearing shale particles in the presence of cationic (dodecylamine hydrochloride) and anionic (sodium dodecyl sulfate) surfactants and their mixture. The experimental results demonstrated that there was a strong relationship between zeta potential, hydrophobic coagulation, oil agglomeration and particle hydrophobicity in the presence of cationic surfactant, whereas shale neither coagulated nor agglomerated in the presence of anionic surfactant. Addition of either anionic or cationic surfactant in emulsification of a bridging oil increased the size of agglomerates and reduced the concentration of surfactant used in the suspension. The results pointed to synergism between cationic and anionic surfactants in oil agglomeration. Based on the results obtained from this study, the mechanism of oil agglomeration of shale in the presence of ionic surfactants and their mixture was elucidated.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1052-1059
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of cationic-anionic surfactants on selective oil agglomeration of oil shale
Autorzy:
Abdel-Khalek, Mohamed A.
Amin, Rasha
Hassan, El-Sayed R. E.
Powiązania:
https://bibliotekanauki.pl/articles/1450561.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
oil shale
oil agglomeration
kerogen
surfactants
zeta potential
Opis:
Egyptian oil shale from Red Sea area is upgraded via oil agglomeration technique to achieve a clean fuel. A representative sample is characterized to identify its undesirable components and its liberation size. The quartz, apatite, calcite, siderite and anhydrite are the main gangue minerals. The sample was pulverized to less than 20 µm for efficient liberation. The impact of anionic (Calcium dodecyl benzene sulfonate, CDBS) or/and cationic (Cetrimonium bromide, CTAB) surfactants on the zeta-potential and agglomeration process was investigated in presence of different kerosene concentrations. A concentrate of 62% kerogen with 95% recovery was obtained from feed of 29% kerogen using 0.1% CTAB/CDBS mixture in 2% kerosene emulsion.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 137-144
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A procedure of Arrhenius activation energy determination for salt flotation of particles in the vicinity of one molar salt aqueous solutions
Autorzy:
Ratajczak, Tomasz
Kurkiewicz, Szymon
Drzymala, Jan
Powiązania:
https://bibliotekanauki.pl/articles/1450643.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activation energy
salt flotation
Arrhenius equation
Gibbs potential
Opis:
A modified Arrhenius equation, in which thermal energy is replaced with chemical (Gibbs) potential, and a special calculation procedure were used to evaluate the flotation activation energy for salt solutions in the one molar range of concentrations. The proposed formula overcomes the difficulties of calculating the salt flotation activation energy caused by mathematical problems of finding 1/(ln($c$/$c_o$)) for the standard salt concentration $C_o$ =1 M (1 kmol/m3 and when the applied salt concentration c is in the vicinity of 1 M. The salt flotation activation energy was calculated for flotation of copper-bearing carbonaceous shale in the 0.25, 0.50, 1.00 and 2.00 M NaCl solutions performed in a laboratory machine as equal to 1.9 RT for standard salt solution equal to 1 M.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 1-5
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Diffuse-layer surface potentials of colemanites mined in Turkey
Autorzy:
Senol-Arslan, Dilek
Drelich, Jaroslaw W.
Powiązania:
https://bibliotekanauki.pl/articles/2146938.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
colemanite
surface potential
atomic force microscopy
boron
DLVO
Opis:
Colemanite crystal specimens were handpicked at Kestelek, Emet (Hisarcik, Espey), Bigadic mines in Turkey for characterization of their composition and surface potential. X-ray diffraction analysis revealed no differences in mineralogical makeup of the crystals, but elemental analysis indicated differences in the type of trace (<0.1 wt%) elements. Zeta potential measurements showed small differences in zeta potential values, with isoelectric points (iep) varying from about pH = 9.6 to pH = 10.2. However, no correlation was found between iep and the type of trace elements. Additionally, atomic force microscopy (AFM) was employed to measure the colloidal interactions between a silicon nitride (Si3N4) cantilever tip and colemanite crystal surfaces in 1 wt% colemanite-saturated aqueous solutions at three different pHs (8.4, 9.4 and 11). The Derjaguin-Landau-Verwey-Overbeek theory (DLVO) was applied to examine the AFM tip interactions with colemanite surfaces in an aqueous solution of colemanite saturated solutions. The results revealed attractive forces at pH = 8.4 and 9.4 and repulsive forces at pH = 11, confirming the location of an isoelectric point for colemanite specimens somewhere between pH = 9.5 and pH = 10.1. Theoretical analysis of the force curves using the DLVO theory allowed for assessment of both surface charge density and surface potential for colemanite specimens used in this study.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 151933
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation separation of dravite from phlogopite using a combination of anionic/nonionic surfactants
Autorzy:
Fawzy, Mona M.
Powiązania:
https://bibliotekanauki.pl/articles/1446137.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
dravite
phlogopite
anionic/nonionic mixture
flotation
zeta potential
FTIR
Opis:
In the present study, the effect of a mixture of anionic collector (sodium oleate)/ non-ionic surfactant (sorbitan monooleate) on the flotation separation of dravite from the main associated gangue phlogopite was investigated in comparison of using single sodium oleate as a collector. The flotation experiments were conducted on pure single minerals of dravite and phlogopite. The flotation results demonstrated that adding sorbitan monooleate to Na-oleate at a dose of 5.64 kg/Mg Na-oleate with 0.43 kg/Mg sorbitan monooleate in the presence of methyl isobutyl carbinol (MIBC) as a frother (0.12 Kg/Mg) at pH 7.7 improved the flotation efficiency of dravite from 73.5% by using sodium oleate as a single collector to 96.9% using the mixture. Whereas, the flotation recovery of phlogopite in the same conditions reached 26.3%. The zeta potential measurements and Fourier transform infrared (FTIR) spectroscopy analysis were also implemented to investigate and predict the mechanism of collector adsorption on the mineral surfaces. As a result of flotation experiments and the zeta potential measurements of FTIR analysis, high chemisorption of the mixed collector on the surface of dravite was obtained, on the contrary, a little amount of the collector mixture adsorbed on the phlogopite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 87-95
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zeta potential of Teflon in presence of monovalent and divalent ions
Autorzy:
Gulgonul, Ilhan
Powiązania:
https://bibliotekanauki.pl/articles/110571.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
polytetrafluoroethylene
PTFE surface
natural hydrophobic
zeta potential
contact angle
Opis:
In this study, the specific effects of Na+ and Ca2+ ions on natural hydrophobic Teflon particles and flat Teflon surfaces were investigated using zeta potential and contact angle measurements, respectively. The zeta potential measurements showed that the surface charge of Teflon was negative at all pH values in the absence of salt ions, and became the positive with the increased salt concentration, and obtained an iso electric point (iep) between pH 3 and 4. The results also indicated that Ca+2 ions more adsorbed on the Teflon surface compared to Na+ ions in the case of the compression of the electrical double layer. The contact angle measurements with Teflon sample showed that while the flat Teflon had a contact angle of 107° at pure water, and the contact angle considerably reduced as a function of salt concentration. This decrease was more effective in the presence of Ca2+ ions rather than Na+ ions. While calcium is a strong water structure maker cation, sodium is a weak structure maker cation, but the role of calcium is more effective at the Teflon-water interface according to zeta potential and contact angle measurements. It is revealed that the Ca+2 ions have a specific effect on Teflon surface due to low salt concentrations and ion charges. The different effects of these cations on Teflon-water interface can be attributed to use in mineral processing, especially in flotation enrichment.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 792-801
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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