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    Wyświetlanie 1-4 z 4
    Tytuł:
    Kinetics and mechanism of one-step reductive leaching of manganese oxide ores by EDTA/EDTA-2Na
    Autorzy:
    Zhang, C.
    Wang, S.
    Cao, Z.
    Zhong, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/109834.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    kinetics
    EDTA
    reductive leaching
    manganese oxide ores
    EDTA-2Na
    Opis:
    In this research, the kinetics and mechanism of one-step reductive leaching of manganese oxide ores by ethylenediaminetetraacetic acid (EDTA) or its disodium salt (EDTA-2Na) in an aqueous medium have been investigated. The kinetic data of this reductive leaching process may be described by the Avrami model, and the apparent activation energy was determined to be 15.8 kJ·mol-1/7.9 kJ·mol-1 for leaching by EDTA/EDTA-2Na with a reaction order of -1.7/2.0. The EDTA/EDTA-2Na leach liquor characterized and analyzed by X-ray photoelectron spectra (XPS), Fourier transform infrared spectra (FTIR), and total organic carbon (TOC) determination denoted that the oxidation-reduction reaction happened between manganese(IV) and EDTA/EDTA-2Na, and a coordination complex, EDTA-manganese(II/III) formed. This new process can be easily used to leach manganese from manganese oxide ores in a moderate environment with the pH range of 5–8.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 858-867
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of two-stage stirred pulp-mixing on coal flotation
    Autorzy:
    Gui, X.
    Wang, Y.
    Zhang, H.
    Li, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110764.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    mixing
    stirred
    two stage
    fine coal
    flotation
    Opis:
    Stirred pulp-mixing is performed before coal flotation. In this study, a two-stage stirred pulpmixing tank was designed based on the single-stirred process to intensify the mixing effect of pulp and flotation reagents. A tank has a pitched-impeller opening-type turbine. Stirred pulp-mixing and flotation experiments were conducted on a sample of anthracite fine coal (-0.5mm) from the Xuehu Coal Preparation Plant in Henan Province, China. The results of the two-stage stirred pulp-mixing were compared with those of a single-stage stirred pulp-mixing in terms of flotation performance. Compared with the single-stage stirred pulp-mixing, two mixing areas and double-layer impeller were able to strengthen the energy input to the stirred system, thereby improving the mixing efficiency of flotation reagents and coal particles in the pulp. The two-stage stirred pulp-mixing significantly increased the flotation feed rate of the cyclone-static micro-bubble flotation column and concentrate yield, enhanced the combustible matter recovery effect of coarse particles at a suitable flotation feed rate, and ensured the recovery effect of fine particles at high flotation feed rate.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 1; 299-310
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation behaviour and surface characteristic of anosovite in a sodium oleate solution
    Autorzy:
    Wang, Y.
    Wen, S.
    Zhang, J.
    Wu, D.
    Xian, Y.
    Shen, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/110766.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    anosovite
    sodium oleate
    flotation
    adsorption
    Opis:
    Properties of anosovite in titanium slag, anosovite flotation response in a collector solution of sodium oleate, and adsorption behaviour of sodium oleate on the mineral surface were studied in the present work using XRD, Raman spectra, flotation tests, zeta potential analysis, FTIR and XPS. The results show that the anosovite crystal contains magnesium, and its chemical composition is Mg0.09Ti2.91O5. The chemical bonds on the anosovite surface mainly comprise Ti-O bonds. Micro-flotation tests indicate that anosovite has better floatability at a wide pH range and the recovery reaches 88% at pH=6, when the dosage of sodium oleate is only 4·10−6 mol/dm3. The point of zero charge of anosovite was determined near pH 3.2 by the zeta potential measurement. In the flotation process, chemical adsorption occurs between the carboxyl of sodium oleate and the titanium sites on the anosovite surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 714-723
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Response of energy-size reduction to the control of circulating load in vertical spindle pulverizer
    Autorzy:
    Li, H.
    He, Y.
    Zhang, Y.
    Ge, Z.
    Xie, W.
    Wang, S.
    Li, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/110803.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    circulating load control
    response of energy-size reduction
    mixture grinding
    energy efficiency
    Opis:
    In the vertical spindle pulverizer (VSP), the large circulation ratio and high ash and sulfur contents in circulating load would result in intensive energy consumption and low grinding efficiency. Although the control of circulating load would help increase the energy efficiency, no quantitative study has been conducted due to the high temperature and pressure in the closed VSP. In this study, response of energy-size reduction to the control of circulating load was studied by the experimental simulation method. Coal mixtures with fine/coarse ratio of 11:1, 8:1 and 6:1 were ground by a lab-scale roller mill. Energy-size reductions of the coarse coal were compared to evaluate the influence of circulating load control. Results showed that the product with the coarse coal increased by 30% when the specific breakage energy was 1.0 kWht–1 as the circulation ratio decreased from 11 to 6. Meanwhile, a breakage characteristic index of the coarse coal was two times higher due to the cushioning effect of fines. Besides, decrease of circulation ratio led to increase of the breakage rate of coarse coal, and the energy saving improved by 57%. With the same energy input of 2.0 kWht-1, the yield of –0.09 mm pulverized fuel (PF) increased from 22 to 43%. Therefore, controlling the circulating load is an effective method to improve the breakage rate of coarse coal and energy efficiency for PF generation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 793-801
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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