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    Tytuł:
    Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor
    Autorzy:
    Yang, Xiao-Feng
    Xu-Zhao
    Liu, Yao-Yao
    Powiązania:
    https://bibliotekanauki.pl/articles/24085868.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ethyl thioglycolate
    chalcopyrite
    molybdenite
    inhibitor
    separation
    Opis:
    The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162824
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dispersion of sodium phytate on muscovite and the implications for arsenopyrite flotation
    Autorzy:
    Zou, Dan
    Wang, Zhen
    Zhao, Kaile
    Xu, Ying
    Powiązania:
    https://bibliotekanauki.pl/articles/2175449.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cassiterite
    chlorite
    sodium oleate
    carboxymethyl cellulose
    selective inhibition
    Opis:
    The effective flotation separation of sulfides and sliming silicate minerals is always a difficult problem. In this paper, the selective flotation of arsenopyrite from muscovite was studied by using sodium phytate (SP) as dispersant, and the mechanism was investigated through SEM/EDS, zeta potential, FTIR and XPS measurements. Single mineral flotation results showed that with the increasing isoamyl xanthate (IAX) dosage the recovery of arsenopyrite increased, until 8×10−5 mol/L IAX (79.40% recovery, pH=7), after that it decreased slightly. While muscovite floated poorly at any IAX concentration. For the mixed minerals, arsenopyrite recovery was only 54.63% while that of muscovite was 42.70%, which was attributed to the coverage of muscovite on arsenopyrite surface. When 6×10−5 mol/L SP was added into the mixed minerals system, the recovery of arsenopyrite recovered to 68.26% while that of muscovite was 8.48% (approximate the value of the single mineral). SEM/EDS results showed that SP could disperse muscovite and prevented its coverage on arsenopyrite surface. Zeta potential results showed that the electrokinetic potential of muscovite and arsenopyrite decrease from -26.60mV to -39.01 mV and from -26.90 mV to -27.84 mV at pH=7, respectively. It was obvious that the negatively charged phytate ions selectively adsorbed on the surface of muscovite. FTIR and XPS resulted co-proved the chemisorption of SP with active sites on muscovite while arsenopyrite spectrum did not change significantly, which was consistent with flotation and zeta potential results. The selective adsorption of SP on muscovite compared to arsenopyrite was responsible for the effective separation of them.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 154951
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption of yeast dextran on clinochlore surface and the implications for pyrite/clinochlore separation
    Autorzy:
    Wang, Zhen
    Zou, Dan
    Zhao, Kaile
    Safarov, Sayfidin
    Xu, Ying
    Powiązania:
    https://bibliotekanauki.pl/articles/2146917.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    clinochlore
    pyrite
    flotation
    yeast dextran
    adsorption
    Opis:
    Silicate minerals with a certain degree of flotability are often easy to mix into sulfide ore concentrate in mineral processing industry. In this paper, the adsorption of yeast dextran on clinochlore and its application in pyrite/clinochlore separation were investigated. The adsorbed amount and micro polarity measurement results displayed that the yeast dextran molecules selectively adsorbed onto clinochlore surface compared with pyrite. The adsorbed yeast dextran resulted in the increase in the surface polarity of clinochlore surface, and inhibited the further adsorption of xanthate, thus keep it hydrophilic and depressed. Quantum chemical computation results indicated that yeast dextran was mainly adsorbed on mineral surface by the chelation with the surface metal active sites, and the chelating strength of yeast dextran with three ions was in the sequence of Fe3+ > Mg2+ > Fe2+. While Mg2+, Fe2+ and Fe3+ are the main metal ions on the surface of clinochlore, and Fe2+ is the unique metal ions on pyrite surface. This is the reason of the selectivity of the yeast dextran depressant for pyrite/clinochlore flotation system. The flotation results demonstrated that yeast dextran was qualified to selectively depress clinochlore in pyrite flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 151635
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation separation of quartz from phosphorite using an imidazole ionic liquid collector and its adsorption mechanism
    Autorzy:
    Zhao, Yuanyuan
    Xu, Wei
    Mei, Guangjun
    Yu, Mingming
    Yang, Siyuan
    He, Zhan
    Powiązania:
    https://bibliotekanauki.pl/articles/2146857.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    reverse flotation
    imidazole ionic liquid
    desilication
    phosphorite
    quartz
    Opis:
    In this study, an imidazole ionic liquid (dodecyl-tri-methylimidazolium chloride) was employed as a collector to separate quartz from phosphorite. The micro-flotation experiments of a single mineral found that it had selective collecting ability for quartz than phosphorite. Mixed mineral flotation experiments confirmed that efficient separation results could be obtained using the imidazole ionic liquid as the collector. A concentrate with a 31.44% grade of phosphorite could be obtained with a 0.285 kg/Mg collector dosage at neutral pH, which was much better than the traditional collector dodecylamine. The adsorption mechanism of the imidazole ionic liquid on the surface of phosphorite and quartz was investigated by contact angle and zeta potential measurements, Fourier transform infrared and X-ray photoelectron spectroscopy analyses. These results showed that the adsorption of imidazole ionic liquid at the quartz surface was stronger than that of phosphorite, and the collector adsorbability difference between quartz and phosphorite resulted in the efficient flotation separation. Consequently, the dodecyl-tri-methylimidazolium chloride salt is an effective collector for reverse flotation of quartz from phosphorite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 1; 159--168
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mineralogical factors affecting the separation behavior of Ta-Nbbearing minerals in the gravity field: mineral grain size, liberation, and association relationship
    Autorzy:
    Cheng, Hongwei
    Xu, Jian
    Wang, Shoujing
    Lv, Zihu
    Wei, Fushuai
    Zhao, Dengkui
    Wu, Dongyin
    Powiązania:
    https://bibliotekanauki.pl/articles/27323650.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    separation behavior
    gravity field
    mineralogical characteristic
    columbite-tantalite
    association relationship
    liberation
    Opis:
    Gravity separation is the primary method used to beneficiate Ta-Nb-bearing minerals, however, it performs poorly in low-grade and fine-grained ores. A comparative study of gravity separation products (concentrate, middlings, and tailings) reveals the factors affecting the separation behavior of Ta-Nb-bearing minerals in the process combined with a spiral chute and shaking table from the perspective of mineralogy. The results reveal that columbite-tantalite is the principal Ta-Nb-bearing mineral. As the grinding time increases, the grade of Ta and Nb in concentrate increases significantly. The grain size of columbite-tantalite in the concentrate is the coarsest, followed by that in the middlings, and the finest in the tailings, which are mainly distributed in the range of -150+38 μm, -75+20 μm, and -38 μm, respectively. The liberation degree of columbite-tantalite in the concentrate and tailings is positively correlated with grinding time, while that in the middlings is negatively correlated with grinding time. The density of columbite-tantalite-bearing particles in concentrate is mainly distributed above 3 or even 4, due to the high liberation degree of the columbite-tantalite in the concentrate, as well as the high amount of rich intergrowth associated with heavy minerals. The density of Ta-Nb-bearing mineral particles in the middlings and tailings is predominantly distributed in D<3, owing to columbite-tantalite mainly associated with lighter gangue minerals such as quartz, albite, and orthoclase. It demonstrates that the liberation degree is not the most essential factor in determining columbite-tantalite separation behavior in the gravity field, and the mineralogical characteristics of columbite-tantalite including grain size, association relationship, and particle density, may be more important. The results of this investigation can provide theoretical support for the strengthening separation of low-grade tantalum-niobium ore.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174504
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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