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    Wyświetlanie 1-6 z 6
    Tytuł:
    Investigation on different behavior and mechanism of Ca(II) and Fe(III) adsorption on spodumene surface
    Autorzy:
    Yu, F.
    Wang, Y.
    Wang, J.
    Xie, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/110230.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    spodumene surface
    calcium ions
    iron ions
    adsorption mechanism
    DFT calculation
    Opis:
    Behavior and mechanism of Ca2+ and Fe3+ adsorption on spodumene surface were investigated by micro flotation tests, zeta potential measurements, and density functional theory (DFT) calculation methods. The micro flotation tests showed that Ca2+ and Fe3+ activated the flotation of spodumene remarkably. However, the effect of Fe3+ was more significant than that of Ca2+. Additionally, Fe3+ significantly changed the zeta potential of spodumene while Ca2+ showed a little change. Meanwhile, the calculated adsorption energy of Fe3+ on spodumene surface was much greater than that of Ca2+ indicating that Fe3+ is more apt to be adsorbed on spodumene surface than Ca2+. The value of bond population in Ca-O illustrated that the bond of Ca-O consists of partial covalent proportion and some ionic component. On the contrary, the bond of Fe-O showed a relatively strong covalent property. The partial density of states (PDOS) of free Ca/Fe and the reacted O atom on spodumene (110) surface before and after the adsorption showed that Fe 3d orbital and O 2p orbital formed hybridization. The density of states (DOS) near the Fermi level of spodumene surface after adsorption with Fe3+ was much stronger than that with Ca2+.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 2; 535-550
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of flotation behavior and mechanism of cervantite activation by copper ions
    Autorzy:
    Wang, J.
    Wang, Y.
    Fu, K.
    Xu, L.
    Wang, Z.
    Sun, H.
    Xiao, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/110228.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    cervantite
    copper ions
    activation mechanism
    Opis:
    Copper-ion activation plays a highly important role in cervantite (Sb2O4) flotation. Without metal-ion activation, cervantite cannot be floated by sodium oleate. In this study, flotation tests were conducted to study the effect of Cu2+ on the flotation behaviours of cervantite and quartz (SiO2) as the main gangue mineral. Metal-ion adsorption capacities, zeta potentials, solution chemistry and X-ray photoelectron spectra were analyzed to study the adsorption behavior and mechanism of copper ions and sodium oleate interaction with the minerals surfaces. The results demonstrate that under weakly acidic conditions, cervantite can be flotated and separated from quartz by the addition of copper ions. The reason is that copper ions can be selectively adsorbed on the cervantite surface under weakly acidic conditions, thereby promoting the adsorption of sodium oleate onto the cervantite surface by chemical adsorption. Conversely, copper ions are weakly adsorbed on quartz surfaces below pH 6.1, and sodium oleate cannot be adsorbed on quartz surfaces by chemical adsorption. The hydroxy copper species are integral to the selective activation of cervantite over quartz.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 814-825
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation separation of cervantite from quartz
    Autorzy:
    Wang, J.
    Hua, Y.
    Yu, S.
    Xiao, J.
    Xu, L.
    Wang, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/110941.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cervantite
    quartz
    dodecylamine
    flotation
    density functional theory
    Opis:
    Flotation separation of cervantite (Sb2O4) from quartz was investigated using dodecylamine (DDA) as a collector. Experiments were conducted on single minerals and on a synthetic mixture of quartz and cervantite. Flotation separation mechanisms were investigated using the zeta potential technique, solution chemistry principles, density functional calculations and Fourier Transform Infrared (FT-IR) spectroscopy. The results indicated that DDA, primarily in the form of molecules, exhibited excellent performance in flotation of cervantite and quartz at pH 10.5. The adsorption energy of the DDA molecules on the cervantite surface was greater than the adsorption energy of water molecules, while the adsorption energy of DDA on the quartz surface was less than the adsorption energy of water molecules. DDA molecules can be adsorbed on the quartz surface to a certain extent, but it was difficult for the same molecule to be adsorbed on the cervantite surface in the pulp. This resulted in flotation of quartz. DDA molecules were adsorbed on quartz not only through physical adsorption but also by hydrogen bonding. However, cervantite could not be floated at pH 10.5 since adsorption of DDA molecules occurred through weak physical bonds on cervantite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1119-1132
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    One step purification of impurities in the leachate of weathered crust elution-deposited rare earth ores
    Autorzy:
    Zhou, F.
    Feng, J.
    Wang, Z.
    Xu, Y.
    Zhang, Z.
    Chi, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/110333.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    leachate
    weathered crust
    rare earth ore
    leachate purification
    precipitation
    Opis:
    It is necessary to control and reduce the high content of Al3+, Cu2+ and Pb2+ ions in the leachate of weathered crust elution-deposited rare earth ore to facilitate the rare earth recovery and the quality of rare earth products. Neither NH4HCO3 nor Na2S are suitable for removal of all impurity ions and meanwhile maintain high rare earth recovery. Conventionally, NH4HCO3 is firstly adopted to remove Al3+, and then Cu2+ and Pb2+ are removed by using Na2S. This two steps purification process is quite long and results in lots of complication in operation. In this paper, a one-step purification by using the compound of NH4HCO3 and Na2S was proposed to remove Al3+, Cu2+ and Pb2+. The results showed that after purification 89% Cu, 92% Pb and 74% Al were removed from the leachate solution by using 0.1 M compound of NH4HCO3/Na2S, while maintaining 89% rare earth. The optimal purification parameters were: volume ratio of NH4HCO3 to Na2S of 9:1, volume ratio of compound to leachate of 0.05:1, precipitation time of 30 min.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1188-1199
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Evaluation of sodium petroleum sulfonates with different molecular weights for flotation of kyanite ore
    Autorzy:
    Chen, B. Z.
    Gao, H.
    Li, Y.
    Jin, J.
    Ren, Z.
    Wang, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/109492.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    evaluation
    sodium petroleum sulfonate
    kyanite
    flotation kinetics
    entrainment
    Opis:
    The flotation performance of sodium petroleum sulfonates with different molecular weights was evaluated for flotation of a kyanite ore, by investigating valuable mineral recovery-grade, flotation kinetics and gangue entrainment. The results indicated that the higher molecular weight of agent, the higher final cumulative kyanite recovery was, with the maximum value of 72% being obtained with KY-3 with the molecular weight of 438. The final cumulative kyanite grade initially increased, and then decreased with the molecular weight increasing. In other words, the maximum final cumulative kyanite grade (i.e. 89.05%) was obtained with KY-2 with the molecular weight of 392. The kyanite flotation kinetics followed the first order kinetics well, while the modified flotation rate constant showed a decreasing trend after the initial increase as the molecular weight increased. In addition, the overall entrainment degree decreased with decreasing molecular weight of sodium petroleum sulfonates. The use of KY-2 in kyanite flotation was an attractive option in comparison with KY-1 and KY-3.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 956-968
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Response of energy-size reduction to the control of circulating load in vertical spindle pulverizer
    Autorzy:
    Li, H.
    He, Y.
    Zhang, Y.
    Ge, Z.
    Xie, W.
    Wang, S.
    Li, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/110803.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    circulating load control
    response of energy-size reduction
    mixture grinding
    energy efficiency
    Opis:
    In the vertical spindle pulverizer (VSP), the large circulation ratio and high ash and sulfur contents in circulating load would result in intensive energy consumption and low grinding efficiency. Although the control of circulating load would help increase the energy efficiency, no quantitative study has been conducted due to the high temperature and pressure in the closed VSP. In this study, response of energy-size reduction to the control of circulating load was studied by the experimental simulation method. Coal mixtures with fine/coarse ratio of 11:1, 8:1 and 6:1 were ground by a lab-scale roller mill. Energy-size reductions of the coarse coal were compared to evaluate the influence of circulating load control. Results showed that the product with the coarse coal increased by 30% when the specific breakage energy was 1.0 kWht–1 as the circulation ratio decreased from 11 to 6. Meanwhile, a breakage characteristic index of the coarse coal was two times higher due to the cushioning effect of fines. Besides, decrease of circulation ratio led to increase of the breakage rate of coarse coal, and the energy saving improved by 57%. With the same energy input of 2.0 kWht-1, the yield of –0.09 mm pulverized fuel (PF) increased from 22 to 43%. Therefore, controlling the circulating load is an effective method to improve the breakage rate of coarse coal and energy efficiency for PF generation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 793-801
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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